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High casting speed continuous casting covering slag used for ultra-low-carbon steel

A technology of ultra-low carbon steel and mold flux, applied in the direction of improving process efficiency, etc., can solve problems such as inability to achieve, inability to adapt, and carbon increase, so as to reduce the effect of carbon increase and overcome negative effects

Active Publication Date: 2011-06-15
BAOSHAN IRON & STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The mold slag mentioned above can effectively reduce the carburization effect on the molten steel when the casting speed of the continuous casting machine is low and the fluctuation of the molten steel surface is small. The direct contact between the layer and the molten steel, the carburization phenomenon is obvious
At the same time, the high casting speed has higher requirements on the performance of the mold flux and requires more stable metallurgical properties. If the amount of the flame retardant or flame retardant added in the above patent is too small, it will not be able to play its due role. If the amount is too large, it will It will destroy the related properties of mold powder, so it can no longer meet the requirements of high casting speed mold powder for ultra-low carbon steel

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A continuous casting mold powder for ultra-low carbon steel, the weight percent distribution ratio of the chemical composition of the premelt is: CaO: 31%, SiO 2 : 42%, Al 2 o 3 : 7%, MgO: 2%, F: 7%, Na 2 O: 8%, B 2 o 3 : 1.0%, the rest are trace impurities brought by the raw materials, the basicity of which is CaO / SiO 2 =0.74, the viscosity is 0.45Pa.s. On the basis of the premelted material, 0.45% of carbon black, 0.45% of graphite, 1.3% of borax, 0.7% of CaSi, and 1.2% of manganese ore are added.

[0027] The preparation method of the above-mentioned continuous casting mold flux for ultra-low carbon steel comprises the following steps:

[0028] (1) Pre-melting, prepare the raw materials of mold flux according to a certain proportion, such as wollastonite, quartz sand, bauxite, fluorite, soda ash, borax, magnesia, etc., and mix them in the vertical furnace or electric furnace with water-cooled lining Melting, so that the composition of the slag meets the requir...

Embodiment 2

[0035] A continuous casting mold powder for ultra-low carbon steel, the weight percentage ratio of the premelt chemical composition is: CaO: 34%, SiO 2 : 39%, Al 2 o 3 : 4%, MgO: 3%, F: 5%, Na 2 O: 11%, B 2 o 3 : 2.8%, the rest are trace impurities brought by the raw materials, the basicity of which is CaO / SiO 2 =0.87, the viscosity is 0.25Pa.s. On the basis of the premelt, add 0.4% carbon black, 0.4% graphite, 0.3% borax, 0.3% CaSi, and 3.4% manganese ore.

[0036] The preparation method of the above-mentioned continuous casting mold flux for ultra-low carbon steel comprises the following steps:

[0037] (1) Pre-melting, prepare the raw materials of mold flux according to a certain proportion, such as wollastonite, quartz sand, bauxite, fluorite, soda ash, borax, magnesia, etc., and mix them in the vertical furnace or electric furnace with water-cooled lining Melting, so that the composition of the slag meets the requirements of the above premelt;

[0038] (2) Water q...

Embodiment 3

[0044] A continuous casting mold powder for ultra-low carbon steel, the chemical composition of the premelt is as follows: CaO: 37%, SiO 2 : 36%, Al 2 o 3 : 8%, MgO: 2%, F: 6%, Na 2 O: 7%, B 2 o 3 : 2%, the rest are trace impurities brought by the raw materials, the basicity of which is CaO / SiO 2 =1.03, the viscosity is 0.36Pa.s. On the basis of the premelt, add 0.4% carbon black, 0.3% graphite, 0.8% borax, 0.5% CaSi, and 2.2% manganese ore.

[0045] The preparation method of the above-mentioned continuous casting mold flux for ultra-low carbon steel comprises the following steps:

[0046] (1) Pre-melting, preparing mold slag raw materials in a certain proportion, such as wollastonite, quartz sand, bauxite, fluorite, soda ash, boron-calcium ore, magnesia, etc. Melting in an electric furnace so that the composition of the slag meets the requirements of the above-mentioned premelt;

[0047] (2) Water quenching, the pre-melted slag directly enters the water pool and solid...

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PUM

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Abstract

The invention relates to assistant materials used for continuous casting of steelmaking, in particular to a high speed continuous casting mold flux used for ultra-low-carbon steel, comprising a premelting material and an accessory material. The percentage proportion of chemical components of the premelting material is as follows: 30 to 40 percent of CaO, 35 to 45 percent of SiO2, 3 to 10 percent of Al2O3, 1 to 5 percent of MgO, 4 to 8 percent of F, 6 to 12 percent of Na2, 0.5 to 3 percent of B2O3, and the balance being microimpurity contained in raw materials. The alkalinity, namely CaO / SiO2, of the premelting material is 0.70 to 1.05; the viscosity is 0.2 to 0.5Pa.s; and the premelting material is processed by pre-melting. The accessory material comprises 0.7 to 0.9 percent of simple-substance carbon and 0.25 to 1.5 percent of boron flame retardant, wherein a small part of the boron flame retardant is added in the form of borax and the majority of the boron materials is pre-melted into the premelting material; and the content of B2O3 in the pre-melted slag is 0.5 to 3 percent. The accessory material also comprises 0.2 to 0.8 percent of CaSi powder and 0.8 to 4.0 percent of manganese ore. The high speed continuous casting mold flux not only can effectively reduce the carburetion of the mold flux to molten steel, but also can avoid negative impact on the metallurgical physicochemical property of the mold flux.

Description

technical field [0001] The invention relates to auxiliary materials for steelmaking and continuous casting, in particular to high-speed continuous casting mold slag for ultra-low carbon steel. Background technique [0002] Continuous casting mold flux is a powdery or small granular steelmaking auxiliary material used to cover the surface of molten steel in the mold of a continuous casting machine. It has multiple functions such as thermal insulation, preventing oxidation of molten steel, absorbing inclusions, lubricating and controlling heat transfer. Surface defects such as slag inclusions and cracks occur in the billet, and even cause steel breakout accidents in serious cases. Therefore, mold flux is an important means to ensure the continuous casting process and the surface quality of the slab. [0003] Mold flux is usually made of CaO, SiO 2 Mainly binary system, with external CaF 2 、Na 2 O. Li 2 Flux such as O, and a small amount of Al 2 o 3 , MgO, MnO, FeO and ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B22D11/111C21C7/076
CPCY02P10/20
Inventor 张晨朱祖民蔡得祥
Owner BAOSHAN IRON & STEEL CO LTD
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