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System for concurrently measuring uranium concentration and nitric acid concentration

A nitric acid and concentration technology, applied in the field of analytical chemistry, can solve the problems of long time consumption, large measuring device volume, and easy poisoning, and achieve the effects of reducing the dose received, avoiding electrode poisoning, and reducing workload

Active Publication Date: 2013-08-28
CHINA INSTITUTE OF ATOMIC ENERGY
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Problems solved by technology

For the analysis of the concentration of uranium and nitric acid, the traditional method is to use the specific gravity method and Wheatstone bridge method to measure the concentration of uranium and nitric acid respectively. The disadvantage of not being able to grasp the concentration of the liquid components in time
In addition, the measurement device used in the specific gravity method is bulky, and the electrode of the Wheatstone bridge method is easily poisoned. These characteristics make the traditional method unable to be applied to the on-line analysis of the concentration of uranium and nitric acid in the post-treatment liquid.

Method used

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  • System for concurrently measuring uranium concentration and nitric acid concentration
  • System for concurrently measuring uranium concentration and nitric acid concentration

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Embodiment

[0023] The operation process of the system is: the sample to be tested is sent to one end of the U-shaped oscillating tube by a peristaltic pump after passing through the valve, and then flows out from the other end and then enters the conductivity measuring cell of the electrodeless conductivity meter for conductivity measurement. The current analog signal of uranium and nitric acid in the solution is obtained through the instrument system and output to the data acquisition and control system. The current analog signal is converted into a digital signal by the data acquisition and control system and then transmitted to the computer, which is calculated and saved by UraniumAcid1.0 software or Print out the uranium concentration and nitric acid concentration.

[0024] Prepare 4 standard uranium-nitrate samples, measure their density, conductivity and temperature, and calculate the uranium concentration and acidity in the sample solution by UraniumAcid1.0 software according to th...

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Abstract

The invention belongs to the technical field of analytical chemistry, and discloses a system for concurrently measuring a uranium concentration and a nitric acid concentration during a spent fuel post-treatment process. The system comprises two parts such as a hardware system and a software system, wherein the hardware system comprises a sampling analysis system, an instrumentation system, a data acquisition and control system, an industrial control machine and a peripheral equipment system, the sampling analysis system comprises a U-shaped oscillation tube density meter and a electrode-free conductivity analyzer, analog signals of the measured uranium concentration and the measured nitric acid concentration are read by the instrumentation system, are converted into digital signals through the data acquisition and control system, and are transmitted to the industrial control machine through a data transmission line, and the uranium concentration and the nitric acid concentration in the solution are directly calculated through a UraniumAcid1.0 software. With the system, the uranium concentration and the nitric acid concentration can be rapidly and concurrently measured.

Description

technical field [0001] The invention belongs to the technical field of analytical chemistry, and in particular relates to a system for simultaneously measuring the concentrations of uranium and nitric acid in the spent fuel reprocessing process. Background technique [0002] In the spent fuel reprocessing process, the concentration of uranium and nitric acid are two important process control parameters, which directly affect the operation effect of the reprocessing process. For the analysis of the concentration of uranium and nitric acid, the traditional method is to use the specific gravity method and Wheatstone bridge method to measure the concentration of uranium and nitric acid respectively. The disadvantage of not being able to grasp the concentration of feed liquid components in time. In addition, the measuring device used in the specific gravity method is bulky, and the electrodes of the Wheatstone bridge method are easily poisoned. These characteristics make the tra...

Claims

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Application Information

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IPC IPC(8): G01N27/02G01N9/00
Inventor 邵少雄刘权卫范德军朱海巧吴继宗罗中艳
Owner CHINA INSTITUTE OF ATOMIC ENERGY
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