Conductive polymeric material, manufacturing method thereof, and capacitor comprising same
A conductive polymer and capacitor technology, applied in the field of capacitors, can solve the problems of poor frequency adaptability of plug-in capacitors, and achieve the effects of strong voltage resistance, low ESR and high breakdown voltage
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[0030] In a typical implementation of the present invention, a preparation method of a conductive polymer material is provided, the preparation method includes the following steps: comprising the first monomer having the structural formula (1), the first monomer having the structural formula (2) The second monomer, the monomer mixed solution of the third monomer having the structural formula (3) and the oxidizing agent solution are uniformly mixed, and reacted at a temperature of 20° C. to 180° C. for 45 minutes to 5 hours to prepare a conductive polymer material.
[0031]
[0032] Wherein, R is an alkane group. Further, R is preferably methyl, ethyl or propyl.
[0033] Wherein, the molecular formula of the first monomer is C 6 h 6 OS 2 , is thieno[3,4-b]-1,1-oxo-4-sulfonylmethylsulfonylmethane-cyclopentane sulfide, the molecular formula of the second monomer is C 7 h 8 o 3 Thieno[3,4-b]-1,4-dioxin-2-methanol (EDT-methanol) of S. When R in the third monomer is ethyl,...
Embodiment 1
[0063] Raw materials: 5g of the first monomer, 40g of the second monomer, 55g of the third monomer (R is ethyl), 400g of iron p-toluenesulfonate.
[0064] Production method: prepare the first monomer, the second monomer, the third monomer and the volatile solvent into a monomer mixed solution with a concentration of 30%, and prepare the oxidizing agent (iron p-toluenesulfonate) and the volatile solvent The oxidant solution with a concentration of 60% is uniformly mixed with the monomer mixed solution and the oxidant solution, and reacted for 5 hours at a temperature of 20° C. to obtain a conductive polymer material; and the conductive polymer material is used to make an aluminum solid conductive high molecular capacitor. The volatile solvent is methanol-ethanol mixed liquid, wherein the methanol content is 40%.
Embodiment 2
[0066] Raw materials: 40g of the first monomer, 5g of the second monomer, 55g of the third monomer (R is ethyl), 1000g of iron p-toluenesulfonate.
[0067]Production method: prepare the first monomer, the second monomer, the third monomer and the volatile solvent into a monomer mixed solution with a concentration of 60%, and prepare the oxidant p-toluenesulfonate iron and the volatile solvent to a concentration of 40% oxidant solution, mix the monomer mixed solution and the oxidant solution evenly, react at 180°C for 45 minutes to prepare a conductive polymer material; use the conductive polymer material to make aluminum solid conductive polymer capacitors. The volatile solvent is methanol-ethanol mixed liquid, wherein the methanol content is 60%.
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