Polyurethane wood substitution composition

A technology of polyurethane and composition is applied in the field of manual preparation of the model products, which can solve the problems such as short operating time of pasty wood substitutes, and achieve the effects of good hardness and good mechanical properties.

CN103665313AInactive Publication Date: 2014-03-26COVESTRO DEUTSCHLAND AG
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Patent Information

Authority / Receiving Office
CN · China
Current Assignee / Owner
Publication Date
2014-03-26
Estimated Expiration
Not applicable · inactive patent

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Abstract

The invention relates to a polyurethane wood substitution composition which comprises: (a) one or more organic polyisocyanate(s); (b) one or more polyether polyol(s), wherein the degree of functionality of the polyether polyols is 2-6 and the hydroxyl value of the same is 100-700; the one or more polyether polyol(s) is / are homopolymerized and / or copolymerized products of an alkylene oxide compound and an amido-free polyhydric alcohol compound; (c) one or more aliphatic polyester polyol(s), wherein the hydroxyl value of the aliphatic polyester polyols is 100-500, and the degree of functionality of the same is 2-4; (d) optional one or more thixotropic agent (s); (e) optional one or more dehumidizer(s); (f) optional one or more microsphere(s), wherein the density of the microspheres is 20-500kg / m<3>. The polyurethane composition provided by the invention has long gelation time; the prepared polyurethane wood substitution has high hardness and high glass-transition temperature.
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Description

technical field

[0001] The present invention relates to a polyurethane substitute wood composition, and a molded article prepared from the polyurethane substitute wood composition, the molded article comprising polyurethane substitute wood with improved physical and process properties; the present invention also relates to the manual preparation of said molded article Methods. Background technique

[0002] Paste substitute wood is a paste resin material system, which usually uses polyester or epoxy resin to add fillers such as glass beads to form a paste. After the paste is mixed with a curing agent and cured, it has good Toughness, hardness, dimensional stability, temperature resistance, compressive strength, flexural strength and other physical properties, as well as good machinability, are often used in the manufacture of models, molds or gages. Polyurethane paste substitute wood is a paste material system formed by filling fillers with polyurethane resin.

[0003] Pate...

Examples

Embodiment 1

[0112] Embodiment 1: adopt the following steps to implement. Prepare 1000g of materials according to the weight percentages shown in Table 1, and mix them by hand. All operations (weighing and mixing) were performed at room temperature in a fume hood (temperature 20-25°C, relative humidity 45% to 55%).

[0113] 300g of the mixed material was horizontally applied to a vertical surface of a foam substrate with a thickness of 20mm, 30mm, 40mm and 50mm to evaluate its anti-sag performance.

[0114] Apply 500g of the mixed material to a foam substrate with a thickness of 30mm. After curing at room temperature for 12 hours, use a CNC machine tool to process it into a designed shape, and use an electronic magnifying glass to observe its surface quality.

[0115] The remaining 200g material is used to test Shore D hardness and density, the test standards are ISO868:2003 and ISO2781:1996 respectively

[0116] The operation method of embodiment 2-6 is the same as embodiment 1, and con...