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Novel multifunctional electrolyte

An electrolyte, multi-functional technology, applied in the field of electrolyte, can solve the problem of not taking into account the performance, etc., achieve the effect of high conductivity, low viscosity, and improve production efficiency

Inactive Publication Date: 2012-01-11
HUNAN UNIV
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  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These patents often only improve a certain performance of the battery, while other performances are not taken into account

Method used

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Embodiment Construction

[0035] 1. Two organic solvents, dimethyl carbonate DMC and ethylene carbonate EC, were taken at a volume ratio of 2:1, mixed fully and evenly in a glove box with a humidity of less than 1%, and prepared as electrolyte solvents. The functional compound vinylene carbonate VC and trimethyl phosphate are added in a weight ratio of 10%. The content ratio of the two types of compounds is 2:1. Add electrolyte lithium salt with a total amount of 1 mol / L in portions, and stir properly to fully dissolve it. Set aside for 12h to prepare the electrolyte.

[0036] 2. According to the volume ratio of 2:1, take two organic solvents, ethyl methyl carbonate EMC and ethylene carbonate EC, and mix them well and evenly in a glove box with a humidity of less than 1%, and configure them as electrolyte solvents. The functional compounds propylene sulfite PS and triethyl phosphate were added in a weight ratio of 10%. The content ratio of the two types of compounds is 3:1. Add electrolyte lithium ...

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Abstract

Provided is a novel multifunctional electrolyte which comprises lithium salts, a novel cosolvent and a functional compound. The novel cosolvent comprises line style carbonic ester and annular carbonic ester, wherein, line style carbonic ester with a low melting point and low viscosity accounts for the majority of the novel cosolvent, and the novel cosolvent is enabled to perform good charge and discharge performance at low temperature by compounding line style carbonic ester and annular carbonic ester according to an optimized ratio. The functional compound is obtained by mixing compounds A and compounds B, wherein, compounds A have a good film forming characteristic and maintain stable at high temperature, which enables cycle performance of a battery to be effectively improved, pneumatic swelling of the battery to be avoided and high temperature performance of the battery to be enhanced, and compounds B are phosphate ester compounds with a low melting point, which enables low temperature performance of the battery to be further enhanced on the one hand and safety performance of the battery to be substantially improved on the other hand thanks to the flame retardation characteristic of phosphate ester compounds. Through component and ratio optimization, the problems of low temperature performance, high temperature performance, safety performance, cycle performance and pneumatic swelling of the electrolyte are well solved simultaneously.

Description

technical background [0001] The invention relates to the technical field of lithium ion batteries, in particular to a novel multifunctional electrolyte suitable for lithium ion batteries technical background [0002] In the context of energy crisis, resource scarcity, and environmental pollution, lithium-ion batteries are widely used in various fields such as communications, digital, transportation, and aerospace due to their high operating voltage, long cycle life, high energy density, and environmental protection. become the trend of new energy development. [0003] However, lithium-ion batteries have a narrow operating temperature range, poor discharge performance at low and high temperatures, and even safety hazards at high temperatures. These have become bottlenecks for the further development of lithium-ion batteries. [0004] The high and low temperature performance of lithium batteries is mainly determined by the electrolyte. As an important part of the battery, th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/056
CPCY02E60/10
Inventor 王太宏黄睿陈立宝罗雨王耀玲胡悦丽
Owner HUNAN UNIV
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