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Low-hysteresis-loss crown compound for solid tyres of heavy trucks

A solid tire, low hysteresis technology, applied in the field of crown rubber with low hysteresis loss, can solve the problems of accelerated wear, increased heat generation, overvulcanization, etc.

Inactive Publication Date: 2014-03-26
SHANDONG YONGTAI CHEM GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Heavy-duty trucks are often overloaded during use, which leads to increased deformation and creep of the tires. With the increase of deformation and creep, the rolling resistance of the tires will also increase, resulting in a decrease in vehicle speed. , the energy consumption accelerates
Although the high-modulus rubber compound with better reinforcing performance can be obtained by selecting the appropriate carbon black variety and dosage, and the deformation of the tire can be reduced at the same time, but the increase in hysteresis loss will also affect the rolling resistance. Therefore, it is necessary to use high modulus and low To strike a balance between hysteresis loss, solid tires must also have good wear and tear resistance
[0003] Solid tires need a longer vulcanization time to ensure that the central part of the tread rubber reaches the ideal degree of vulcanization. This long-term vulcanization has a great impact on the performance of the tire, which will cause over-vulcanization on the surface of the tread and a certain depth in the lower part of the tread. , although vulcanization reversion usually does not significantly decrease the surface hardness during inspection, but during the use of the tire, that is, under dynamic conditions, the rapid decrease in hardness and modulus will lead to accelerated wear, increased rolling resistance and increased heat generation, while heat generation It will further reduce the modulus and hardness

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0085] A low-hysteresis-loss crown rubber for heavy-duty solid tires, which consists of the following raw materials in proportions by weight:

[0086] 31 parts of natural rubber

[0087] EPDM rubber 54 parts

[0088] Carbon black N550 28 parts

[0089] 7 parts ester oil

[0090] Poly-2,3,4-trimethyl-1,2-dihydroquinoline 1.5 parts

[0091] Microcrystalline wax 1.0 parts

[0092] 0.7 p-aminobenzoic acid

[0093] Zinc oxide 4 parts

[0094] Zinc stearate 4 parts

[0095] 1.5 parts of N-tert-butylbenzothiazole-2-sulfenamide

[0096] Sulfur 1.5 parts

[0097] 0.4 parts of N-cycloethylthiophthalimide

[0098] Flat clay 15 parts

[0099] Polyolefin fiber 8 parts.

[0100] Using the low hysteresis loss crown rubber for heavy truck solid tires described in Example 1, the 100% constant elongation strength is 3.8MPa, and the retention rate is 92%; the 300% constant elongation strength is 16.8MPa, and the retention rate is 96.5%; Tensile strength is 26MPa, retention rate is 89.5...

Embodiment 2

[0102] The low hysteresis loss crown rubber used for heavy truck solid tires is composed of the following raw materials in proportions by weight:

[0103] 31.6 parts of natural rubber

[0104] EPDM rubber 54.9 parts

[0105] Carbon black N550 28.6 parts

[0106] 7.3 parts of ester oil

[0107] Poly-2,3,4-trimethyl-1,2-dihydroquinoline 1.8 parts

[0108] Microcrystalline wax 1.3 parts

[0109] 0.85 p-aminobenzoic acid

[0110] Zinc oxide 4.7 parts

[0111] Zinc stearate 4.8 parts

[0112] 1.6 parts of N-tert-butylbenzothiazole-2-sulfenamide

[0113] Sulfur 1.9 parts

[0114] N-cycloethylthiophthalimide 0.46 parts

[0115] Flat clay 15.2 parts

[0116] Polyolefin fiber 8.3 parts.

[0117] Using the low hysteresis loss crown rubber for heavy truck solid tires described in Example 2, the 100% constant elongation strength is 3.96MPa, and the retention rate is 93.6%; the 300% constant elongation strength is 17.3MPa, and the retention rate is 97.6%; The tensile strength i...

Embodiment 3

[0119] The low hysteresis loss crown rubber used for heavy truck solid tires is composed of the following raw materials in proportions by weight:

[0120] 34.3 parts of natural rubber

[0121] EPDM rubber 56.4 parts

[0122] Carbon black N550 29.7 parts

[0123] 8.9 parts of ester oil

[0124] Poly-2,3,4-trimethyl-1,2-dihydroquinoline 1.72 parts

[0125] Microcrystalline wax 1.1 parts

[0126] 0.9 p-aminobenzoic acid

[0127] Zinc oxide 6.2 parts

[0128] Zinc stearate 5.7 parts

[0129] 1.9 parts of N-tert-butylbenzothiazole-2-sulfenamide

[0130] Sulfur 1.74 parts

[0131] N-cycloethylthiophthalimide 0.52 parts

[0132] Flat clay 16.4 parts

[0133] Polyolefin fiber 9.2 parts.

[0134] Using the low hysteresis loss crown rubber for heavy truck solid tires described in Example 3, the 100% constant elongation strength is 4.1MPa, and the retention rate is 94.3%; the 300% constant elongation strength is 18.2MPa, and the retention rate is 97.3%; The tensile strength i...

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Abstract

The invention belongs to the technical field of rubber production, and particularly relates to a low-hysteresis-loss crown compound for solid tyres of heavy trucks. The low-hysteresis-loss crown compound for the solid tyres of the heavy trucks comprises raw materials in parts by weight as follows: natural rubber, ethylene propylene diene monomer, carbon black N550, ester oil, poly-2,3,4-trimethyl-1,2-dihydroquinoline, microcrystalline wax, para aminobenzoic acid, zinc oxide, zinc stearate, N-tert-butylbenzothiazole-2-sulfenamide, sulfur, N-cyclohexylthiophthalimide, flat pottery clay and polyolefin fibers. The crown compound has the excellent rebound resilience, so that the lower hysteresis loss is obtained; and meanwhile, the reversion resistance is kept good, the performance retention rate is basically unchanged and kept at the higher level, and the excessive sulfur phenomenon is avoided.

Description

technical field [0001] The invention belongs to the technical field of rubber production, in particular to a low-hysteresis-loss crown rubber used for heavy-duty solid tires. Background technique [0002] Heavy-duty solid tires require lower rolling resistance, the purpose is to ensure the maximum speed and working time of the vehicle, although the tire tread shape, crown radius, tread design and tread thickness have a lot to do with obtaining these properties , but to obtain the best results must also use the appropriate rubber formulations. Heavy-duty trucks are often overloaded during use, which leads to increased deformation and creep of the tires. With the increase of deformation and creep, the rolling resistance of the tires will also increase, resulting in a decrease in vehicle speed. , energy consumption is accelerated. Although a high-modulus rubber compound with better reinforcement performance can be obtained by selecting an appropriate carbon black variety and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/16C08L7/00C08K13/02C08K3/04C08K5/18C08K3/22C08K5/098C08K5/47C08K3/06C08K5/378C08K3/34
CPCC08L23/16C08L2205/035C08L2205/16C08L7/00C08L91/06C08L23/00C08K13/02C08K3/04C08K5/18C08K2003/2296C08K5/098C08K5/47
Inventor 尤晓明李洋刘国华张兰鹏葛汝海燕纪祥
Owner SHANDONG YONGTAI CHEM GROUP
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