Energy-saving and high-efficiency self-cleaning polymerization process and device

A technology of polymerization device and polymerization process, applied in the directions of cleaning hollow objects, cleaning methods and utensils, chemical/physical/physicochemical processes, etc. , product quality decline and other problems, to avoid the use of anti-sticking agent, avoid the decline of heat transfer coefficient, and save production costs.

Inactive Publication Date: 2013-11-27
BEIJING UNIV OF CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] 1. The adhesion fastness of the anti-adhesive coating is low, it is easy to mix into the product, reduce the purity of the product, and affect the effect of the anti-adhesive agent
[0009] 2. Insufficient anti-oxidation time will cause the anti-sticking agent to fail early, resulting in a decline in product quality
[0010] 3. The problem of color cast, the coating will be eroded and dropped into the kettle during the polymerization reaction, and the dark anti-sticking kettle agent may contaminate the resin (such as "American red", "British blue"), which may contaminate the resin Make the resin reddish or bluish, affecting the color of the product
[0011] 4. It is difficult to operate when using, and manual spraying is required, and the uniformity and integrity of the spraying cannot be guaranteed

Method used

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  • Energy-saving and high-efficiency self-cleaning polymerization process and device
  • Energy-saving and high-efficiency self-cleaning polymerization process and device
  • Energy-saving and high-efficiency self-cleaning polymerization process and device

Examples

Experimental program
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Effect test

specific Embodiment approach 2

[0036] The water used for batching is sent from the pure water workshop and then added to the high-purity water storage tank. The high-purity water is pumped to the monomer metering tank, and the vinyl chloride monomer is sent to the monomer metering tank by the vinyl chloride workshop. The weighed various additives It flows into the tubes 4 of the tube-and-tube reactor by means of the delivery pump, and the rotor 6 inside the tube 4 is driven to rotate by means of the fluid action, and the turbulent flow formed by the rotation of the rotor 6 is used to realize the cold stirring of the material, and the hot water pump is started after the end. Send hot water into the shell of the reactor, stop the hot water pump when the tube side temperature rises to the reaction temperature, and absorb the reaction heat with cooling water, the polymerization reaction continues, and the material can be discharged when the reaction pressure drops to 0.1-0.15MPa.

specific Embodiment approach 3

[0037] Ethylene is used as a polymerization raw material to flow into the tube 4 of the tube-and-tube reactor through a delivery pump, and the rotation of the rotor 6 in the tube 4 driven by the fluid is used to prevent wall sticking and clogging, and it is added to the shell side of the reactor. Hot water is used to provide the reaction temperature. After a period of reaction time, the polymer slurry flowing out of the reactor tube passes through the flash tank, the gas-liquid separator to the powder dryer, and then granulates.

specific Embodiment approach 4

[0038] Taking the slurry method as an example, when feeding into the reactor, control the hot water on the shell side to ensure that the reaction temperature is 50-70°C and control the feed pressure at 0.5-1MPa when feeding, and add a trace amount of hydrogen at the same time, and use the rotor 6 to rotate The effect makes it fully mixed to achieve the effect of adjusting the relative molecular mass. After the reaction is over, alcohols will be added to another device to remove catalyst residues.

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Abstract

The invention relates to an energy-saving and high-efficiency self-cleaning polymerization process and device. The energy-saving and high-efficiency self-cleaning polymerization device comprises a shell and tube reactor and a rotor type self-cleaning strengthened heat transfer device, wherein the rotor type self-cleaning strengthened heat transfer device mainly comprises rotors, middle support frames, backwater end pendants, limit members and lifting hook pendants, and the middle support frames are used for strengthening the rigidity of a rotating shaft, improving a self-centering effect of the rotors and prolonging the operation service life of the whole device. A locating pin roll of each lifting hook pendant is matched with a locating hole of the adjacent lifting hook pendant so that the axial tension strength of the single lifting hook pendant is enhanced. Materials participating in the polymerization pass through a tube pass, and heating or cooling fluid passes through a shell pass. Reaction materials are fully mixed through the rotation of the rotors, and heat generated in the polymerization is rapidly released. The energy-saving and high-efficiency self-cleaning polymerization device also has a self-cleaning function; according to the energy-saving and high-efficiency self-cleaning polymerization device, the problem of adhering of a kettle is solved, the product quality and production efficiency are improved, and thus the defect of a traditional production mode is avoided.

Description

technical field [0001] The invention belongs to the field of polymerization production, and in particular relates to an energy-saving, high-efficiency, self-cleaning polymerization process and device. Background technique [0002] All kinds of polymer material products appear in modern life, including rubber, plastic, fiber, coating, adhesive and polymer-based composite materials, etc. One method usually used in the production of polymer materials is polymerization reaction, such as plastic (PVC), polyester fiber, etc. are prepared by polymerization reaction. [0003] In the process of polymerization reaction, the problem of sticking to the kettle has always been a major obstacle restricting the development of polymerization reaction. In the polymerization reaction of any process, as long as the monomer contacts (such as the inner wall of the reaction vessel, stirring equipment, other parts of the polymerization vessel), the deposition or adhesion of polymer plasticized she...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J19/18C08F2/01C08F14/06
CPCC08F2/01B01J19/0066B01J19/1825B01J2219/00094B01J2219/00254B01J2219/00779B08B9/027B08B17/02
Inventor 杨卫民张震阎华贾雨川焦志伟丁玉梅
Owner BEIJING UNIV OF CHEM TECH
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