Nanostructured articles and methods to make the same
A product, sub-micron technology, applied in the fields of nanotechnology, nano-optics, nanotechnology, etc., can solve the problems of reduced display quality, high haze, etc., and achieve the effect of enhanced optical performance and low stripe effect
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[0270] Process 1: Vacuum plasma treatment plasma heating batch reactor
[0271] A batch plasma system (available from Oerlikon, St. Petersburg, FL under the trade designation "PLASMATHERM" (model 3032)) configured for reactive ion etching (RIE) with 68.6 cm (27 in.) low-level power electrodes and central air pump. The chamber was pumped by a dry mechanical pump (available as model iQDP80 from Edwards Vacuum) via a Roots blower (available as model EH1200 from Edwards Vacuum, Tewsbury, MA). Do the pumping. RF power was provided by a 3 kW, 13.56 Mhz solid-state generator (commercially available under the trade designation "RFPP" (model RF30H) from Advanced Energy, Fort Collins, CO) through an impedance-matched network. The system has a nominal base pressure of 5 mTorr. The flow rate of the gas was controlled by a flow rate controller (commercially available from MKS Instruments, Woburn, MA) under the trade designation "MKS 1179".
[0272] A substrate for plasma treatment is...
example 18
[0303] 450 g of 1-methoxy-2-propanol, 6 g of 3-(methacryloxy)propyltrimethoxysilane, and 0.16 g of a 5% aqueous solution of hindered amine nitroxide inhibitor (“PROSTAB5128”) Mix together with 190nm silica dispersion ("MP2040") while stirring. The solution was sealed in a jar and heated to 80°C and held at that temperature for 16 hours. Water and 1-methoxy-2-propanol were removed from the mixture by rotary evaporation. The resulting dry, surface-functionalized silica particles were redispersed into an 88 / 12 1-methoxy-2-propanol / water mixture, then sonicated and filtered to form a 42.4% by weight solid dispersion.
[0304] A monomer blend of pentaerythritol triacrylate, 1,6-hexanediol diacrylate and isobornyl acrylate ("SR444", "SR238", "SR506", respectively) was mixed in a 40 / 40 / 20 ratio with Dispersions of 190 nm silica particles modified with 3-(methacryloxy)propyltrimethoxysilane were blended to form 65% by weight of 3-(methacryloxy)propyltrimethoxysilane Oxysilane-modif...
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