A kind of quaternary ammonium salt type hyperbranched anion exchange resin and preparation method thereof
A technology of exchanging resin and anion, applied in the field of polymer, can solve the problem that resin has not been reported, and achieve the effect of large pore size and large specific surface area.
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0065] Embodiment 1 contains the ion exchange resin of second generation hyperbranched polymer
[0066] Porous ceramic particles pretreatment, first soak porous ceramic particles with 1 mol / L NaOH solution for 3 hours, then rinse sodium hydroxide with secondary deionized water and methanol to treat porous ceramic particles, and finally dry the treated porous ceramic particles The porous ceramic particles were soaked in a toluene solution of 10% γ-glycidyl etheroxypropyltrimethoxysilane, and reacted in a reaction kettle at 110°C for 40min. Finally, rinse with toluene and methanol for 10 min each to obtain silanized porous ceramic particles.
[0067] Using a reactor with a stirrer and a nitrogen inlet, take 1.34 kg of trimethylolpropane and 20 L of anhydrous dichloromethane into the reactor, and take the monomer 3-methyl-3-hydroxymethyloxetane 9.18 kg was dissolved in 50 L of anhydrous dichloromethane and poured into the reaction apparatus. Then repeatedly vacuumize and pass ...
Embodiment 2
[0068] Embodiment 2 contains the ion exchange resin of three generations of hyperbranched polymers
[0069] Porous ceramic particles pretreatment, first soak porous ceramic particles with 1 mol / L NaOH solution for 3 hours, then rinse sodium hydroxide with secondary deionized water and methanol to treat porous ceramic particles, and finally dry the treated porous ceramic particles The porous ceramic particles were soaked in a toluene solution of 10% γ-glycidyl etheroxypropyltrimethoxysilane, and reacted in a reaction kettle at 110°C for 40min. Finally, rinse with toluene and methanol for 10 min each to obtain silanized porous ceramic particles.
[0070] Use a reactor with a stirrer and a nitrogen inlet, take 0.67 kg of trimethylolpropane, add 20 L of anhydrous dichloromethane into the reactor, and take the monomer 3-methyl-3-hydroxymethyloxetane 10.71 kg was dissolved in 50 L of anhydrous dichloromethane and poured into the reaction apparatus. Then repeatedly vacuumize and ...
Embodiment 3
[0071] Embodiment 3 contains the ion exchange resin of four generations of hyperbranched polymers
[0072] Porous ceramic particles pretreatment, first soak porous ceramic particles with 1 mol / L NaOH solution for 3 hours, then rinse sodium hydroxide with secondary deionized water and methanol to treat porous ceramic particles, and finally dry the treated porous ceramic particles The porous ceramic particles were soaked in a toluene solution of 10% γ-glycidyl etheroxypropyltrimethoxysilane, and reacted in a reaction kettle at 110°C for 40min. Finally, rinse with toluene and methanol for 10 min each to obtain silanized porous ceramic particles.
[0073] Use a reactor with a stirrer and a nitrogen inlet, take 0.27 kg trimethylolpropane, add 20 L of anhydrous dichloromethane into the reactor, and take the monomer 3-methyl-3-hydroxymethyloxetane 9.18 kg was dissolved in 50 L of anhydrous dichloromethane and poured into the reaction apparatus. Then repeatedly vacuumize and pass ...
PUM
| Property | Measurement | Unit |
|---|---|---|
| particle diameter | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More