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Methods to enhance the properties of tial intermetallic compounds

An intermetallic compound and performance technology, applied in the enhancement field of TiAl intermetallic compounds, can solve the problems of uneven strength and segregation, and achieve the effects of increased strength, stable process and uniform structure

Inactive Publication Date: 2016-08-17
ZHONGYUAN ENGINEERING COLLEGE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved by the present invention is to overcome the deficiencies such as segregation, unevenness and low strength of the existing cast TiAl structure, and provide a method of adding C element powder and Si element powder to TiAl powder to obtain in-situ SiC reinforced TiAl composite material

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] Cast TiAl 5kg, crushed by a jaw crusher for 10 hours, and the crushing process was divided into three stages, and passed through an 80-mesh sieve to obtain TiAl powder; ball milled the TiAl powder for 70 hours, and then sieved 200 mesh to obtain TiAl fine powder; TiAl Fine powder, 0.375kg C powder, and 0.875kg Si powder were mixed evenly, and high-energy mechanical alloying was carried out for 72hrs to obtain composite powder; the composite powder was sintered by hot pressing at 1000-1500°C and 10MPa to obtain in-situ SiC reinforced TiAl composite material. The tensile strength is increased from 400MPa to 450MPa, the fracture toughness is increased by 10%, and the brittleness is improved.

Embodiment 2

[0014] Cast TiAl 5 kg, crushed by a jaw crusher for 12 hr, and passed through an 80-mesh sieve. The above powder was ball milled for 72 hrs, and passed through a 200-mesh sieve. The obtained TiAl fine powder, 0.225 kg C powder and 0.525 kg Si powder were uniformly mixed, and then high-energy mechanical alloying was performed for 72 hr. The obtained alloy powder was hot-pressed and sintered at 1200° C. for 2.5 hr at a pressure of 12 MPa to obtain a SiC-reinforced TiAl composite material.

[0015] The tensile strength of the composite material is increased from 400MPa to 440MPa, the fracture toughness is increased by 10%, and the brittleness is improved.

Embodiment 3

[0017] Cast TiAl 4 kg, crushed by a jaw crusher for 10 hr, and passed through an 80-mesh sieve. The above powder was ball milled for 70 hrs, and passed through a 200-mesh sieve. The obtained TiAl fine powder, 0.3 kg C powder and 0.7 kg Si powder were evenly mixed, and then high-energy mechanical alloying was performed for 70 hr. The obtained alloy powder was hot-pressed and sintered at 1200°C for 2.0 hr at a pressure of 10 MPa to obtain a SiC-reinforced TiAl composite material.

[0018] The tensile strength of the composite material is increased from 400 MPa to 500 MPa, the fracture toughness is increased by 10%, and the brittleness is improved.

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PUM

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Abstract

A method for enhancing the performance of TiAl intermetallic compounds, by pulverizing cast TiAl, ball milling, and sieving to obtain TiAl fine powder, and then adding Si powder and C powder with a molar weight of 1:1 to the TiAl fine powder, Si powder and The ratio of the total mass of C powder to the total mass of TiAl fine powder, Si powder and C powder is not more than 30%, and then mechanically alloyed, and the resulting composite powder is sintered by hot pressing at 1000-1500°C and 5-15 MPa for 2- The SiC reinforced TiAl composite material was obtained in 3 hr. The obtained composite material has the characteristics of uniform structure, high strength and stable process, and is suitable for industrial scale.

Description

technical field [0001] The invention belongs to the technical field of improving the strength of TiAl, and in particular relates to a strengthening method of TiAl intermetallic compounds. Background technique [0002] TiAl is an emerging metal compound structural material, which has the characteristics of low density and high specific strength; it can still maintain a certain strength and stiffness at higher temperatures, and it also has good creep resistance and oxidation resistance. It is one of the most competitive materials for heat-resistant structural parts of engines used in aerospace, aviation and automobiles. [0003] Although TiAl has many advantages and has made many important breakthroughs in technology, there are still many performance problems to be solved. For example, TiAl has relatively low high-temperature strength, tensile strength, and plasticity for high-temperature components used above 1000 °C. It has an inverse relationship with fracture / creep resist...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C32/00C22C1/05
Inventor 张小立徐向俊郭建穆云超刘英张瑞杰
Owner ZHONGYUAN ENGINEERING COLLEGE