Electrically conductive element, photosensitive material for formation of electrically conductive element, and electrode
A technology of conductivity and conductive metal, applied in the direction of photosensitive materials, conductive materials, conductive materials, etc., can solve problems such as unsatisfactory conductivity
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Embodiment 1
[0186]"Preparation of Emulsion A (Silver / Binder Volume Ratio: 1 / 1)"
[0187] 1 solution:
[0188]
[0189] · 2 fluids
[0190] water 300ml
[0191] Silver nitrate 150g
[0192] ·3 fluids
[0193]
[0194] Potassium hexachloroiridate (III) (0.005% KCl 20% aqueous solution) and ammonium hexachlororhodium (0.001% NaCl 20% aqueous solution) used in liquid 3 are respectively dissolved in KCl 20% aqueous solution , NaCl 20% aqueous solution and heated at 40°C for 120 minutes to prepare.
[0195] To liquid 1 kept at 38°C and pH 4.5, an amount corresponding to 90% of liquid 2 and liquid 3 was added over 20 minutes while stirring to form silver halide core particles of 0.16 μm. Next, the following 4 and 5 liquids were added over 8 minutes, and the remaining 10% of the 2 and 3 liquids were added over 2 minutes to grow the silver halide particles to 0.21 μm. Furthermore, 0.15 g of potassium iodide was added and aged for 5 minutes to complete the formation of silver halide par...
Embodiment 2)
[0257] The conductive fine particle-containing layer in the photosensitive material 5 was changed to the following, and the durability was evaluated.
[0258] (with conductive particle layer)
[0259] Coating 5cc / m on top of the silver halide emulsion layer 2 The following conductive fine particle liquid 2 liquids provided the conductive fine particle containing layer.
[0260] 2 fluids:
[0261]
[0262] In addition, a preservative and a pH adjuster are added appropriately. Here, according to the product catalogue, the Sb-doped tin oxide manufactured by Ishihara Sangyo Co., Ltd. under the product name SN100P is granular, has a primary particle size of 0.01 to 0.03 μm, and has an aspect ratio of approximately 1.
[0263] Photosensitive material A was obtained by drying the coated product obtained by using the emulsion layer coating liquid A for the silver halide emulsion layer and the conductive fine particle liquid 2 liquid for the conductive fine particle containing la...
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