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Sio2-based self-cleaning paint and self-cleaning glass and preparation method thereof

A self-cleaning and coating technology, applied in the direction of coating, etc., can solve the problems of inapplicability to large-scale processing, high cost, and environmental impact, and achieve excellent super-hydrophilic effect, low processing cost, and good self-cleaning and weather resistance

Active Publication Date: 2015-07-29
GUANGDONG SOUTH BRIGHT GLASS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this process uses spin-coating coating technology, which is not suitable for large-scale processing, and the invention uses an organic solvent system, which has high cost and has a certain impact on the environment

Method used

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  • Sio2-based self-cleaning paint and self-cleaning glass and preparation method thereof
  • Sio2-based self-cleaning paint and self-cleaning glass and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] 1. Preparation of self-cleaning coatings:

[0025] 1) Take 25ml of water-based silica sol (particle size 8-20nm, solid content 5%), add 0.3g of polyvinylpyrrolidone K30 into it, stir and mix well. Among them, polyvinylpyrrolidone is a dispersant.

[0026] 2) Dilute the above solution with deionized water until the solid content of silica is 1.2%, stir and mix evenly.

[0027] 3) Add 0.02% (volume ratio) of alkoxy-modified polytrisiloxane and 0.02% (volume ratio) of silane coupling agent KH-570 to the above solution in turn, mix well and set aside. Wherein alkoxy modified polytrisiloxane is used as surfactant.

[0028] 2. Preparation of self-cleaning curtain wall glass:

[0029] Take prepared SiO 2 The self-cleaning coating solution is evenly sprayed on the clean glass substrate, then cured at room temperature for 20 minutes, and finally heat-cured at 400°C for 20 minutes to obtain self-cleaning curtain wall glass.

[0030] figure 1 It is the test result of the con...

Embodiment 2

[0033] 1. Preparation of self-cleaning coatings:

[0034] 1) Take 25ml of water-based silica sol (particle size 8-20nm, solid content 5%), add 0.3g of polyvinylpyrrolidone K30 into it, stir and mix well;

[0035] 2) Dilute the above solution with deionized water until the solid content of silica is 1.2%, stir and mix evenly;

[0036] 3) Add 0.01% (volume ratio) of alkoxy-modified polytrisiloxane and 0.01% (volume ratio) of KH-570 to the above solution in turn, mix well and set aside.

[0037] 2. Preparation of self-cleaning curtain wall glass:

[0038] Take prepared SiO 2 The self-cleaning coating solution is evenly sprayed on the clean glass substrate, then baked with hot air at 80°C for 1 minute, and finally cured according to the glass tempering process to obtain the self-cleaning curtain wall glass.

Embodiment 3

[0040] 1. Preparation of self-cleaning coatings:

[0041] 1) Take 25ml of water-based silica sol (particle size 8-20nm, solid content 2%), add 0.1g of polyvinylpyrrolidone K30 into it, stir and mix evenly;

[0042] 2) Dilute the above solution with deionized water until the solid content of silica is about 1.2%, stir and mix evenly;

[0043] 3) Add 0.05% (volume ratio) of alkoxy-modified polytrisiloxane and 0.01% (volume ratio) of silane coupling agent KH-570 to the above solution in turn, mix well and set aside.

[0044] 2. Preparation of self-cleaning curtain wall glass:

[0045] Take prepared SiO 2 The self-cleaning coating solution is evenly sprayed on the clean glass substrate, then baked with hot air at 80°C for 1 minute, and finally cured according to the glass tempering process to obtain the self-cleaning curtain wall glass.

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Abstract

The invention relates to an SiO2 based self-cleaning paint and a self-cleaning glass, and a preparation method thereof. The preparation method of the self-cleaning paint comprises: 1) adding polyvinylpyrrolidone into a waterborne silica sol with a particle size of 8-20nm and a solid content of 1.5-10%, keeping the mass ratio of the polyvinylpyrrolidone to the silica at 1:0.5-10, stirring them fully to make them evenly mixed; 2) diluting the solution to a silica solid content of 0.8-1.5%; and 3) adding alkoxy modified polytrisiloxane and a silane coupling agent into the diluted solution in order, mixing them evenly so as to obtain the self-cleaning paint. Then the self-cleaning paint is employed to form a film on a glass surface by a spray coating technology, and then curing treatment is carried out so as to obtain the self-cleaning glass. The self-cleaning film layer formed in the invention is firmly combined with the glass substrate, has excellent weather resistance and a super hydrophilic effect, can effectively remove dirt on the surface, and can be used in the building glass field.

Description

technical field [0001] The invention belongs to the technical field of functional materials, in particular to a SiO 2 Self-cleaning coatings and self-cleaning glass, and methods for their preparation. Background technique [0002] With the awareness of the harm of environmental degradation to human life and the improvement of environmental protection requirements, people have more and more urgent requirements for the use of green building materials that are environmentally friendly, use natural conditions to achieve automatic cleaning, and can beautify the environment. . Glass curtain wall is favored by architects because of its functional and decorative advantages, but the cleaning of glass curtain wall is a headache. Using detergent to clean glass not only pollutes the environment, but also wastes a lot of water resources. Self-cleaning glass relying on natural water washing is the most effective way to fundamentally solve glass cleaning. Most of the self-cleaning glass...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D139/06C09D7/12C09D5/00C03C17/30
Inventor 王丹李智文胡柱东陈铭波江文俊梁衍忠江坚
Owner GUANGDONG SOUTH BRIGHT GLASS TECH