Highly flame-resistant external wall heat preservation material and process for producing same

A technology for external wall insulation and production technology, applied in insulation, building components, etc., can solve problems such as potential safety hazards, and achieve the effects of low smoke density, low free acid, and low smoke density

Inactive Publication Date: 2010-06-23
滕州市华海新型保温材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, insulation materials such as molded polystyrene foam, extruded polystyrene foam and rigid polyurethane foam are widely used in external wall insulation systems in our country, all of which are B2 flammable insulation materials, and there are great safety hazards
Aiming at the fire defects of the existing external wall insulation system, our company has developed a new type of high flame retardant external wall insulation material

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0041] 1. Preparation of modified low-hydroxyl phenolic resin:

[0042] The resole phenolic resin was synthesized under the conditions of alkalinity and methanol as a polymerization inhibitor, and the molar ratio of phenol to formaldehyde was 1:1.6-2.5. Based on the mass of phenol, polyvinyl alcohol accounts for 5-15% of phenol, polyurethane prepolymer containing NCO groups accounts for 1-50% of phenol, active rubber powder accounts for 2-20% of phenol, coupling agent The 10-20mm chopped glass fiber after treatment accounts for 2-10% of phenol.

[0043] Production process of modified low hydroxyl phenolic resin:

[0044] 1. Add acid (such as oxalic acid) to adjust the pH value to 3 to 4 when phenol and all polyvinyl alcohol are mixed evenly, and the reaction temperature is between 80 and 92 degrees, and the reaction is 50 minutes to 65 minutes (preferably 1 hour) after passing water to cool to 40~55 degree (preferably 50 degree).

[0045] 2. After adding all the polyurethan...

Embodiment 1

[0054] Mix phenol and polyvinyl alcohol accounting for 6% by mass of phenol evenly, adjust the pH value to 4 conditions, the reaction temperature is at 85 degrees, and cool to 50 degrees by passing water after reacting for 1 hour, add phenol mass parts (hereinafter the same ) 10% polyurethane prepolymer and then heated up to 80°C, reacted for 1 hour and cooled to 50°C with water. Add sodium hydroxide aqueous solution to adjust the pH value to 9, add all the formaldehyde under the condition, raise the temperature to 88 degrees, react for 3 to 4 hours (preferably 3.5 hours), and stop heating. Add active rubber powder accounting for 2% by mass of phenol, add treated chopped glass fibers accounting for 3% by mass of phenol, add acid to neutralize the pH value to about 7, and then vacuum dehydrate to adjust the viscosity to 25 degrees. 5500mPas, obtain the modified low hydroxyl phenolic resin.

[0055] High flame-retardant exterior wall insulation material (board), based on modifi...

Embodiment 2

[0059] When mixing phenol and 6% polyvinyl alcohol evenly, adjust the pH value to 4. The reaction temperature is 85 degrees. After reacting for 1 hour, pass water and cool to 50 degrees. After the reaction, the temperature was raised to 84 degrees, and after 1 hour of reaction, the water was cooled to 50 degrees. Add sodium hydroxide aqueous solution to adjust the pH value to 9, add all the formaldehyde under the condition, raise the temperature to 89 degrees, react for 3.5 hours, and stop heating. Add active rubber powder accounting for 2% by mass of phenol, add treated chopped glass fibers accounting for 3% by mass of phenol, add acid to neutralize the pH value to about 7, and then vacuum dehydrate to adjust the viscosity to 25 degrees. 5500mPas. A modified low-hydroxyl phenolic resin is obtained.

[0060] Based on modified low-hydroxyl phenolic resin, 100 parts modified water repellent 2 parts, emulsifier "AK8804" 2 parts, emulsifier "Tween 80" 2 parts, foaming agent "HFC...

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Abstract

The invention discloses a highly flame-resistant external wall heat preservation material and a process for producing the same, which are mainly used for the construction of isolation belts and the heat preservation of high-rise buildings and building bodies with relatively higher requirement on fire-protection rating. According to the process, the highly flame-resistant external wall heat preservation material is produced by taking modified phenol aldehyde resin with low hydroxyl content as a raw material and performing low-acid curing on the modified phenol aldehyde resin. The modified phenol aldehyde resin with the low hydroxyl content is prepared by heating phenol, formaldehyde, a modifier and chopped glass fiber firstly under an acidic condition and then under an alkali condition and then performing copolymerization and condensation on the phenol, the formaldehyde, the modifier and the chopped glass fiber. The modified phenol aldehyde resin with the low hydroxyl content, a surfactant, a gas foaming agent, a modified moisture repel and an organic acid catalytic system are cured and molded on a continuous line. The highly flame-resistant external wall heat preservation material has the following advantages that: a terminal hydroxyl group of the adopted phenol aldehyde resin is closed, so the water absorbing capacity of the material is reduced; the cured molding material has high strength and low acidity; the service life of the material is prolonged and simultaneously convenience is provided for construction; the highly flame-resistant external wall heat preservation material has excellent flame resistance, lower smoke density and a higher oxygen index; and fire protecting safety property in a construction and use process is greatly improved due to the non-smoldering property of the highly flame-resistant external wall heat preservation material.

Description

technical field [0001] The invention belongs to the fields of building exterior wall heat preservation and building energy saving, and relates to a high-flame-retardant exterior wall heat preservation material and a production process thereof, which are mainly used for high-rise buildings and building body heat preservation and construction of isolation belts with relatively high fire protection level requirements. Background technique [0002] The popularization and application of external thermal insulation systems for building exterior walls has been developed in my country for more than 10 years. Driven by the national building energy conservation policies and regulations, the external thermal insulation technology independently developed in China has shown a vigorous development trend. Related standards, specifications and construction methods, etc. be continuously improved. Despite this, there are still differences in the development level of external wall thermal insul...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): E04B1/76C08L61/14C08K13/06C08K7/14C08K5/42
Inventor 钟东南孙助海孙志武杨建中张经泽孙浩严来春
Owner 滕州市华海新型保温材料有限公司
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