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Micro-nano oxide particle enhanced nickel base alloy powder as well as preparation method thereof

A technology of micro-nano oxides and micro-nano particles, which is applied in the field of nickel-based alloys, can solve the problems of unseen special combination powder for laser cladding, easy segregation during storage, transportation and use, uneven cladding layer structure and performance, etc. , to achieve excellent laser cladding process performance, reduce laser cladding costs, and achieve the effect of grain refinement

Inactive Publication Date: 2014-01-22
江苏盛伟模具材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The added hard particles are larger and different in density from the matrix metal, and the distribution of the particles in the cladding layer is often uneven, usually showing a gradient distribution; the wettability, stability, and expansion coefficient of the added particle material and the matrix and chemical reactivity all lead to the inhomogeneity of the structure and performance of the cladding layer
Moreover, the prepared combined powder is prone to segregation during storage, transportation and use due to the large difference in the specific gravity of each component.
Commercial market supply cannot be carried out, and there is no commercial sale of micro-nano particle-enhanced laser cladding special powder in the market
Due to the above reasons, there is no special combination powder for laser cladding, which restricts the application of laser cladding in the field of high wear-resistant conditions.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] A nickel-based alloy powder reinforced with micro-nano oxide particles and a preparation method thereof. The nickel-based alloy powder reinforced with micro-nano oxide particles is composed of matrix alloy powder, micro-nano oxide particles and a binder, and the proportion thereof is: 60% matrix alloy powder, 37% micro-nano Al 2 o 3 , 3% phenolic resin binder is prepared into combined powder; wherein the nanoparticle content in the micro-nanoparticles is 20-30%; wherein the chemical composition and mass percentage of the matrix alloy are;

[0054] 0.5%C, 2%Si, 1.5%B, 14%Cr, 6%Cu, 0.5%Sn, 13%Fe, 0.1%MgO, 0.5%CaF 2 , 0.2% CeO 2 , 0.2%Y 3 o 2 , 0.2% La 2 o 3 , Ni balance.

[0055] Its manufacturing process steps:

[0056] Preparation of matrix alloy powder→adding micronano oxide particles→adding binder→stirring ball milling→combining powder→drying→crushing→sieving; the specific process steps are as follows:

[0057] (1) Preparation of matrix alloy

[0058] The pr...

Embodiment 2

[0076] A nickel-based alloy powder reinforced with micro-nano oxide particles and a preparation method thereof. The nickel-based alloy powder reinforced with micro-nano oxide particles is composed of matrix alloy powder, micro-nano oxide particles and a binder, and the proportion thereof is: 68% matrix alloy powder, 30% micro-nano ZrO 2 , 2% epoxy resin binder is prepared into a combined powder; wherein the nanoparticle content in the micro-nanoparticles is 20-30%; wherein the chemical composition and mass percentage of the matrix alloy are;

[0077] 0.6%C, 3%Si, 2.5%B, 16%Cr, 7%Cu, 1%Sn, 15%Fe, 0.15%MgO, 0.9%CaF 2 , 0.25% CeO 2 , 0.25%Y 3 o 2 , 0.25% La 2 o 3 , Ni balance.

[0078] (2) Add micronano oxide particles

[0079] Select the commercially available micronano ZrO with a particle size range of -300 mesh 2 The powder is used as reinforced hard particles; the content of nanoparticles in the micro-nano particles is 20-30%;

[0080] (3) Add binder

[0081] Use th...

Embodiment 3

[0086] A nickel-based alloy powder reinforced with micro-nano oxide particles and a preparation method thereof. The nickel-based alloy powder reinforced with micro-nano oxide particles is composed of matrix alloy powder, micro-nano oxide particles and a binder, and the proportion thereof is: 68% matrix alloy powder, 30% micro-nano Al 2 o 3 and micronano ZrO 2 The formed micro-nano hybrid powder is made, and 2% epoxy resin binder is prepared into a combined powder; wherein the nano-particle content in the micro-nano particles is 20-30%; wherein the chemical composition and mass percentage of the matrix alloy are ;

[0087] 0.4%C, 2.8%Si, 2.0%B, 18%Cr, 8%Cu, 0.7%Sn, 10%Fe, 0.2%MgO, 1.5%CaF 2 , 0.3% CeO 2 , 0.3%Y 3 o 2 , 0.3% La 2 o 3 , Ni balance.

[0088] (2) Add micronano oxide particles

[0089] Select a commercially available 50% micro-nano Al with a particle size range of -200 mesh 2 o 3 and 50% micronano ZrO 2 Composition of micro-nano hybrid powder as reinfor...

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Abstract

The invention relates to micro-nano oxide particle enhanced nickel base alloy powder as well as a preparation method thereof. The micro-nano oxide particle enhanced nickel base alloy powder is characterized in that the micro-nano oxide particle enhanced nickel base alloy powder contains matrix alloy powder and micro-nano oxide hard particles as well as a binder. The micro-nano oxide particle enhanced nickel base alloy powder is prepared from the following components in percent by weight: 50-98% of the matrix alloy powder, 1-45% of combined mixture powder of one or more than two out of micro-nano Al2O3 or micro-nano Cr3C2 and micro-nano ZrO2, and 1-5% of the binder which are prepared as combined powder. The preparation process comprises the following steps: preparation of the matrix alloy powder; addition of the micro-nano particle particles; addition of the binder; stirring and ball-milling; combination of powder; drying; crushing; sieving. The micro-nano oxide particle enhanced alloy powder provided by the invention not only has higher hardness and tenacity, but also has excellent wear resistance and corrosion resistance, so that the powder is particularly applicable to laser-cladding parts in high impact and high-wear-resisting working conditions. The powder can effectively prevent segregation in the storage, transportation and using processes due to wide difference of the components in proportion.

Description

technical field [0001] The invention belongs to the technical field of nickel-based alloys, and relates to an alloy powder and a preparation method thereof, in particular to a nickel-based alloy powder reinforced with micronano oxide particles and a preparation method thereof, the micronano oxide particle reinforced nickel The base alloy powder is suitable for laser cladding parts with high impact and high wear resistance. Background technique [0002] In modern daily life and industrial production, wear and corrosion of metal materials will appear in various fields. It is one of the two main ways to damage mechanical parts and engineering components. Corrosion will lead to a large amount of consumption of mechanical parts, while wear It is one of the important reasons leading to the failure of mechanical parts. While they consume a lot of metal materials, they also waste a lot of resources, accounting for a very large proportion of economic losses. [0003] The failure of...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C19/05C22C32/00B22F1/00C23C24/10
Inventor 丁刚丁家伟耿德英张莹符寒光谢宗翰王爱华郭洪才印杰孙健张宁强颖怀郭长庆
Owner 江苏盛伟模具材料有限公司
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