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Preparation method of wave-absorbing material

A wave-absorbing material, nano-silver technology, applied in chemical instruments and methods, other chemical processes, etc., can solve the problem of low wave-absorbing efficiency of pure ferrite, achieve excellent electrical and thermal conductivity, stable performance, and improve wave-absorbing The effect of potency

Active Publication Date: 2015-02-25
SUZHOU JUHUIBANG NEW MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to provide a method for preparing a wave-absorbing material to solve the problem of low wave-absorbing efficiency of pure ferrite. The wave-absorbing material has a simple preparation process and low production cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] 1) Take 1 gram of graphene oxide powder and add 200 ml of deionized water, and ultrasonically disperse for 2 hours to obtain a graphene oxide dispersion;

[0021] 2) Add 200 grams of 2mol / L silver nitrate solution and 10 grams of dispersant polyvinylpyrrolidone to the prepared graphene oxide dispersion, stir for 2 hours, heat up to 40°C, and then add 20 grams of 0.5mol / L The hydrazine hydrate solution was reacted for 50 minutes under stirring conditions, and the pH value of the system was adjusted to 5 with a mass fraction of 5% ammonia solution. After the reaction was completed, the product was separated by centrifugation, washed 3 times with deionized water and ethanol, and dried Dry, prepare nano-silver-graphene composite material;

[0022] 3) Take 40 grams of the above-prepared nano-silver-graphene composite material and 60 grams of nickel-zinc ferrite, mix them, and ball mill for 3 hours. The particle size of the mixture is ≤ 2 μm, and the wave-absorbing material f...

Embodiment 2

[0024] 1) Add 1 gram of graphene oxide powder to 100 ml of deionized water, and ultrasonically disperse for 3 hours to obtain a graphene oxide dispersion;

[0025] 2) Add 50 grams of 2mol / L silver nitrate solution and 5 grams of dispersant polyvinylpyrrolidone to the prepared graphene oxide dispersion, stir for 1 hour, heat up to 50°C, and then add 15 grams of 0.5mol / L The hydrazine hydrate solution was reacted for 40 minutes under stirring conditions, and the pH value of the system was adjusted to 5 with an ammonia solution with a mass fraction of 2%. After the reaction was completed, the product was separated by centrifugation, washed twice with deionized water and ethanol, and dried Dry, prepare nano-silver-graphene composite material;

[0026] 3) Take 30 grams of the above-prepared nano-silver-graphene composite material and 70 grams of nickel-zinc ferrite, mix them, and ball mill for 2 hours. The particle size of the mixture is ≤ 2 μm, and the wave-absorbing material for ...

Embodiment 3

[0028] 1) Take 1 gram of graphene oxide powder and add 50 ml of deionized water, and ultrasonically disperse for 4 hours to obtain a graphene oxide dispersion;

[0029] 2) Add 17 grams of 2mol / L silver nitrate solution and 2.55 grams of dispersant polyvinylpyrrolidone to the prepared graphene oxide dispersion, stir for 1 hour, heat up to 60°C, and then add 8.5 grams of 0.5mol / L The hydrazine hydrate solution was reacted for 30 minutes under stirring conditions, and the pH value of the system was adjusted to 6 with an ammonia solution with a mass fraction of 2%. After the reaction was completed, the product was separated by centrifugation, washed twice with deionized water and ethanol, and dried Dry, prepare nano-silver-graphene composite material;

[0030] 3) Take 20 grams of the above-prepared nano-silver-graphene composite material and 80 grams of nickel-zinc ferrite, mix them, and ball mill for 2 hours. The particle size of the mixture is ≤ 2 μm, and the wave-absorbing mate...

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PUM

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Abstract

The invention discloses a preparation method of a wave-absorbing material. The preparation method comprises the steps: mixing 60-80% of ferrite and 20-40% of nanosilver-graphene according to weight percentage, and carrying out ball milling for 2-3h until the particle size of a mixture is smaller than or equal to 2mu m to obtain the wave-absorbing material. According to the invention, nanosilver powder is loaded on a graphene carrier through an in-situ synthesis method, so that the problem of local agglomeration among nanosilver particles is solved; and meanwhile, the nanosilver powder and the graphene have excellent conductivity and heat conducting property, and the nanosilver-graphene can generate eddy current loss and the magnetic conducting ferrite can generate magnetic loss under the action of electromagnetic waves, so that the wave-absorbing effect of the wave-absorbing material can be greatly improved through compounding both the nanosilver and the graphene.

Description

technical field [0001] The invention relates to a method for preparing a wave-absorbing material, in particular to a method for preparing a ferrite composite wave-absorbing material. Background technique [0002] Radio Frequency Identification (RFID) technology is an important part of the Internet of Things, and has been widely used in transportation, enterprise production process control, and industries that require dynamic management of items, etc. [0003] The RFID system transmits data through radio waves. When radio waves encounter metal, liquid or electromagnetic interference, the signal will be attenuated, which will affect the reliability and accuracy of data reading. Therefore, a layer of electromagnetic shielding absorbing material must be packaged in the electronic tag to ensure that the effective communication distance of the electronic tag is not affected. Currently, electromagnetic shielding conductive paints are used to solve this shielding problem. Ultrafin...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K3/00
Inventor 张宇
Owner SUZHOU JUHUIBANG NEW MATERIAL TECH CO LTD