Colored Curable Resin Composition
A technology of curable resins and compositions, applied in the directions of optics, optomechanical equipment, instruments, etc., can solve problems such as insufficient satisfaction
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[0389] Next, examples will be given to further describe the present invention in detail. In the examples, unless otherwise specified, % and parts indicating the content or usage amount are based on mass.
Synthetic example 1
[0391] 20 parts of the compound represented by the formula (1a) and 200 parts of N-ethyl-o-toluidine (manufactured by Wako Pure Chemical Industries, Ltd.) were mixed under light-shielding conditions, and the obtained solution was stirred at 110° C. for 6 hours. After cooling the obtained reaction liquid to room temperature, it added to the mixed liquid of 800 parts of water and 50 parts of 35% hydrochloric acid, and stirred at room temperature for 1 hour, and the crystal was deposited. The precipitated crystal as the residue was collected by suction filtration and dried to obtain 24 parts of the compound represented by the formula (1-1). The yield was 80%.
[0392]
[0393] The structure of the compound represented by the formula (1-1) was confirmed by mass spectrometry (LC; Agilent 1200 type, MASS; Agilent LC / MSD type).
[0394] (Mass spectrometry) ionization mode = ESI+: m / z = [M+H] + 603.4
[0395] Exact Mass: 602.2
Synthetic example 2
[0397] Except that N-isopropyl-o-toluidine was used instead of N-ethyl-o-toluidine, the compound represented by formula (1-5) was obtained as in Synthesis Example 1.
[0398] Identification of compounds represented by formula (1-5)
[0399]
[0400] (Mass spectrometry) ionization mode = ESI+: m / z = [M+H] + 632.3
[0401] Exact Mass: 631.3
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