Method for producing low-salt high-quality soda ash dense

A technology of heavy soda ash and soda ash, which is applied in the manufacturing industry of basic chemical raw material soda ash and the field of preparation of low-salt heavy soda ash, which can solve the problems that the combined soda production method cannot normally produce low-salt heavy soda ash and the large amount of waste liquid discharge, and achieves The effect of good product quality and broad development prospects

Active Publication Date: 2010-06-02
DALIAN RES & DESIGN INST OF CHEM IND
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] The purpose of the present invention is to overcome the shortcomings of the above-mentioned ammonia-soda method to produce low-salt heavy soda ash, which has a large amount of waste liquid discharge, and the combined soda production method cannot normally produce low-salt heavy soda ash, and provides an improved method for producing low-salt heavy soda ash

Method used

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  • Method for producing low-salt high-quality soda ash dense

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Embodiment 1

[0028] The crude brine is refined by the lime-soda ash method, that is, the Ca(OH) 2 Precipitate magnesium with Na 2 CO 3 Precipitates calcium, Mg(OH) 2 and CaCO 3 Precipitation; refined brine absorbs ammonia to make it reach F NH3 102.0tt,T Cl - 90.5tt, F NH3 / Na+ 1.12, the temperature is 38°C, enter the carbonization tower, and the volume fraction of CO entering under the tower is 60% 2 carbonation reaction, the temperature in the middle of the carbonization tower is controlled at 62°C, the take-out temperature is 30°C, and the CO in the carbonization tail gas 2 The volume fraction is 5%. After the resulting sodium bicarbonate suspension is taken out from the lower part of the tower, it is filtered with a vacuum filter and spray washed. The washing water temperature is 40 ° C. The washing water volume per ton of soda ash is 1005 kg. The sodium bicarbonate filter cake base contains salt The amount is 0.145%, sodium bicarbonate is calcined at 170°C in a calciner, the fi...

Embodiment 2

[0032] The crude brine is refined by the lime-soda ash method, that is, the Ca(OH) 2 Precipitate magnesium with Na 2 CO 3 Precipitates calcium, Mg(OH) 2 and CaCO 3 Precipitation; refined brine absorbs ammonia to make it reach F NH3 99.6tt,T Cl - 88.5tt, F NH3 / Na+ 1.125, temperature 35°C, enter the carbonization tower, and the volume fraction of entering the tower is 80% CO 2 carbonation reaction, the temperature in the middle of the carbonization tower is controlled at 64°C, the take-out temperature is 34°C, and the CO in the carbonization tail gas 2 The volume fraction is 7%. After the resulting sodium bicarbonate suspension is taken out from the lower part of the tower, it is filtered with a vacuum filter and spray washed. The washing water temperature is 43°C. The washing water volume per ton of soda ash is 1030kg. The sodium bicarbonate filter cake base contains salt The amount is 0.14%, and the sodium bicarbonate is calcined at 190° C. in a calciner, the firing ra...

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Abstract

The invention provides an improved method for producing low-salt high-quality soda ash dense by taking light soda ash produced by a hot method integrated soda process as a raw material. The low-salt high-quality soda ash dense can be prepared by the following steps of: in the process of producing the light soda ash by using the hot method integrated soda process, controlling the mass fraction of NaCl to be lower than 0.015 percent by adding a washing intermediate product of sodium bicarbonate filter cake so as to enable the mass fraction of light soda ash NaCl to be lower than 0.3 percent; and then producing the low-salt high-quality soda ash dense by taking the low-salt soda ash dense as the raw material and adopting a solid-phase hydration method or extrusion method. The method overcomes the defects that waste liquid of the low-salt soda ash dense produced by an ammonia-soda process has large discharge amount and the low-salt soda ash dense cannot be produced by a united soda production method; the raw material can be crude sea salt and rock salt or can be bittern explored by salt mine solution; in addition, the invention has no water liquid discharge, high quality of product and broad development prospect.

Description

technical field [0001] The invention relates to a method for preparing soda ash. Specifically, it relates to a method for preparing low-salt heavy soda ash with crude brine, and belongs to the industry of soda ash manufacturing, which is a basic chemical raw material. Background technique [0002] The light soda ash produced by industrial synthesis has a density of 0.45-0.79g / cm 3 , the particles are fine, the cost of packaging and storage is high, and the dust is flying when used. Therefore, most of the light soda ash should be processed into heavy soda ash. Heavy soda ash with a bulk density of 0.8g / cm 3 above. In addition, another important quality index to measure heavy soda ash is the salt content. Salt content (referring to NaCl mass fraction, the same below) is low-salt high-quality heavy soda ash if it is lower than 0.3%, and it is ordinary heavy soda ash if it is higher than this value. quality soda ash. When low-salt heavy soda ash is used to make glass, it ca...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01D7/12
Inventor 王金福陈萍
Owner DALIAN RES & DESIGN INST OF CHEM IND
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