Catalytic conversion method of high-sulfur wax oil

A catalytic cracking and wax oil technology, which is applied in the petroleum industry, hydrocarbon oil treatment, hydrotreating process, etc., can solve the problems of lower use efficiency, lower processing efficiency and high hydrogen consumption of S-Zorb units

A catalytic cracking and wax oil technology, which is applied in the petroleum industry, hydrocarbon oil treatment, hydrotreating process, etc., can solve the problems of lower use efficiency, lower processing efficiency and high hydrogen consumption of S-Zorb units

CN102911733BActive Publication Date: 2015-05-20CHINA PETROLEUM & CHEM CORP +1

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  • Catalytic conversion method of high-sulfur wax oil

Examples

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Embodiment 1

[0090] This example illustrates the product distribution and product properties of raw material A after being treated by a medium-sized catalytic cracking unit and a medium-sized hydrotreating unit using the method provided by the present invention. Both the first catalytic unit and the second catalytic unit use medium-sized catalytic cracking units with the same structure, but the operating conditions of the two catalytic units are different.

[0091] The medium-sized catalytic cracking unit adopts a variable-diameter riser reactor. The total height of the pre-lift section, the first reaction zone, the second reaction zone and the outlet zone of the reactor is 15 meters, the diameter of the pre-lift section is 0.025 meters, and its height is 1.5 meters; the diameter of the first reaction zone is 0.025 meters, and its height It is 4 meters; the diameter of the second reaction zone is 0.1 meters, and its height is 6.5 meters; the diameter of the outlet zone is 0.025 meters, and...

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Abstract

The invention discloses a catalytic conversion method of high-sulfur wax oil, and is characterized by comprising the following steps of: contacting the high-sulfur wax oil and a thermal regeneration catalyst with lower activity and relatively uniform activity distribution at the lower part of a catalytic unit reactor and carrying out cracking reaction, carrying out secondary cracking reaction and isomerization reaction on the generated oil gas and a carbon-containing catalyst under a certain reaction environment, separating the reaction oil gas to obtain a reaction product comprising liquefied gas, gasoline and catalytic wax oil, after stripping and regenerating a spent catalyst, circulating, hydrogenating the catalytic wax oil and the other optional secondary processing wax oil into an aromatic hydrocarbon separation unit, and further cracking the hydrogenated wax oil into a second catalytic unit. According to the method, low-carbon olefin, such as propylene and the like, can be produced furthest, and production of high-octane gasoline is both considered, so that a new way for a clean oil refining process and a clean oil refining product is provided.

Description

technical field [0001] The invention belongs to a catalytic conversion method of petroleum hydrocarbons, and more specifically relates to a catalytic conversion method of an integrated process of catalytic cracking and hydrotreating of high-sulfur wax oil. Background technique [0002] The processing of high-sulfur low-quality wax oil raw materials by conventional catalytic cracking technology not only makes the SO in catalytic cracking regeneration flue gas X Emissions do not meet environmental requirements, and the sulfur content in gasoline and diesel products does not meet product specifications. Therefore, usually these high-sulfur low-quality wax oil raw materials are first hydrotreated to remove impurities such as sulfur, nitrogen and metals, saturate the polycyclic aromatic hydrocarbons in the raw materials, and improve their catalytic cracking reaction performance, and then use them as raw materials for catalytic cracking to produce low Sulfur gasoline and diesel. ...

Claims

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Application Information

Patent Timeline
20 May 2015
Publication
CN102911733B
IPC
C10G69/04
Inventors
龙军; 龚剑洪