Production process for complete set of general asphalt carbon fiber

A production process and general-purpose technology, applied to the chemical characteristics of fibers, textiles and papermaking, etc., can solve the problems of low product performance, lack of transformation funds, and no industrial production capacity, etc., to achieve low industrialization costs, simple process conditions, The effect of strong industrialization operability

Inactive Publication Date: 2013-02-13
SICHUAN CHUANGYUE CARBON MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The research and development of pitch carbon fiber in my country is earlier, but there is a big gap compared with foreign countries in terms of development, production and application
In the early 1970s, the Shanghai Coking Plant successfully developed pitch carbon fiber using coal tar as a raw material, but due to unstable product quality and research results, it failed to realize industrial production.
Subsequently, the former Ministry of Metallurgical Industry prepared to build a new material research institute in Yantai, Shandong, and built a set of pitch carbon fiber production equipment with a production capacity of 70-100 tons per year. discontinued status
In the early 1990s, Anshan Dongya Carbon Fiber Co., Ltd. in Liaoning Province introduced a 200-ton / year melt-blown pitch carbon fiber production line from American Ashland Corporation, and it was completed and put into operation in 1995. At present, the operation of the device has tended to Normal, but its product performance is low
However, due to unoptimized process conditions, the production process cannot be carried out continuously, and no industrial production capacity has been formed.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] A production process of a complete set of general-grade pitch carbon fiber, comprising the following steps:

[0017] (1) Add heavy aromatic components with 5% carbon residue and 0.015% ash content to the 1# reactor, control the temperature of the reactor to 300°C, and feed air into the reactor, and the gas volume required for raw materials is 0.15m 3 / h / kg, stirring and reacting for 16 hours to obtain oxidized asphalt with a softening point of 180°C, and then pump the oxidized asphalt into the continuous reactor through a high-temperature delivery pump. The temperature of the continuous reactor is 370°C, and the continuous reactor is pumped Vacuum, the vacuum degree is -0.098MPa, the oxidized asphalt is reacted in the continuous reactor for 2 hours to make thermal condensation asphalt, and then the thermal condensation asphalt in the continuous reactor is transported to the continuous granulation equipment through the metering pump, and prepared according to the conventi...

Embodiment 2

[0023] A production process of a complete set of general-grade pitch carbon fiber, comprising the following steps:

[0024] (1) Add the heavy components of aromatics with 15% carbon residue, 0.01% ash, and a softening point of 70°C to the 1# reactor, control the temperature of the reactor to 310°C, and feed air into the reactor, The required gas volume is 0.12m 3 / h / kg, stirring and reacting for 12 hours to obtain oxidized asphalt with a softening point of 190°C, and then pump the oxidized asphalt into the continuous reactor through a high-temperature delivery pump. The temperature of the continuous reactor is 380°C, and the continuous reactor is pumped Vacuum, the vacuum degree is -0.098MPa, the oxidized asphalt is reacted in the continuous reactor for 1.5h, and the heat-condensed asphalt is made, and then the heat-condensed asphalt in the continuous reactor is transported to the continuous granulation equipment through the metering pump, and prepared according to the convent...

Embodiment 3

[0030] A production process of a complete set of general-grade pitch carbon fiber, comprising the following steps:

[0031] (1) Add heavy aromatic components with 20% carbon residue, 0.01% ash, and a softening point of 90°C to the 1# reactor, control the temperature of the reactor to 315°C, and feed air into the reactor. The required gas volume is 0.12m 3 / h / kg, stirring and reacting for 14 hours to obtain oxidized asphalt with a softening point of 200°C, and then pump the oxidized asphalt into the continuous reactor through a high-temperature delivery pump. The temperature of the continuous reactor is 380°C, and the continuous reactor is pumped Vacuum, the vacuum degree is -0.098MPa, the oxidized asphalt is reacted in the continuous reactor for 2 hours to make thermal condensation asphalt, and then the thermal condensation asphalt in the continuous reactor is transported to the continuous granulation equipment through the metering pump, and prepared according to the conventio...

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Abstract

The invention belongs to the technical field of a fiber asphalt preparation method, and particularly relates to a production process for a complete set of a general asphalt carbon fiber. The production process solves problems of a conventional production method for a general asphalt carbon fiber that a technology is complex, cost is high, and continuous production cannot be carried out. The production process comprises steps as follows: getting aromatic heavy components as raw materials, adjusting by asphalt, fusing and spinning, continuously non-melting, and continuously carbonizing, so as to obtain the general asphalt carbon fiber. The production process has the advantages of being simple in production process and technological condition, low in industrialization cost, and strong in industrialization operability and the like.

Description

technical field [0001] The invention belongs to the technical field of fiber pitch preparation methods, and in particular relates to a production process of a complete set of general-grade pitch carbon fibers. Background technique [0002] There are two main series of industrially produced carbon fibers in the world according to raw materials. One is polyacrylonitrile as raw material, and the other is petroleum asphalt or coal tar pitch. The output of the former accounts for about 90% of the total output of carbon fiber, and the latter Those accounted for about 10%. The pitch-based carbon fiber is divided into two categories, one is general-grade pitch carbon fiber, and the other is high-performance carbon fiber. [0003] The research and development of pitch carbon fiber in my country is earlier, but there is a big gap in development, production and application compared with foreign countries. In the early 1970s, the Shanghai Coking Plant successfully developed pitch carb...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F9/15D01F9/155
Inventor 张福强王斌余洋林源伍孝阳贤刘朗史景利
Owner SICHUAN CHUANGYUE CARBON MATERIAL
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