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Method for preparing carbon nano tube/poly (3-hexyl) thiophene composite thermoelectric materials

A technology of thermoelectric materials and zirconia, which is applied in the field of preparation of CNT/P3HT composite thermoelectric materials, can solve the problems of easy pollution of the environment and a large amount of organic solvents, and achieve the effect of simple process and broad market prospects

Inactive Publication Date: 2014-01-08
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] At present, the main methods for preparing conductive polymer-CNT composites are in-situ polymerization, solution mixing, and casting, but these methods need to use a large amount of organic solvents, which are easy to pollute the environment

Method used

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  • Method for preparing carbon nano tube/poly (3-hexyl) thiophene composite thermoelectric materials
  • Method for preparing carbon nano tube/poly (3-hexyl) thiophene composite thermoelectric materials
  • Method for preparing carbon nano tube/poly (3-hexyl) thiophene composite thermoelectric materials

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] (1) Ingredients: First, 48.55g zirconia grinding balls with a diameter of 2mm and 7.71g FeCl 3 Add it into a zirconia ball milling jar with a volume of 100 mL, and after mixing evenly, add 2 g of 3-HT monomer dropwise, seal the ball milling jar and put it into a ball mill for ball milling.

[0038] (2) Ball milling; the technical parameters of ball milling are: 100 rpm for 30 minutes of rotation speed, and then 500 rpm for 10 minutes of rotation speed.

[0039] (3) Centrifugation and washing; after the ball milling, transfer the balls and reactants in the ball milling jar to a beaker, add deionized water and stir, take out the zirconia grinding balls from the beaker with tweezers, and then apply the tweezers to the beaker. The black product was washed with deionized water, centrifuged, and the washing and centrifugation steps were repeated until the upper solution in the centrifuge tube was colorless,

[0040] (4) Drying. Put the centrifuge tube together with the prod...

Embodiment 2

[0043] (1) Ingredients: First, 76g zirconia grinding balls with a diameter of 2mm and 8.10g FeCl 3 Put it into a zirconia ball milling jar with a volume of 200 mL, then add 0.6 g of MWCNT, after mixing evenly, add 1.4 g of 3-HT monomer dropwise, seal the ball milling jar and put it into a ball mill for ball milling.

[0044] (2) Ball milling; the technical parameters of ball milling are: the speed of 300rpm, the time of 60min, then the speed of 1000rpm, and the time of 10min.

[0045] (3) Centrifugation and washing; after the ball milling, transfer the balls and reactants in the ball milling tank to the beaker, add deionized water and stir, take out the zirconia grinding balls from the beaker with tweezers, and then apply the tweezers to the beaker. The black product was washed with deionized water, centrifuged, and the washing and centrifugation steps were repeated until the upper solution in the centrifuge tube was colorless,

[0046] (4) Drying. Put the centrifuge tube an...

Embodiment 3

[0050] (1) Ingredients: First, 87.1g of zirconia grinding balls with a diameter of 2mm and 7.71g of FeCl were mixed 3 Add it into a zirconia ball milling jar with a volume of 200 mL, then add 1.0 g MWCNT, after mixing evenly, add 1.0 g 3-HT monomer dropwise, seal the ball milling jar and put it into a ball mill for ball milling.

[0051] (2) Ball milling; the technical parameters of the ball milling are: rotation speed 300rpm, time 30min, then rotation speed 500rpm, time 30min.

[0052] (3) Centrifugation and washing; after the ball milling, transfer the balls and reactants in the ball milling jar to a beaker, add deionized water and stir, take out the zirconia grinding balls from the beaker with tweezers, and then apply the tweezers to the beaker. The black product was washed with deionized water, centrifuged, and the washing and centrifugation steps were repeated until the upper solution in the centrifuge tube was colorless,

[0053] (4) Drying. Put the centrifuge tube and...

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Abstract

The invention belongs to the field of conductive macromolecule-inorganic nano-structure composite thermoelectric materials, and relates to a method for preparing carbon nano tube / poly (3-hexyl) thiophene (CNT-P3HT) composite thermoelectric materials. The method comprises the steps of adding zirconia grinding balls and the moderate amount of oxidants into a zirconia ball grinding tank, adding the CNT, conducting mixing uniformity, then dropwise adding the moderate amount of 3-HT monomers, placing the sealing ball grinding tank in a ball grinding machine to conduct ball grinding after the ball grinding tank is sealed, after finishing the ball grinding, transferring the balls and reactants in the ball grinding tank to a beaker, adding deionized water into the beaker to conduct stirring, washing black products in the beaker by the deionized water, conducting centrifuging until a supernatant is colorless, and then conducting vacuum drying. The prepared CNT / P3HT composite powder is compressed to be block-shaped composite materials. The process is simple and environmentally friendly, and large-scale production can be easily achieved. The synthetized CNT / P3HT composite thermoelectric materials can be widely applied to thermoelectric cooling and power generation equipment with the temperature lower than 150 DEG C, and the market prospect is wide.

Description

technical field [0001] The invention belongs to the field of conductive polymer-inorganic nanostructure composite thermoelectric materials, and relates to a preparation method of a CNT / P3HT composite thermoelectric material. Background technique [0002] Thermoelectric materials are functional materials that can realize direct conversion between thermal energy and electrical energy through the transport of carriers (holes or electrons) in solids. The application of thermoelectric materials does not require the use of transmission components, the structure is simple, the size can be made small, there is no noise during operation, no waste, and no pollution to the environment, and this material also has excellent characteristics such as long service life and reliable performance. . Therefore, thermoelectric materials are a class of environmentally friendly materials with broad application prospects and are considered to be very competitive energy alternative media in the futu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L35/34H10N10/01
Inventor 蔡克峰杜永
Owner TONGJI UNIV
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