Method for quantitatively detecting trace rhodamine 6G

A quantitative detection and trace technology, applied in the field of SERS detection, can solve problems such as detection that cannot be traced quantitatively, and achieve high stability, high repeatability, uniform diameter and length.

Inactive Publication Date: 2011-06-29
INST OF SEMICONDUCTORS - CHINESE ACAD OF SCI
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Benefits of technology

Inventions described in this patents have several technical benefits over existing methods such as those mentioned earlier. These improvements include improved accuracy, reproducible results, stable storage time, etc., resulting from controlling the sizes and shapes of particles or elements within an opaque material called gold nanoparallels (NGP). By adjusting these dimensions, we found out how well metal NPGs absorb light near certain frequencies while also forming heatspikes. Additionally, our proposed technology uses uniformly distributed AuNPs instead of regular ones like AgNWs, making them more effective than previously known alternatives. Overall, these new technologies improve the efficiency and effectiveness of chemical analysis techniques.

Problems solved by technology

This patents describes different methods for improving the performance of optically excited surfaces (SES) based upon their ability to generate strong signals from small particles attached onto them. One method involves adding certain substance like ruthenium oxide into the SES itself during fabrication process. Another approach suggests modifying the structure of the metallic elec trode through various techniques including lithography, deposition, coating, etching, etc., resulting in improved sensors having higher levels of specificity than previously possible without sacrificially damaging the device's components themselves.

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  • Method for quantitatively detecting trace rhodamine 6G
  • Method for quantitatively detecting trace rhodamine 6G
  • Method for quantitatively detecting trace rhodamine 6G

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[0033] The following is an example of using the method provided by the present invention to quantitatively detect rhodamine 6G at an ultra-low concentration in a solution.

[0034] First, an AAO template 10 with a pore diameter of 50 nm is prepared for use. Then, add 0.05mol / L silver nitrate and 30g / L boric acid into 200ml deionized water to make an electrolyte solution, and deposit the silver nanowire array 20 in the AAO template 10 under the AC voltage of 17.8V and 50HZ, The deposition time is 120 seconds, and then the deposited AAO template 10 is washed repeatedly with deionized water. The aluminum layer on the back of the deposited AAO template 10 was removed with a supersaturated solution of copper chloride perchlorate, and then the back was immersed in a phosphoric acid solution with a mass fraction of 5% for 90 minutes to remove the barrier layer. Afterwards, it was immersed in deionized water at 60° C. for 30 minutes to remove impurity ions on the surface of the silve...

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Abstract

The invention relates to a method for quantitatively detecting trace rhodamine 6G by using a Raman spectrometer, which comprises the following steps of: preparing a plurality of silver nanowire arrays by an alternating current chemical deposition method, namely depositing silver nanowires in holes of an anodic aluminum oxide (AAO) template in a domain limiting mode by using mixed aqueous solution of silver nitrate and boric acid as electrolyte to form the silver nanowire arrays; preparing silver nanoparticles, mixing with rhodamine 6G solution at different concentration respectively, and dripping on the prepared silver nanowire arrays respectively to form a surface enhanced Raman spectroscopy (SERS) enhanced sandwich system; after the sandwich system is naturally dried, performing a Raman spectrum test on the dried sandwich system on the Raman spectrometer to obtain the SERS spectra of the rhodamine 6G solution at the different concentration; calculating the characteristic peak intensity of the SERS spectra of the rhodamine 6G solution at the different concentration to obtain an SERS intensity-concentration relation curve of the rhodamine 6G solution, wherein the curve is taken as a basis of quantitatively detecting the rhodamine 6G; and contrasting the SERS intensity of the rhodamine 6G solution at unknown concentration with the SERS intensity-concentration relation curve of the rhodamine 6G to obtain the concentration of the rhodamine 6G solution.

Description

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Claims

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Application Information

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Owner INST OF SEMICONDUCTORS - CHINESE ACAD OF SCI
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