Polyorganosiloxane, encapsulation material obtained from the polyorganosiloxane, and electronic device including the encapsulation material
A technology of polyorganosiloxane and electronic devices, which is applied in the direction of electric solid devices, electrical components, semiconductor devices, etc., and can solve problems such as poor processability and easily damaged interface adhesion of polyorganosiloxane
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[0130] Synthesis of the first polyorganosiloxane
[0131] Synthesis Example 1
[0132] Add 158.65g (1.2mol) of dicyclopentadiene into a five-necked flask containing 600g of toluene. The flask is equipped with a stirrer, temperature controller, nitrogen injector, cooler, and Dean-Stark. Separator (Dean-Stark trap), nitrogen gas flows through the flask and is dissolved in it. At this time, PS-CS-1.8CS (Unicore) was added thereto so that the Pt concentration of the reaction solution was 20 ppm. In about 30 minutes, 332g (1mol) 3,3-diphenyl-1,1,5,5-tetramethyltrisiloxane dissolved in 600g of toluene was slowly added dropwise to the solution to prepare the Solution. Then, the reaction solution was heated to reflux for 24 hours. The resulting reaction solution was passed through a 5 cm thick silica gel column to remove the platinum complex. The solvent was removed under reduced pressure distillation, thereby preparing a linear polyorganosiloxane resin (A-1).
[0133] The number aver...
Embodiment 1
[0154] 3.83g of the polyorganosiloxane resin (A-1) of Synthesis Example 1, 5g of the polyorganosiloxane resin represented by the above chemical formula 3a, and 2.03g of 3,3-diphenyl-1,1,5 were mixed , 5-tetramethyltrisiloxane, and PS-CS-1.8CS (Unicore) to prepare a polyorganosiloxane resin composition so that the Pt concentration of the reaction solution is 3 ppm.
Embodiment 2
[0156] 1.65g of the polyorganosiloxane resin (A-1) of Synthesis Example 1, 5.3g of the polyorganosiloxane resin represented by the above chemical formula 3a, 2.07g of 3,3-diphenyl-1,1, 5,5-tetramethyltrisiloxane, and 3,3-diphenyl-1,1,5,5-tetramethyltrisiloxane, and PS-CS-1.8CS (Unicore) The polyorganosiloxane resin composition was prepared so that the Pt concentration of the reaction solution was 3 ppm.
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