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Polypropylene composition for producing bottle cap of carbonated beverage

A polypropylene composition and a technology for the composition, applied in the field of polypropylene compositions, can solve the problems of deformation of bottle caps, poor toughness of anti-theft rings of bottle caps, brittleness of anti-theft rings of bottle caps, etc., so as to improve performance and improve stress The effect of whitening

Active Publication Date: 2013-06-12
CHINA PETROLEUM & CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the past, homopolypropylene was also used to produce carbonated beverage bottle caps. The bottle cap has good rigidity and bleaching resistance, but the anti-theft ring of the bottle cap has poor toughness and is prone to cracking. Later, people used block copolymerized polypropylene to produce carbonated beverage bottles. Cap, which solves the brittle phenomenon of the anti-theft ring of the bottle cap well, but the bottle cap deforms and the color of the thread of the bottle cap turns white under pressure
Some people also blend some polyethylene into block copolymerized polypropylene to improve the whitening phenomenon of the material, but due to the incompatibility of polypropylene and polyethylene, the bottle cap will crack and the deformation resistance of the bottle cap will be reduced under harsh conditions.

Method used

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  • Polypropylene composition for producing bottle cap of carbonated beverage

Examples

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Comparison scheme
Effect test

Embodiment 1

[0009] Example 1: Homopolymer polypropylene: MFR: 8.0g / 10 minutes, 40 parts, block copolymer polypropylene: MFR: 3.0g / 10 minutes, 40 parts; polyethylene: density: 0.955, MFR: 6g / 10 minutes , 15 parts; POE: 5 parts; nucleating agent NA21 (2,2′-methylenebis(4,6-tert-butylphenol) phosphine aluminum salt) 0.1 part; Oleic acid amide: 0.5 part; in a high-speed mixer After mixing for 1 minute, pelletize in a twin-screw extruder, prepare samples and test.

Embodiment 2

[0010] Example 2: Homopolymer polypropylene: MFR: 8.0g / 10 minutes, 50 parts, block copolymer polypropylene: MFR: 3.0g / 10 minutes, 30 parts; polyethylene: density: 0.955, MFR: 6g / 10 minutes , 15 parts; POE: 5 parts; nucleating agent NA21: 0.1 parts; Oleic acid amide: 0.5 parts; after mixing in a high-speed mixer for 1 minute, granulate in a twin-screw extruder, prepare samples and test.

Embodiment 3

[0011] Example 3: Homopolymer polypropylene: MFR: 8.0g / 10 minutes, 40 parts, block copolymer polypropylene: MFR: 3.0g / 10 minutes, 40 parts; polyethylene: density: 0.955, MFR: 6g / 10 minutes , 10 parts; POE: 10 parts; nucleating agent NA21: 0.1 parts; Oleic acid amide: 0.5 parts; after mixing in a high-speed mixer for 1 minute, granulate, sample and test in a twin-screw extruder.

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Abstract

The invention relates to a polypropylene composition for producing a bottle cap of a carbonated beverage. The composition comprises the following substances: 30-60 parts of homopolymerized polypropylene with an isotacticity higher than 99% and an MFR of 1-30g / 10 min; 30-60 parts of block copolymerized polypropylene with an MFR of 1-15g / 10 min; 4-20 parts of polyethylene with a density of 0.955-0.968 g / cm<3> and an MFR of 1-15 g / 10 min; 5-15 parts of polyolefin elastomer; 0.05-0.2 part of nucleating agent; and 0.3-1 part of slipping agent. The product has excellent rigidity, good impact resistance and good stress whitening resistance.

Description

Technical field [0001] The invention relates to a polypropylene composition, in particular to a polypropylene composition with excellent rigidity, good impact resistance and good resistance to stress whitening. Background technique [0002] The bottle caps used for packaging carbonated beverages are required to have excellent hygiene, high deformation resistance, good crack resistance, drop crack resistance, and stress whitening resistance in accordance with their performance requirements. Currently, block copolymer polypropylene and high-density polyethylene are mostly used as raw materials for producing carbonated beverage bottle caps. In the past, homopolypropylene was also used to produce carbonated beverage bottle caps. The bottle cap has good rigidity and whitening resistance, but the anti-theft ring of the bottle cap is poor and prone to cracking. Later, people use block copolymer polypropylene to produce carbonated beverage bottles. The cap is a good solution to the brit...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/12C08L53/00C08L23/06C08L23/08C08L23/16C08K5/20
Inventor 王德鑫左英飞
Owner CHINA PETROLEUM & CHEM CORP
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