Pipes comprising beta-nucleated propylene copolymers
A propylene copolymer and pipe technology, which is used in the preparation of molded products and pipes, can solve problems such as strict requirements and inability to meet pipes and so on.
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[0088] Using commercially available Ziegler-Natta catalyst (MgCl 2 The supported titanium tetrachloride catalyst) polymerizes the propylene-butene copolymer in the monomer suspension.
[0089] The polymerization reaction is continuously performed in the pre-polymerization reactor and the main polymerization reactor. The temperature, pressure, catalyst-, monomer- and hydrogen feed during the polymerization step and the polymer concentration in the main reactor are kept constant. The concentration of hydrogen in the liquid monomer mixture is continuously monitored by gas chromatography analysis. The relevant processing parameters are listed below:
[0090] The first polymerization step was carried out in a small reactor equipped with a stirrer and a cooling system, in which an excess liquid mixture of propylene monomer and 1-butene monomer was prepolymerized at 20°C for 9 minutes. The catalyst components and the cocatalyst triethylaluminum (TEAL) and cyclohexylmethyldimethoxysilane...
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