Processing method of shale oil

A processing method and technology for shale oil, which are applied in the petroleum industry, refining hydrocarbon oil, and multi-stage series refining process treatment, etc., can solve the problems of single product, complex process, high hydrogen consumption and operating cost

Inactive Publication Date: 2013-08-21
抚顺欧力石化有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this process needs to be carried out under high temperature, high pressure and catalyst conditions. The reaction conditions are harsh, the process is complex, the hydrogen consumption and operating costs are high, and it is not easy to realize due to the limitation of hydrogen source supply.
At the same time, the product is relatively single, and non-hydrocarbon compounds containing S, N, O, etc. cannot be fully utilized, resulting in a waste of resources

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Example 1: Take 40kg of Jilin Huadian shale oil and 40kg of N-methylpyrrolidone extractant, put them into an extraction and separation apparatus and mix them, heat up to 25°C, and start stirring to make the shale oil and N-methylpyrrolidone extractant fully Mixed contacts. Stirring was stopped after 30 minutes, the extract phase and the raffinate phase were allowed to stand for 30 minutes to separate layers, and the extract phase was released from the discharge port to separate the extract phase from the raffinate phase. The extract phase and the raffinate phase are distilled separately to obtain extract oil, raffinate oil and N-methylpyrrolidone extractant respectively, and the obtained extractant is recovered.

[0015] The extracted oil was separated by distillation under reduced pressure to obtain 8% light components and 92% heavy components by weight respectively. It has been determined that the index of the heavy component can meet the standard of heavy traffic as...

Embodiment 2

[0016] Example 2: Take 40 kg of Fushun shale oil and 10 kg of furfural extractant, put them into an extraction separator and mix them, raise the temperature to 60° C., start stirring, so that the shale oil and furfural extractant are fully mixed and contacted. After 60 minutes, the stirring was stopped, and the extract phase and the raffinate phase were left to stand for 60 minutes, and the extract phase was released from the discharge port to separate the extract phase and the raffinate phase. The extraction phase and raffinate phase are distilled separately to obtain extracted oil, raffinate oil and furfural extractant respectively, and the obtained extractant is recovered.

[0017] The extracted oil was separated by distillation under reduced pressure to obtain 6% light components and 94% heavy components by weight respectively. It has been determined that the index of the heavy component can meet the standard of heavy traffic asphalt (GB / T 15180-2000) AH-70, and can be mad...

Embodiment 3

[0018] Example 3: Take 60 kg of Jilin Huadian shale oil and 10 kg of N-methylpyrrolidone extractant, put them into an extraction and separation apparatus for mixing, heat up to 85° C., and start stirring to make the shale oil and N-methylpyrrolidone extractant fully Mixed contacts. Stirring was stopped after 120 minutes, the extract phase and the raffinate phase were allowed to stand for 120 minutes to separate layers, and the extract phase was released from the discharge port to separate the extract phase and the raffinate phase. The extract phase and the raffinate phase are distilled separately to obtain extract oil, raffinate oil and N-methylpyrrolidone extractant respectively, and the obtained extractant is recovered.

[0019] The extracted oil was separated by vacuum distillation to obtain 5% light components and 95% heavy components by weight respectively. It has been determined that the heavy component is close to the 60# road petroleum asphalt index (SH / T 0522-2000), ...

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PUM

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Abstract

The invention discloses a processing method of shale oil, which comprises the following steps: after mixing shale oil and an extracting agent, heating up, and starting to stir so that the shale oil and the extracting agent are thoroughly mixed and are thoroughly in contact with each other; stopping stirring, standing so that the extract phase and the raffinate phase stratify, and separating the extract phase and the raffinate phase; and respectively distilling the extract phase and the raffinate phase to respectively obtain extract oil and the extracting agent, and raffinate oil and the extracting agent, and recovering the extracting agent. The method disclosed by the invention is simple and easy to operate, and the reaction conditions are mild; and the method can be carried out under theconditions of atmospheric pressure and low temperature, does not need the participation of the catalyst, and thus, has the advantages of low input cost and obvious economic benefit. Meanwhile, the method can be used for generating multiple products, such as extract oil composed of light and heavy components respectively for preparing non-hydrocarbon compounds and asphalt products, and raffinate oil which can be directly used as the raw material for catalytic cracking, thereby increasing the added value of the products. The heavy component of the extract oil has the advantages of low viscosity, high plasticity and high temperature sensibility, and can be blended into asphalt of different designations to satisfy the demands for different purposes.

Description

1. Technical field [0001] The invention belongs to the technical field of shale oil processing, and in particular relates to a shale oil processing method. 2. Background technology [0002] Shale oil is a very rich potential energy source in the world. Its total reserves greatly exceed that of petroleum. It was used as fuel as early as 800-1000 years ago. The development of shale oil reached its peak in the 1930s and 1940s. However, since the 1950s, due to the supply of high-quality oil, the development of the shale oil industry has temporarily stopped. Until the energy crisis at the end of the 1970s, people re-emphasized the research and development of shale oil and used modern scientific methods to carry out research and development of shale oil. In-depth analysis provides a basis for the utilization and deep processing of shale oil. Shale oil is a mixture of various organic compounds obtained by thermally decomposing organic matter in kerogen shale through low-temperatur...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G53/04C10G21/20C10G21/22C10G21/16
Inventor 曹祖斌韩冬云赵荣祥曹群石薇薇马海燕李广欣翟学研袁萌萌陈海丽
Owner 抚顺欧力石化有限公司
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