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Conductive glass for thin film solar battery and preparation method thereof

A technology of solar cells and conductive glass, applied in the field of new optoelectronic materials and solar materials, can solve the problem that the light transmittance, conductivity and scattering degree of conductive glass are not greatly improved, solar energy cannot be fully utilized and converted, transparent and conductive The problem of single film layer structure, etc., achieves the effect of cost-effective, ingenious design, and rich transparent conductive film layer structure.

Active Publication Date: 2012-09-19
CHANGZHOU ALMADEN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, in order to improve the light transmittance, people continue to improve the structure of the transparent conductive film that affects the light transmittance, conductivity and scattering of conductive glass, increase the number of layers of the metal oxide conductive layer, and add a layer of metal oxide conductive layer It is changed to multi-layer, but the multi-layer metal oxide conductive layers are still physically superimposed, and the transparent conductive film layer structure is single and the stability is poor. These improved transparent conductive film layer structures have not changed the performance of conductive glass in essence. , the light transmittance, conductivity and scattering degree of conductive glass have not been greatly improved
As a result, very huge solar energy cannot be fully utilized and converted, which reduces the conversion efficiency of solar energy and increases the cost of use

Method used

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  • Conductive glass for thin film solar battery and preparation method thereof
  • Conductive glass for thin film solar battery and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] As shown in the drawings, a conductive glass for thin film solar cells includes a glass substrate 1 and a transparent conductive film 5, and the transparent conductive film 5 includes a metal oxide conductive layer 2 and a second metal oxide conductive layer 4. A metal layer 3 is sandwiched between the metal oxide conductive layer 2 and the second metal oxide conductive layer 4, and the metal oxide conductive layer 2, the metal layer 3 and the second metal oxide conductive layer 4 are sequentially deposited on the glass substrate 1 on one side surface. The glass substrate 1 is common float white glass with a thickness of 3.2mm. The metal oxide conductive layer 2 has a thickness of 250 nm, the metal layer 3 has a thickness of 50 nm, and the second metal oxide conductive layer 4 has a thickness of 250 nm. The metal oxide conductive layer 2 is AZO, the metal layer 3 is a silver film, and the second metal oxide conductive layer 4 is SnO 2 :F.

[0028]A preparation method...

Embodiment 2

[0036] As shown in the accompanying drawings, a conductive glass for thin film solar cells, the structure of the conductive glass of this embodiment is basically the same as that of the first embodiment, the metal oxide conductive layer 2 is AZO, the metal layer 3 is a silver film, and the second metal The oxide conductive layer 4 is SnO 2 :F. The difference from Example 1 is: the glass substrate 1 is ultra-clear float glass with a thickness of 3.2mm; the thickness of the metal oxide conductive layer 2 is 150nm, the thickness of the metal layer 3 is 30nm, and the second metal oxide The thickness of the material conductive layer 4 is 250nm.

[0037] A preparation method for realizing the above-mentioned conductive glass for thin-film solar cells, the preparation method is basically the same as the preparation method in Example 1. the difference is:

[0038] In the first step, the distance between the target and the glass substrate 1 is adjusted to 50 mm, and the rest are the...

Embodiment 3

[0045] As shown in the accompanying drawings, a conductive glass for thin film solar cells, the structure of the conductive glass of this embodiment is basically the same as that of the first embodiment, the metal layer 3 is a silver film, and the second metal oxide conductive layer 4 is SnO 2 :F. The difference from the first embodiment is that the metal oxide conductive layer 2 has a thickness of 200 nm, the metal layer 3 has a thickness of 50 nm, and the second metal oxide conductive layer 4 has a thickness of 300 nm. The metal oxide conductive layer 2 is GZO.

[0046] A preparation method for realizing the above-mentioned conductive glass for thin-film solar cells, the preparation method is basically the same as the preparation method in Example 1. the difference is:

[0047] In the first step, the high-purity metal oxide GZO target and the high-purity metal silver target are installed in the sputtering chamber of the magnetron sputtering production line, and the rest ar...

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Abstract

The invention relates to novel high-property conductive glass, in particular to conductive glass for a thin film solar battery and a preparation method of the conductive glass. According to the conductive glass provided by the invention, a metal layer (3) is clamped between a metallic oxide conductive layer (2) and a second metallic oxide conductive layer (4); and the metallic oxide conductive layer (2), the metal layer (3) and the second metallic oxide conductive layer (4) are sequentially arranged on one side surface of a glass base material (1). According to the conductive glass, the metallic oxide conductive layer is prepared on the glass base material through methods such as LPCVD (low pressure chemical vapor deposition), a PECVD (plasma enhanced chemical vapor deposition), SPUTFER (magnetron sputtering) or SPRAY (hot spraying) method; the metal layer is prepared by a magnetron sputtering or thermal evaporation method; and the second metallic oxide conductive layer is prepared by a chemical vapor deposition method. The conductive glass provided by the invention has the advantages of good light transmission, strong conduction, high scattering degree, good film layer structure stability and high cost performance. Furthermore, according to the method for preparing the conductive glass provided by the invention, the preparation cost is low.

Description

technical field [0001] The invention relates to a new type of high-performance conductive glass, in particular to a conductive glass for thin-film solar cells and a preparation method thereof, which belongs to the field of photoelectric new materials, and is especially suitable for the field of solar materials. Background technique [0002] With the utilization of solar energy, which is a green, environmentally friendly and energy-saving new energy source, the development and development of new solar cells has increasingly become an important topic in the field of solar energy applications. At present, thin-film solar cells are widely used in solar cells. The quality of conductive glass as an important part of thin-film solar cells is directly related to the quality of thin-film solar cells. Therefore, the improvement and innovation of conductive glass for thin-film solar cells has always been very important. important. Existing conductive glass for thin-film solar cells ge...

Claims

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Application Information

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IPC IPC(8): H01L31/0224H01L31/0216H01L31/18C03C17/23C03C17/36
CPCY02P70/50
Inventor 林金锡林金汉林于庭林鹏
Owner CHANGZHOU ALMADEN
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