High conductivity and low loss ferrite material, ferrite thin film and preparation method thereof
A technology of ferrite material and ferrite film, which is applied in the field of electronic materials, can solve problems such as non-response of card readers and electronic tags, long recognition distance and low design distance, failure of reading process, etc., to achieve operation and process flow No pollution, smooth surface, adjustable thickness and size
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[0046] A preparation method for 13.56MHz high-conductivity and low-loss ferrite material and its thin film comprises the following steps:
[0047] 1) Mix raw materials: Weigh the raw materials as required, put them into a ball mill for a ball mill. Among them, the mass ratio of material, balls and absolute ethanol is 1:3:1, and the mass ratio of large balls to small balls is 1:2. The ball milling time was 2 hours, and the rotational speed was set at 250 rpm. The main purpose of a ball mill is to mix the raw materials evenly, and the average particle size of the raw materials after ball milling is about 1 μm.
[0048] 2) Pre-burning: Dry the raw materials that have been ball-milled once, put the dried raw materials into a high-temperature furnace for pre-burning, the pre-burning temperature is 900°C, and the holding time is 2 hours.
[0049] 3) Secondary ball milling: The pre-burned raw materials are subjected to secondary ball milling, and additives CoO0~1.2wt% are added, V ...
Embodiment 1
[0055] 1) The ratio of ingredients: Fe 2 o 3 50mol% for NiO; 25mol% for NiO; 20mol% for ZnO; 5mol% for CuO; 0.3wt% for doping component CoO.
[0056] 2) One-time ball milling: Weigh the raw materials according to the requirements, and put them into a ball mill for one-time ball milling. Among them, the mass ratio of material, balls and absolute ethanol is 1:3:1, and the mass ratio of large balls to small balls is 1:2. The ball milling time was 2 hours, and the rotational speed was set at 250 rpm.
[0057] 3) Pre-burning: Dry the raw materials that have been ball-milled once. The temperature of the oven is 80°C. Put the dried raw materials into the furnace for pre-burning. The pre-burning temperature is 900°C, the holding time is 2 hours, and the heating rate is 2°C / min.
[0058] 4) Secondary ball milling: The raw materials after pre-burning are subjected to secondary ball milling, and the additive CoO~0.3wt% is added. Among them, the mass ratio of material, balls and abso...
Embodiment 2
[0062] 1) The ratio of ingredients: Fe 2 o 3 50mol% for NiO; 25mol% for NiO; 20mol% for ZnO; 5mol% for CuO; 0.3wt% for doping component CoO.
[0063] 2) One-time ball milling: Weigh the raw materials according to the requirements, and put them into a ball mill for one-time ball milling. Among them, the mass ratio of material, balls and absolute ethanol is 1:3:1, and the mass ratio of large balls to small balls is 1:2. The ball milling time was 2 hours, and the rotational speed was set at 250 rpm.
[0064] 3) Pre-burning: Dry the raw materials that have been ball-milled once. The temperature of the oven is 80°C. Put the dried raw materials into the furnace for pre-burning. The pre-burning temperature is 900°C, the holding time is 2 hours, and the heating rate is 2°C / min.
[0065] 4) Secondary ball milling: The raw materials after pre-burning are subjected to secondary ball milling, and additives CoO~0.3wt% are added, V 2 o 5 ~0.9wt%. Among them, the mass ratio of materia...
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