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A photocurable coating composition for preparing high-toughness optical-grade hardened film and corresponding hardened film

A composition and photo-curing technology, applied in optics, optical components, coatings, etc., can solve the problem of not meeting the requirements of 3D micro-nano optical structure coatings, affecting the impact resistance, weather resistance, hardened film layer and Reduce the adhesion of substrates and other problems, to achieve the effect of improving light transmittance, improving light transmittance, and improving flexibility

Active Publication Date: 2016-08-10
FSPG HI TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Chinese invention patent application 201010566198.1 provides a cured film that can be used for flat display. It adds a small amount of inorganic particles to the cured film coating liquid, and after ultraviolet (UV) curing, it forms a cured film with good acid and alkali resistance and High-hardness hardened coating, but it can be observed from the scanning electron microscope that there is an obvious interface separation phenomenon between the inorganic particles and the organic film layer, and there are many unevenly distributed holes, resulting in a gap between the hardened film layer and the substrate. The adhesiveness of the cured film is reduced, which affects the impact resistance and weather resistance of the cured film, and reduces the toughness and stability of the cured film
As a result, its performance cannot meet the requirements of coatings for 3D micro-nano optical structures

Method used

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  • A photocurable coating composition for preparing high-toughness optical-grade hardened film and corresponding hardened film
  • A photocurable coating composition for preparing high-toughness optical-grade hardened film and corresponding hardened film
  • A photocurable coating composition for preparing high-toughness optical-grade hardened film and corresponding hardened film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] 1. Preparation of photocurable coating composition:

[0049] (1) Prepare the following materials:

[0050]

[0051] (2) In the absence of ultraviolet light and sunlight, and the relative humidity of the air is less than 60%, add the above substances into the mixing container in turn, and fully stir for 20 minutes after adding each component;

[0052] (3) Filtrating the mixture to remove impurities to obtain a photocurable coating composition.

[0053] 2. Preparation of optical high toughness hardened film:

[0054] Such as figure 1 As shown, the above-prepared photocurable coating composition was coated on a thermoplastic flexible substrate (such as a polyester film) with a wire bar. Such as figure 2 As shown, after drying treatment, use a concentrated high-pressure electrodeless mercury lamp (80w / cm), and the irradiation energy is 600mj / cm 2 Irradiation, while pressing with a precision transfer pressure roller, the photocurable coating composition is cured and...

Embodiment 2

[0056] 1. Preparation of photocurable coating composition:

[0057] (1) Prepare the following materials:

[0058]

[0059] (2) In the absence of ultraviolet light and sunlight, and the relative humidity of the air is less than 60%, add the above substances into the mixing container in turn, and fully stir for 20 minutes after adding each component;

[0060] (3) Filtrating the mixture to remove impurities to obtain a photocurable coating composition.

[0061] 2. Preparation of optical high toughness hardened film

[0062] Coat the above-prepared photocurable coating composition on a thermoplastic flexible substrate (such as a polyester film) with a wire bar, and after drying, irradiate energy with a concentrated high-pressure electrodeless mercury lamp (80w / cm2) 600mj / cm 2 Irradiation, while pressing with a precision transfer pressure roller, the photocurable coating composition is cured and hardened on the substrate to form a nano-microstructure hardened layer—a hardened...

Embodiment 3

[0064] 1. Preparation of photocurable coating composition:

[0065] (1) Prepare the following materials:

[0066]

[0067] (2) In the absence of ultraviolet light and sunlight, and the relative humidity of the air is less than 60%, add the above substances into the mixing container in turn, and fully stir for 20 minutes after adding each component;

[0068] (3) Filtrating the mixture to remove impurities to obtain a photocurable coating composition.

[0069] 2. Preparation of optical high toughness hardened film

[0070] Coat the above-prepared photocurable coating composition on a thermoplastic flexible substrate (such as a polyester film) with a wire bar, and after drying, irradiate energy with a concentrated high-pressure electrodeless mercury lamp (80w / cm2) 600mj / cm 2 Irradiation, while pressing with a precision transfer pressure roller, the photocurable coating composition is cured and hardened on the substrate to form a nano-microstructure hardened layer—a hardened...

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Abstract

The present invention provides a light curing coating composition for preparing a high toughness optical grade hardening film. The light curing coating composition comprises the following components, by weight, A, 25-65% of an acrylate compound with a reaction functionality of 1-6, B, 35-75% of a hydroxyl and amino-containing oligomer with a reaction functionality of 4-6, C, 1-10% of a toughening agent, and D, 1-15% of a photoinitiator, wherein the weight percentage adopts the total weight of the component A and the component B as the reference. According to the present invention, the toughening agent is added to the light curing coating composition (hardening film coating solution) so as to enhance compatibility of the two components and improve light transmittance; and double bonds on a hydroxyl-terminated polybutadiene rubber molecular chain have a certain activity, and a grafting cross-linking reaction can be initiated in the presence of a free radical, such that the hydroxyl-terminated polybutadiene and partial resins form an interpenetrating network (IPN) structure under a photoinitiator effect to generate a synergistic effect and provide a forced inclusion effect so as to increase toughness and stability of the coating solution. The present invention further provides the corresponding high toughness optical grade hardening film.

Description

technical field [0001] The invention relates to a photocurable coating composition for preparing a high-toughness optical-grade hardened film, in particular to a hardened film coating solution with high toughness, good stability, high light transmittance and solvent resistance; the present invention At the same time, it relates to a corresponding high-toughness optical-grade cured film; the present invention also relates to a preparation method of the above photocurable coating composition and cured film. Background technique [0002] With the development of social economy, the increase of communication traffic and video resources, the continuous improvement of the quality of movies and TV programs, and the improvement of the resolution accuracy of display devices, audiences have put forward higher requirements for visual experience, that is, vivid and comfortable three-dimensional viewing experience. [0003] Glasses-free 3D technology enables users to enjoy 3D effects wit...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D4/02C09D171/00C09D175/14C09D7/12G02B1/14
Inventor 周锰植满溪何嘉杰
Owner FSPG HI TECH