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Zirconium microalloyed weldable aluminum-zinc-magnesium alloy with high purity, high-strength and corrosion resistance

A micro-alloying, aluminum-zinc-magnesium technology, which is applied in the field of high-purity, high-strength, corrosion-resistant, weldable aluminum-zinc-magnesium alloys and its preparation, can solve the problems of high strength, high corrosion resistance, and high weldability, etc. Corrosion resistance and welding performance, high corrosion resistance, high strength effect

Inactive Publication Date: 2012-04-11
725TH RES INST OF CHINA SHIPBUILDING INDAL CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] The technical problem to be solved by the present invention is to provide a zirconium microalloyed high-purity, high-strength, corrosion-resistant, weldable aluminum-zinc-magnesium alloy and its preparation method, aiming at the high strength, high corrosion resistance, high It is difficult to take into account the problem of weldability. Combining the composition characteristics of the new 7000 series aluminum alloy and 7A19 aluminum alloy, the comprehensive performance of the 7000 series aluminum alloy is improved by adding trace element zirconium, so as to meet the requirements of some high-strength modern marine structural parts in my country. Requirements for the use of high-strength and corrosion-resistant weldable aluminum-zinc-magnesium aluminum alloys

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Embodiment one: the A-1 alloy in table 1 is prepared by ingot metallurgy.

[0027] Add high-purity aluminum to graphite clay crucible and melt it in a resistance crucible furnace at a melting temperature of 750°C. After the high-purity aluminum is melted, add Al-Cr, Al-Mn, Al-Cu, Al-Zr, Al-Be in the middle Alloy, the temperature is lowered to 700°C, press industrial pure Mg with a bell jar, add industrial pure Zn after melting, and after all the intermediate alloys and metals are melted, the temperature rises to 740°C and uses 0.2%~0.4% hexachloroethane C 2 Cl 6 (briquetting) Refining and degassing, removing slag, standing still for 10-15 minutes, pouring into water-cooled iron mold, demoulding after cooling. The aluminum alloy melted and cast into an ingot is annealed at 410~425℃×24h, hot rolled at 460℃~315℃, and then solution treated. The solution treatment system is as follows: after heating to 510~520℃ and holding for 25~60min, Slowly cool down to 450~460°C at a c...

Embodiment 2

[0029] Example 2: The alloy A-2 in Table 1 was prepared by ingot metallurgy.

[0030] Add high-purity aluminum to the graphite clay crucible and melt it in a resistance crucible furnace at a melting temperature of 760°C. After the high-purity aluminum is melted, add Al-Cr, Al-Mn, Al-Cu, Al-Zr, Al-Be in the middle Alloy, the temperature is lowered to 685°C, press the industrial pure Mg with a bell jar, add industrial pure Zn after melting, and after all the intermediate alloys and metals are melted, the temperature rises to 745°C and uses 0.2%~0.4% hexachloroethane C 2 Cl 6 Refining and degassing, removing slag, standing still for 10-15 minutes, pouring into water-cooled iron mold, demoulding after cooling. The aluminum alloy melted and cast into an ingot is annealed at 415~425℃×20h, hot rolled at 460℃~315℃, and then solution treated. The solution treatment system is as follows: after heating to 510~520℃ and holding for 25~60min, Slowly cool down to 450~460°C at a cooling rat...

Embodiment 3

[0032] Example 3: Alloy A-3 in Table 1 was prepared by ingot metallurgy.

[0033] Add high-purity aluminum to the graphite clay crucible and melt it in a resistance crucible furnace at a melting temperature of 775°C. After the high-purity aluminum is melted, add Al-Cr, Al-Mn, Al-Cu, Al-Zr, Al-Be in the middle Alloy, the temperature is lowered to 686°C, press the industrial pure Mg with a bell jar, add industrial pure Zn after melting, and after all the intermediate alloys and metals are melted, the temperature rises to 737°C and uses 0.2%~0.4% C 2 Cl 6 (briquetting) Refining and degassing, removing slag, standing still for 10-20 minutes, pouring into water-cooled iron mold, demoulding after cooling. The aluminum alloy melted and cast into an ingot is annealed at 415~425℃×26h, hot rolled at 460℃~315℃, and then solution treated. The solution treatment system is as follows: after heating to 510~520℃ and holding for 25~60min, Slowly cool down to 450~460°C at a cooling rate of 0....

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Abstract

The invention provides a zirconium microalloyed weldable aluminum-zinc-magnesium alloy with high purity, high-strength and corrosion resistance, which comprises the following components: 5.2-6.0% of Zn, 2.0-3.1% of Mg, 0.15-0.22% of Zr, 0.10-0.20% of Mn, 0.8-2.0% of Cu, 0.18-0.28% of Cr, 0.0001-0.005% of Be, less than or equal to 0.10% of Ti, less than or equal to 0.15% of Fe, less than or equal to 0.15% of Si and the balance of Al. The preparation method comprises the following steps: adding high purity aluminum in graphite crucible, melting in a resistor crucible furnace, fusing aluminum and adding an intermediate alloy, pressing industrial pure Mg, fusing and adding Zn, fully fusing to the temperature of 730-750 DEG C for refining and removing gas, slagging, standing and filling in a water-cooled iron die, cooling and demoulding, post-treating to obtain the product. According to the alloy of the present invention, the tensile strength is greater than or equal to 525MPa, the yield strength is greater than or equal to 455MPa, the anti-stripping corrosion performance is not less than EA grade, the stress corrosion life is not less than 90d, and the welding crack resistance of the alloy of the invention is equal to that of a 7A19 aluminum alloy.

Description

technical field [0001] The invention relates to an aluminum alloy and a preparation method thereof, in particular to a zirconium microalloyed high-purity, high-strength, corrosion-resistant, weldable aluminum-zinc-magnesium alloy and a preparation method thereof. Background technique [0002] At present, some modern marine structural parts need to use 7000 series high-strength corrosion-resistant weldable aluminum alloys. However, my country currently only has medium-strength corrosion-resistant and weldable 7000-series aluminum alloys, which cannot meet the needs of some modern marine structural parts. 7000 series aluminum alloy is a key structural material for some marine structural parts. The United States has used high-strength, corrosion-resistant and weldable 7000-series aluminum alloys for modern marine structural parts. The tensile strength of the alloy is above 525MPa, and the yield strength is above 455MPa. However, so far, my country has not yet had a high-stren...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C21/10C22C1/03C22F1/053
Inventor 王月刘国元金建新
Owner 725TH RES INST OF CHINA SHIPBUILDING INDAL CORP