Lupine-type triterpenoids, pharmaceutical compositions and applications thereof
A technology of lupinane type and compound is applied in the application field of lupinane type triterpenoids and medicines, and can solve the problems such as no activity of lupinane type triterpenoids.
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Embodiment 1
[0022] Preparation of Compounds 1 and 2:
[0023] Dried coral branches and 4kg of leaves were pulverized and extracted three times with 70% acetone water (each 30 liters) at room temperature, each for 2 days. Combine the extracts, distill off most of the organic solvents under reduced pressure, let stand overnight, filter out the deposited pigment, extract the filtrate three times with petroleum ether and ethyl acetate respectively, combine and concentrate to obtain about 305 g of ethyl acetate. Dissolve the ethyl acetate part with 95% ethanol, use MCI column to decolorize, decolorize, combine and evaporate to dryness to obtain about 268g sample, mix the sample with silica gel and put it on the silica gel column, with different ratios (1:0-0:1) of petroleum ether and Ethyl acetate was washed into the column, detected by TLC, and the same fractions were combined to obtain seven fractions. Wherein the second part is subjected to repeated silica gel column chromatography through...
Embodiment 2
[0031] In vitro insulin-sensitizing activity evaluation of compounds 1 and 2:
[0032] Drugs and reagents: DMEM medium, fetal bovine serum (FBS) and trypsin are Gibco products, the glucose determination kit (batch number 2012041) is the product of Changchun Huili Biotechnology Co., Ltd., and the CellCountingKit-8 (CCK-8) kit is Produced by Japan Tongren Co., Ltd., dexamethasone, insulin and DMSO are Sigma products, and rosiglitazone maleate is provided by Guangzhou Drug Control Institute.
[0033] Cell lines and cell culture: Adipocytes induced by differentiation of human hepatoma cell line HepG2 and mouse preadipocyte cell line 3T3-L1 were used as evaluation models. The culture medium of HepG2 cells was DMEM supplemented with 10% FBS and 2g / L glucose, and the culture medium of 3T3-L1 preadipocytes was high pond DMEM supplemented with 10% FBS. Cell culture conditions: 37°C, saturated humidity, 5% carbon dioxide incubator.
[0034] Drug action: (1) HepG2 cells in the logarith...
Embodiment 3
[0047] Compound 2 was prepared according to Example 1, and excipients were added at a weight ratio of 1:1 to the excipients, granulated and compressed into tablets.
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