Method for producing low-salt high-quality soda ash dense
A technology of heavy soda ash and soda ash, which is applied in the manufacturing industry of basic chemical raw material soda ash and the field of preparation of low-salt heavy soda ash, which can solve the problems that the combined soda production method cannot normally produce low-salt heavy soda ash and the large amount of waste liquid discharge, and achieves The effect of good product quality and broad development prospects
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Embodiment 1
[0028] The crude brine is refined by the lime-soda ash method, that is, the Ca(OH) 2 Precipitate magnesium with Na 2 CO 3 Precipitates calcium, Mg(OH) 2 and CaCO 3 Precipitation; refined brine absorbs ammonia to make it reach F NH3 102.0tt,T Cl - 90.5tt, F NH3 / Na+ 1.12, the temperature is 38°C, enter the carbonization tower, and the volume fraction of CO entering under the tower is 60% 2 carbonation reaction, the temperature in the middle of the carbonization tower is controlled at 62°C, the take-out temperature is 30°C, and the CO in the carbonization tail gas 2 The volume fraction is 5%. After the resulting sodium bicarbonate suspension is taken out from the lower part of the tower, it is filtered with a vacuum filter and spray washed. The washing water temperature is 40 ° C. The washing water volume per ton of soda ash is 1005 kg. The sodium bicarbonate filter cake base contains salt The amount is 0.145%, sodium bicarbonate is calcined at 170°C in a calciner, the fi...
Embodiment 2
[0032] The crude brine is refined by the lime-soda ash method, that is, the Ca(OH) 2 Precipitate magnesium with Na 2 CO 3 Precipitates calcium, Mg(OH) 2 and CaCO 3 Precipitation; refined brine absorbs ammonia to make it reach F NH3 99.6tt,T Cl - 88.5tt, F NH3 / Na+ 1.125, temperature 35°C, enter the carbonization tower, and the volume fraction of entering the tower is 80% CO 2 carbonation reaction, the temperature in the middle of the carbonization tower is controlled at 64°C, the take-out temperature is 34°C, and the CO in the carbonization tail gas 2 The volume fraction is 7%. After the resulting sodium bicarbonate suspension is taken out from the lower part of the tower, it is filtered with a vacuum filter and spray washed. The washing water temperature is 43°C. The washing water volume per ton of soda ash is 1030kg. The sodium bicarbonate filter cake base contains salt The amount is 0.14%, and the sodium bicarbonate is calcined at 190° C. in a calciner, the firing ra...
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