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Catalytic cracking method and apparatus

A catalytic cracking device and catalytic cracking technology, which are applied in the fields of refining and cracking process treatment, petroleum industry, and hydrocarbon oil treatment in multi-stage series, can solve the problems of affecting the stripping effect, affecting the regeneration process, and increasing investment. Reduce unfavorable secondary reactions, reduce olefin content, and simplify the production of equipment

Active Publication Date: 2014-02-26
石宝珍
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in this technology, the catalyst separated from the first zone must be stripped before entering the regenerator. At the same time, the regenerated catalyst must be transported by the conveying medium before entering the second stage. The stripping steam and conveying medium will all enter the second stage, which will inevitably affect The reaction to the second stage; if the amount of stripping steam is limited, the stripping effect will be affected, and then the regeneration process will be affected; and this technology requires two settlers and two stripping sections, which greatly increases the investment

Method used

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  • Catalytic cracking method and apparatus
  • Catalytic cracking method and apparatus

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Embodiment 1

[0039] In the method of the present invention, the reaction raw materials in the secondary reactor and the second reaction zone of the main reactor (i.e. the light raw material in the secondary reactor and the oil and gas after the reaction in the first reaction zone) are lighter than the reaction raw materials in the first reaction zone, The S content is low, during the reaction process, there is no metal pollution to the catalyst, and the coke formation is low, so the second regenerator can adopt different regeneration conditions from the first regenerator, and there is no need to replace the catalyst; in addition, the regeneration temperature is lowered It can also reduce NO in regeneration flue gas X The formation is conducive to environmental protection.

[0040] figure 1 It is a schematic diagram of a catalytic cracking unit in an oil refinery, the first regenerator 40 is regenerated at 680-700°C, and the second regenerator 60 is regenerated at 620-650°C; the reaction ...

Embodiment 2

[0046] The design of a catalytic cracking unit in an oil refinery is as follows: figure 2 As shown, a catalyst cooler 43 is set on the regeneration standpipe 41, a second settler 37 is set in the secondary reactor 20, a catalyst return pipe 23 is arranged between the second settler 37 and the bottom of the secondary reactor 20, and the second settler There is a catalyst relay pipe 22 between 37 and the catalyst replenishment area 12; the oil and gas in the two reactors are treated separately. The rest of the device structure is the same as figure 1 . In the present embodiment, the circulation rate of the spent catalyst that is refluxed from the reactor 20 is controlled by the slide valve on the catalyst return pipe 23, and the reflux rate is 40%; the reaction raw material of the reactor 20 is mixed C 4 components. In this embodiment, the reaction temperature in the first reaction zone of the reactor 10 is 500°C, and the reaction time is 1.0s; the reaction temperature in t...

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Abstract

The invention discloses a catalytic cracking method and an apparatus and belongs to the technical field of petrochemical processing. The catalytic cracking is carried out in a main reactor and a minor reactor. A regeneration catalyst of a first regenerator contacts and reacts with raw oil in a first reaction zone of the main reactor, and a reacted mixture goes upwards and is separated by a diverter into a catalyst; the separated catalyst directly flows into a first stripping stage, is treated with stripping and returns to the first regenerator for regeneration. Reacted oil goes up wards along a conveyer pipe and enters a second reaction zone. A spent catalyst in the minor reactor first enters a catalyst additional area, then enters the second reaction zone through the catalyst additional area and is mixed with the reacted oil gas from the first reaction zone, so that the oil gas continues to react; and the catalyst enters into a second regenerator for regeneration after the reaction. According to the invention, catalyst displacement is realized in the second reaction zone to reinforce catalytic selectivity of the main reactor; the first regenerator and the second regenerator control different regeneration conditions to reduce side reactions; and a connected design of the apparatus reduces investment.

Description

technical field [0001] The invention relates to the field of petrochemical technology, in particular to a method and device for catalytic cracking of petroleum hydrocarbon raw materials. Background technique [0002] Catalytic cracking unit is the most important gasoline production unit. The vast majority of motor gasoline in the world comes from catalytic cracking unit. Conventional catalytic cracking uses riser reactor. [0003] The biggest disadvantage of the existing riser reactor is that the riser is too long, and the catalyst activity at the outlet of the riser is only about 1 / 3 of the initial activity. Therefore, in the second half of the riser reactor, the catalyst activity and selectivity have sharply increased Decrease, catalytic effect worsens, thermal cracking reaction and other unfavorable secondary reactions increase, which not only limits the improvement of single-pass conversion rate, but also causes the olefin content of catalytic gasoline to be as high as 4...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G55/06C10G51/00
Inventor 石宝珍
Owner 石宝珍
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