Highly-filled isophorone diisocyanate (IPDI) polyurethane-based composite material, and preparation method and use thereof

A composite material and polyurethane technology is applied in the preparation of the composite material. As the matrix material of the composite material, the polyurethane can solve the problems of low filling amount, single use, and the functional effect of the filler cannot be well reflected.

Active Publication Date: 2012-07-18
WANHUA CHEM GRP CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The use of this composite material is relatively single, and the preparation method is relatively complicated.
[0010] A variety of filled polyurethane-based composite materials have been disclosed in existing patents. The polyurethane matrix is ​​mostly foam type, and the amount of solid filler added can reach 90wt.%, but t...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] The formula composition of the highly filled IPDI polyurethane-based composite material is as follows: 30 parts by weight of silicon carbide powder with a particle size of less than 30 microns, 30 parts by weight of alumina powder particles with a particle size of less than 30 microns, and 30 parts by weight of zirconia , the particle size is below 30 microns, 9.66 parts by weight are composed of isophorone diisocyanate (IPDI) and polyoxyethylene-oxypropylene copolyether polyol (EP-330N, produced by Shandong Dongda University, the initiator is glycerin, functional Degree is 3, and molecular weight is the polyurethane matrix that reaction generates, the R of polyurethane reaction system (the molar content of isocyanate / active hydrogen molar content in oligomer polyol)=1.05, and auxiliary agent is the organic interfacial agent of 0.3 weight part (Silane titanate coupling agent 201, produced by Nanjing Qianqian Chemical Co., Ltd.), 0.01 parts by weight of organic polyuretha...

Embodiment 2

[0045] The composition of highly filled IPDI polyurethane-based composite material is as follows: 25 parts by weight of aluminum powder, particle size below 20 microns, 25 parts by weight of wood powder particles, particle size below 20 microns, 40 parts by weight of talcum powder, particle size Below 20 microns, 9.37 parts by weight are produced by isophorone diisocyanate (IPDI) and polyoxyethylene polyol (PPG-4000, Jiangsu Province Haian Petrochemical Plant, the initiator is 1,2-propanediol, functional 2, the molecular weight is the polyurethane matrix that 4000) generates, wherein, the R of polyurethane reaction system (the molar content of isocyanate / active hydrogen molar content in oligomer polyol)=1.03, and auxiliary agent is the organic interfacial agent of 0.3 weight part (silane titanate coupling agent 201, produced by Nanjing Qianqian Chemical Industry), 0.3 parts by weight of organic interface agent (silane coupling agent KH-550, produced by Qingdao Haida Chemical In...

Embodiment 3

[0047] The composition of the highly filled IPDI polyurethane-based composite material is as follows: 16 parts by weight of aluminum powder with a particle size below 20 microns, 20 parts by weight of sulfur particles with a particle size below 40 microns, and 50 parts by weight of ammonium nitrate with a particle size between Below 40 microns, 13.37 parts by weight are composed of isophorone diisocyanate (IPDI) and hydroxyl-terminated liquid polybutadiene (HTPB) (type I HTPB, produced by Shandong Zibo Qilong Chemical Industry, with a functionality of 2.3 and a molecular weight of 3900, Viscosity (40 ℃) is the polyurethane matrix that 7500mPa s) and auxiliary agent form, the R of polyurethane reaction system (the molar content of isocyanate / active hydrogen molar content in oligomer polyol)=1.04, auxiliary agent is 0.1 weight part Organic interfacial agent (silane titanate coupling agent 201, produced by Nanjing Qianqian Chemical Industry), 0.5 weight part of organic interfacial...

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Abstract

The invention discloses a highly-filled isophorone diisocyanate (IPDI) polyurethane-based composite material, and a preparation method and the use thereof. The components of the highly-filled IPDI polyurethane-based composite material comprises functional solid filler, a polyurethane substrate produced through a reaction of IPDI and oligomer polyol, and other performance adjusting additives. The functional solid filler, the additives and the oligomer polyol are evenly mixed, and then the IPDI is added to an obtained mixture; and the mixture is mechanically kneaded to react and then casted into a die to be cured and formed, so that a product is manufactured. The composite material can be used as a building structure material, a roof waterproof material, a gap repairing material, an energetic blasting material, an indoor decoration material and an insulation material. As the IPDI polyurethane is adopted as the substrate of the composite material, the composite material can be filled with high content of solid filler, which can reach up to 90 wt%, so that the functional effects of the solid filler in the composite material can be greatly played.

Description

technical field [0001] The present invention relates to a highly filled IPDI polyurethane-based composite material, in particular to the polyurethane produced by the reaction of isophorone diisocyanate (IPDI) and oligomer polyols as the matrix material of the composite material to increase the filling capacity of the solid filler , so that the composite material can give full play to the functional effect of the solid filler. The invention also relates to the preparation method and application of the composite material. Background technique [0002] The rapid development of modern industry and the improvement of people's living standards have put forward higher requirements for traditional materials, and the performance of a single material can no longer meet the needs of industrial development and the requirements of people's lives. Filled composite materials based on polyurethane can provide better mechanical properties, wear resistance, weather resistance, solvent resist...

Claims

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Application Information

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IPC IPC(8): C08L75/08C08L75/04C08L97/02C08G18/75C08G18/48C08G18/62C08K3/08C08K3/22
Inventor 王凯张昊黄岐善华卫琦丁建生臧文哲
Owner WANHUA CHEM GRP CO LTD
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