Alkali-free glass for flat-panel display and founding process thereof
A technology of flat panel display and alkali-free glass, which is applied in the fields of boroaluminosilicate glass and alkali-free boroaluminosilicate glass. Yield rate and other issues to achieve the effect of reducing deformation
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[0038] The alkali-free glass of the present invention is made of SiO 2 、B 2 o 3 and Al 2 o 3 The formed glass network structure, in which SiO 2 +Al 2 o 3 +B 2 o 3 ≥80%, ∑RO (R is Mg, Ca, Sr, Ba, Zn) / Al 2 o 3 It is 0.9-1.2 (mass ratio). Among them, Si is the main component forming the glass network, Al 3+ When there is free oxygen supplied by RO, it can be [AlO 4 ] tetrahedra into the glass network, due to the Si 4+ is tetravalent, Al 3+ is trivalent, Al 3+ Replace Si 4+ After the electricity price is unbalanced, it is necessary to attract metal ions to occupy the network voids, which increases the integrity and strength of the network, thus increasing the viscosity and softening point of the glass.
[0039] General intermediate ions enter the network roughly in the following order when free oxygen is insufficient [BeO 4 ]→[AlO 4 ]→[GaO 4 ]→[BO 4 ]→[TiO 4 ]→[ZnO 4 ]. So when ΣRO (R is Mg, Ca, Sr, Ba, Be, Zn) / Al 2 o 3 0.9-1.2, satisfying Al first 3+ req...
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