Application method of carbon black in master batch of conductive fiber and master batch of garment conductive fiber

A technology of conductive fiber and application method, applied in the direction of fibrous filler, conductive/antistatic filament manufacturing, single-component polyolefin artificial filament, etc., can solve the problems of not being suitable for various and beautiful requirements, and achieve cost Low, excellent dispersion of carbon black, good plasticizing effect of resin

Inactive Publication Date: 2010-09-29
SHANDONG TIANYE PLASTICIZATION +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If the amount added is large, the color and quality of the product will be limited. For example, carbon black filled PP conducts electricity, and the conductivity does not change significantly until the filling perce

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] The preparation method is:

[0025] 1. Put the superconducting carbon black (HG-1P) in a closed container for continuous treatment, spray it on the carbon after spraying it with the coupling agent solution of the present invention while heat treatment (55 ° C ~ 65 ° C) The black surface is modified, the rotation speed of the mixer is 20-30r / min, and the atomization treatment is carried out for 0.5-1.0 hours to obtain the modified superconducting nano-carbon black. The coupling agent is composed of 50wt% composite monoalkoxy titanate LD27 and 50wt% pyrophosphate titanate NDZ-101. The dosage of the coupling agent is 3% of the total amount of superconducting carbon black, the diluent of the coupling agent solution is liquid paraffin, and the mass ratio of the coupling agent to the coupling agent is 1:1.

[0026] 2. Knead 14% POE + 33% TPU + 53% EPDM modified resin to obtain compound modified resin.

[0027] 3. Composition and ratio of masterbatch: in terms of mass percen...

Embodiment 2

[0034] 1. Put the superconducting carbon black (HG-1P) in a closed container for continuous treatment, spray it on the carbon black after spraying it with the coupling agent solution of the present invention while heat treatment (55°C-65°C). The black surface is modified, the rotation speed of the mixer is 20-30r / min, and the atomization treatment is carried out for 0.5-1.0 hours to obtain the modified superconducting nano-carbon black. The coupling agent is composed of 50wt% composite monoalkoxy titanate LD27 and 50wt% pyrophosphate titanate NDZ-101. The dosage of the coupling agent is 5% of the total amount of the superconducting carbon black, the diluent of the coupling agent solution is liquid paraffin, and the mass ratio of the coupling agent to the coupling agent is 1:1.

[0035] 2. Knead 14% POE + 33% TPU + 53% EPDM modified resin to obtain compound modified resin.

[0036] 3. Composition and ratio of masterbatch: in terms of mass percentage, carrier resin (80% LLDPE+2...

Embodiment 3

[0044] Take 77 parts of polypropylene resin and 23 parts of conductive fiber masterbatch (prepared in Example 1), and knead them in a kneader for 10 minutes. Then extrusion spinning is carried out to obtain polypropylene fiber. Take the fiber silk sample and test it, the conductivity of the fiber is: 1×10 5 Ω·cm, meeting the requirements of conductive fibers.

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PUM

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Abstract

The invention discloses an application method of carbon black in the master batch of a conductive fiber, which comprises the following steps: carrying out surface modification on the carbon black, kneading the carbon black with other raw materials for preparing the master batch and granulating to obtain the master batch, and the method for surface modification of the carbon black comprises the steps of atomizing the coupling agent for superconductive carbon black and spraying on the surface of the carbon black for modifying. The master batch of the garment conductive fiber prepared from the modified superconductive carbon black of the invention comprises the following components in mass percent: 44.5% of carrier resin, 12% of composite modified resin, 35% of modified superconductive nano carbon black, 3.5% of lubricant, 1.0% of antioxidant and 4.0% of dispersant. By modifying the superconductive carbon black, compared with the traditional carbon black, the conductivity is improved by more than one time, and the prepared conductive master batch has the advantage of preparing various conductive fibers.

Description

technical field [0001] The invention relates to an application method of carbon black as a conductive agent in a conductive fiber masterbatch, and provides a clothing conductive fiber masterbatch using the modified conductive agent carbon black as a conductive agent. Background technique [0002] Everyday people's clothing is prone to static electricity due to friction and collision phenomena, and there is often a "popping" discharge sound. If this phenomenon is not eliminated in time in certain occasions, such as coal mines, electronics, printing, packaging, etc., it is easy to cause static electricity accidents, which has become one of the major hidden dangers of safety production in the above-mentioned fields. The main methods to prevent static electricity on the surface of polymers are: air ionization method, humidification method, metal contact discharge method, radiation method, conductive substance introduction method, surface moisture absorption film method, chemical...

Claims

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Application Information

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IPC IPC(8): C08L23/06C08K9/04C09C1/56C09C3/08D01F1/09D01F6/46
Inventor 付宇经张宝善
Owner SHANDONG TIANYE PLASTICIZATION
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