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Electro-galvanizing environment-friendly passivation solution and using method thereof

A technology of electro-galvanizing and passivation solution, applied in the direction of metal material coating process, etc., can solve the problems of low economic benefit and poor corrosion resistance, and achieve the effect of improving economic benefit, excellent performance and improving corrosion resistance

Active Publication Date: 2013-08-28
昆明绿朗环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The passivation film of these passivation processes is thin, and the corrosion resistance is not good, or there are problems of low economic benefits, so most of them have not been used in industrial production

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Electro-galvanizing environmental protection passivation solution is composed of the following components:

[0017] Sodium silicate 10g / L, H 2 SO 4 2mL / L,

[0018] TiCl 3 0.5g / L, H 2 o 2 20mL / L,

[0019] Mg(NO 3 ) 2 20g / L, the rest is H 2 O;

[0020] The pH is 1.5. (with concentrated H 2 SO 4 solution to adjust the pH value)

[0021] The passivation solution is used for silicate passivation treatment on screws and nuts. Before electroplating, screws and nuts are subjected to pre-treatments such as grinding, derusting, degreasing, activation, etc., and then put into electroplating bath for electroplating. The bath composition and operating conditions of the galvanizing process are: ZnCl 2 80g / L, NaCl200g / L, boric acid 30g / L, appropriate amount of galvanizing additives, the pH value of the plating solution is maintained at 4.5, and the current density is 1.5A / dm 2 , the temperature is room temperature, and the plating time is 20 minutes.

[00...

Embodiment 2

[0025] Electro-galvanizing environmental protection passivation solution is composed of the following components:

[0026] Potassium silicate 15g / L, H 2 SO 4 3mL / L,

[0027] TiCl 3 1g / L, H 2 o 2 15mL / L,

[0028] Mg(NO 3 ) 2 35g / L, the rest is H 2 O;

[0029] The pH value is 2. (Adjust pH with NaOH solution)

[0030] The passivation solution is used for silicate passivation treatment after electroplating Zn with an oil cylinder of an automobile engine. The steel pipe is electroplated after pretreatment (rust removal, degreasing, activation). The composition and operating conditions of the zinc-iron alloy electroplating process are: NaOH100g / L, ZnCl 2 10g / L, appropriate amount of additives, pH value 12.5, cathode current density 1.7A / dm 2 , The temperature is room temperature, and the electroplating time is 60 minutes.

[0031] Rinse the galvanized steel pipe with water, and then put the concentration of 2% HNO 3 In the aqueous solution, soak for 1 sec...

Embodiment 3

[0034] Electro-galvanizing environmental protection passivation solution is composed of the following components:

[0035] Potassium silicate 30g / L, H 2 SO 4 5mL / L,

[0036] TiCl 3 1.5g / L, H 2 o 2 5mL / L,

[0037] Mg(NO 3 ) 2 50g / L, the rest is H 2 O;

[0038] The pH value is 4. (with concentrated H 2 SO 4 solution to adjust the pH value)

[0039] The passivation solution is used for passivation treatment after the overall galvanizing of large steel plates. Large steel plates are electroplated after pretreatment (rust removal, degreasing, activation), and the bath composition and operating conditions of the galvanizing process are: ZnCl 2 70g / L, KCl190g / L, appropriate amount of additives, pH value 5.5, cathode current density 1.8A / dm 2 , The temperature is room temperature, and the electroplating time is 50 minutes.

[0040] Rinse the galvanized steel plate with water, and then put in 3% HNO 3 In the aqueous solution, soak for 15 seconds at room tem...

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PUM

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Abstract

The invention provides an electro-galvanizing environment-friendly passivation solution and a using method thereof, and belongs to the technical field of metal material surface treatment. The electro-galvanizing environment-friendly passivation solution consists of the following components according to concentration: 10-30 g / L of silicate, 2-5 mL / L of H2SO4, 0.5-1.5 g / L of TiCl3, 5-20 mL / L of H2O2, 20-50 g / L of Mg(NO3)2 and the balance of H2O. The using method comprises the following steps of: washing and cleaning galvanized accessories, then putting the accessories into a polishing solution, soaking the accessories in the polishing solution at room temperature for 1-15 seconds, then washing the accessories, putting the accessories into the electro-galvanizing environment-friendly passivation solution, keeping the pH at 1.5-4, soaking the accessories in the electro-galvanizing environment-friendly passivation solution for 5-100 seconds, then washing and cleaning the accessories by water, and finally drying the water on the surfaces of the accessories. The passivation solution is stable and reliable, is a chromium-free silicate passivation solution and is mainly used for posttreatment of electro-galvanizing for steel accessory surfaces. The corrosion resistance of the zinc treated by the passivation solution is obviously improved, and the chromate passivation effect is achieved; and the electro-galvanizing environment-friendly passivation solution has the advantages of environment friendliness, zero pollution, economical property, practicability, high performance and the like.

Description

technical field [0001] The invention relates to an electro-galvanizing environment-friendly passivation solution and a method for using the same, belonging to the technical field of metal material surface treatment. Background technique [0002] Electrogalvanizing and zinc alloys are widely used in metallurgy, machinery, aviation, construction and many other fields, which can effectively improve the corrosion resistance of steel. However, zinc and zinc alloys are easily corroded in hot and humid environments, and white spots and gray matter are formed on the surface. In order to improve the corrosion resistance and decorative properties of the galvanized layer, passivation treatment is required. The traditional chromate passivation process is simple, the source of raw materials is wide, and the corrosion resistance of the passivation film is good, so it has been widely used. However, the treatment of chromate passivation waste liquid is difficult, and the Cr contained in i...

Claims

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Application Information

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IPC IPC(8): C23C22/53C25D5/48
Inventor 范云鹰陈高伟蒋业华
Owner 昆明绿朗环保科技有限公司