Long-acting active sand-controlling oil washing agent and preparation method thereof

A surfactant and active technology, applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve problems such as the decrease of formation cementation strength, serious sand production in the formation, and aggravate the migration of formation particles, so as to achieve obvious oil washing effect , the effect of high consolidation strength

Active Publication Date: 2014-06-25
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This type of reservoir is mostly muddy and calcareous cemented, and the rock cementation strength is relatively weak. Especially in the middle and late stages of development, a part of the cement between the sand grains is dissolved during long-term water injection development, which reduces the cementation strength of the formation, and rocks are prone to Destruction of sand production; at the same time, the injection of oil displacement media such as polymers, lye, and surfactants currently used will intensify the migration of formation particles to varying degrees, and the formation of sand production will be more serious. The rock particles near the wellbore are partially static, affecting Subsequent modification and production development effect
Studies have shown that chemical sand-consolidating agents are affected by the adhesion of formation crude oil and the electrostatic adsorption of residual polymers in the formation, resulting in incomplete consolidation of the sand-consolidating agent on the surface of the formation sand grains, resulting in a short effective period of sand control. According to statistics, the current overall effective period of chemical sand control is less than one year. year

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] The preparation method of this long-acting active sand control oil washing agent is carried out as follows:

[0028] a. Dissolve 0.3 parts by weight of 3-chloropropyltriethoxysilane in 10 parts by weight of n-hexane and put it into the reaction kettle, then add 5 parts by weight of polyethylene polyamine and 2 parts by weight of The sodium p-hydroxybenzenesulfonate was reacted with rapid stirring for 1 hour, and cooled to room temperature after the reaction to obtain the reaction product A;

[0029] b. Dissolve 3 parts by weight of polyacrylamide in water to form an aqueous solution with a weight content of 50%, then drop 3 parts by weight of formaldehyde into the solution, and then add 0.1 parts by weight of KOH (prepared to a weight content of 15% Aqueous solution), carry out the hydrolysis reaction in the reaction kettle at 80°C for 1 hour, and cool to room temperature to obtain the reaction product B;

[0030] c. Mix reaction product A and reaction product B, pum...

Embodiment 2

[0032] The preparation method of this long-acting active sand control oil washing agent is carried out as follows:

[0033] a. Dissolve 0.6 parts by weight of 3-chloropropyltriethoxysilane in 5 parts by weight of n-hexane and put it into the reaction kettle, then add 3 parts by weight of polyethylene polyamine and 5 parts by weight of The sodium p-hydroxybenzenesulfonate was reacted with rapid stirring for 2 hours, and cooled to room temperature after the reaction to obtain the reaction product A;

[0034] b. Dissolve 5 parts by weight of polyacrylamide in water to form an aqueous solution with a weight content of 50%, then drop 1 part by weight of formaldehyde into the solution, and then add 0.3 parts by weight of KOH (prepared to a weight content of 25% Aqueous solution), carry out the hydrolysis reaction in the reaction kettle at 70°C for 2 hours, and cool to room temperature to obtain the reaction product B;

[0035] c. Mix reaction product A and reaction product B, pum...

Embodiment 3

[0037] The preparation method of this long-acting active sand control oil washing agent is carried out as follows:

[0038] a. Dissolve 0.4 parts by weight of 3-chloropropyltriethoxysilane in 7 parts by weight of n-hexane and put it into a reaction kettle, then add 4 parts by weight of polyethylene polyamine and 4 parts by weight of The sodium p-hydroxybenzenesulfonate was reacted with rapid stirring for 1.5 hours, and cooled to room temperature after the reaction was completed to obtain the reaction product A;

[0039] b. Dissolve 4 parts by weight of polyacrylamide in water to form an aqueous solution with a weight content of 50%, then drop 2 parts by weight of formaldehyde into the solution, and then add 0.2 parts by weight of KOH (prepared to a weight content of 20% Aqueous solution), carry out the hydrolysis reaction at 75°C for 1.5 hours in the reaction kettle, and cool to room temperature to obtain the reaction product B;

[0040] c. Mix reaction product A and reacti...

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Abstract

The invention relates to a long-acting active sand-controlling oil washing agent and a preparation method thereof. The sand-controlling oil washing agent is composed of the following raw materials in percent by mass: 3-5 parts of a long-chain fatty acid ammonium salt, 0.3-0.6 part of a silane coupling agent, 3-5 parts of a poly-amino compound, 1-3 parts of formaldehyde, 2-5 parts of a water soluble surfactant, 0.1-0.3 part of a hydroxide, 0.2-0.5 part of hydrochloric acid and 5-10 parts of hexane. The sand-controlling oil washing agent is synthesized by employing a three-step method. The action principle comprises that the surfactant is absorbed on rock and displaces crude oil originally attaching to rock, so that crude oil falls off from the surface of rock, and the purpose of washing oil is realized; excess ammonium ions are absorbed on the surface of clay, so that the electrostatic repulsion force on the surface of clay is counteracted and clay is stabilized; and also through the consolidation effect of generated sand-controlling oil-washing resin macro-molecules on sandstone, gravels are stabilized and consolidated.

Description

technical field [0001] The invention relates to a sand control and oil washing agent used for sand producing oil wells in oil fields, which belongs to oil field chemical agents for oil field stratum transformation and improvement of development effect; in addition, the invention also relates to a preparation method of the oil washing agent. Background technique [0002] The reserves of unconsolidated sandstone reservoirs account for about one-third of all oilfields. This type of reservoir is mostly muddy and calcareous cemented, and the rock cementation strength is relatively weak. Especially in the middle and late stages of development, a part of the cement between the sand grains is dissolved during long-term water injection development, which reduces the cementation strength of the formation, and rocks are prone to Destruction of sand production; at the same time, the injection of oil displacement media such as polymers, lye, and surfactants currently used will intensify ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/58
CPCC09K8/58
Inventor 吴琼魏芳张冰洋尚岩李鹏陈刚杨军郑铎
Owner CHINA PETROLEUM & CHEM CORP
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