Method for preparing catalytic cracking catalyst

A catalytic cracking and catalyst technology, applied in catalytic cracking, physical/chemical process catalysts, molecular sieve catalysts, etc., can solve the problems of high catalyst compensation rate and high catalyst operation cost, and achieve improved wear performance, excellent catalytic performance and anti-wear performance , the effect of reducing the volume load

Inactive Publication Date: 2012-01-18
常云峰 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

These small particles may be carried out of the reactor as catalyst powder and dust. In order to maintain the activity of the whole system (to compensate for the loss of catalyst and the decline in activity), fresh catalyst must be added, or the so-called catalyst compensation, due to catalyst cracking The higher the catalyst loss and the higher the catalyst compensation rate, the higher the operating cost of the catalyst will naturally be. In addition to the cost factor, the formation of a large amount of catalyst fines can lead to the release of dust into the air to an unacceptable level

Method used

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  • Method for preparing catalytic cracking catalyst
  • Method for preparing catalytic cracking catalyst
  • Method for preparing catalytic cracking catalyst

Examples

Experimental program
Comparison scheme
Effect test

example 1( comparative Embodiment

[0044] Example 1 (comparative example): preparation of a slurry with a solids content of 35%:

[0045] (1) Add 4.15 kilograms of USY molecular sieves (loss on ignition is 7.6%) produced by China Qingdao Shida Excellent Catalyst Co., Ltd. to 17.94 kilograms of distilled water, and use a saw blade mixer to stir at 200 rpm;

[0046] (2) Add 5 kilograms of aluminum chloride solution (loss on ignition is 74.54%) produced by China Qingdao Shida Excellent Catalyst Co., Ltd.;

[0047] (3) 1.97 kg of alumina (loss on ignition: 2.5%) produced by Shandong Aluminum Corporation of China was added.

[0048] (4) Then 7.40 kg of kaolin (loss on ignition 22.14%) produced by China Kaolin Company in Suzhou City, Jiangsu Province, China was added.

[0049] The resulting mixture contained 30 wt.% molecular sieve of type USY, 10 wt.% binder, 15 wt.% alumina and 45 wt.% kaolin. The slurry is ground by a ball mill. The spray drying equipment produced by Changzhou Qunli Drying Equipment Co., Ltd., ...

example 2

[0052] Example 2 (invention): A slurry with a solids content of 44.3 wt.% was prepared by the following steps:

[0053] (1) Weigh out 2347 grams of distilled water;

[0054] (2) While adding 3005 grams of concentrated aluminum chloride solution (loss on ignition: 76.04%) provided by China Qingdao Shida Excellence Technology Co., Ltd., stir at a speed of 500 rpm with a stirring device. The slurry has a pH of 2.6 at 29°C;

[0055] (3) In the state of stirring, add 2105 grams to the slurry in step (2) and be the LISY-2Y type molecular sieve that the loss on ignition of 14.5wt.% is produced by China Qingdao Shida Excellence Technology Co., Ltd., thus The resulting slurry has a pH of 3.1 at 31°C;

[0056] (4) Under stirring, 2343 grams of kaolin with a loss on ignition of 22.14% produced by China Kaolin Company in Suzhou City, Jiangsu Province, China was added, and the resulting slurry had a pH value of 3.1 at 30 degrees Celsius.

[0057] The slurry was stirred at 6000 rpm for 1...

example 3

[0062] Example 3: (Invention) A slurry with 44.6 wt.% solids content was prepared by the following steps:

[0063] (1) Weigh out 2493 grams of distilled water;

[0064] (2) In the state of stirring, add 2858 grams of concentrated aluminum chloride solution (loss on ignition: 74.81%) produced by Shanghai Dongman Chemical Co., Ltd. to 2493 grams of distilled water and mix well. The resulting slurry had a pH of 3.1 at 30°C.

[0065] (3) Add 2105 grams of LISY-2Y molecular sieve produced by China Qingdao Shida Excellence Technology Co., Ltd. to the above slurry. At 31°C, the zeolite was easily disintegrated and dispersed into a slurry with a pH of 3.3.

[0066] (4) Add 2543 grams of kaolin produced by China Kaolin Company in Suzhou, China. The slurry after high shear treatment and before media milling was referred to as water slurry SL-3. Its viscosity and pH measurements are listed in Table 2.

[0067] Same as in Example 2, the viscosity of the slurry was measured using a Br...

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Abstract

The invention relates to a method for preparing a catalytic cracking catalyst, which comprises the following steps: (1) weighting zeolite, a binder precursor, a substrate precursor and a pulpable intermediate; (2) forming a solid-liquid slurry containing the zeolite, the binder precursor, the substrate and the pulpable intermediate; (3) stirring and/or grinding the slurry, performing a uniform mixing and uniformization to the above components to realize the refinement of particle size; (4) converting catalyst slurry into molded particles, and converting the molded catalyst particles into a catalyst finished product by drying or calcinating. The solid content in the catalyst formula is 30%-65%, the addition of the solid content enables a great addition to the apparent density of the catalyst, the addition of the catalyst bulk density enables a close association with the enhancement of the wearing performance, accordingly, the addition of the catalyst bulk density is capable of reducing the volume load of the catalyst or filling more catalyst in a given volume of a reactor.

Description

technical field [0001] The invention belongs to the field of catalysts, in particular to a method for preparing a catalytic cracking catalyst. Background technique [0002] Beginning in 1990, economic growth in Asia boosted gasoline demand, especially in China. Known as the technology behind gasoline production, catalytic cracking is a catalytic process that uses microsphere catalysts to convert petroleum fractions into cracked gasoline. A key role of the microsphere catalyst is to convert the macromolecules of hydrocarbons into higher octane C 4 -C 10 , the activity of this catalyst is high during the conversion process, this function is mainly provided by the acid sites, in order to have high activity, high acid site density and strong acid sites are necessary. However, the combination of high acid site density and strong acid sites often causes serious coking and shortens the service life of the catalyst. In order to maintain the activity of the catalyst, coking (remo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J29/08C10G11/05
Inventor 常云峰杨芳晓周泽奇
Owner 常云峰
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