Image forming apparatus and process cartridge
An imaging device and image technology, applied in electrography, optics, instruments, etc., can solve problems such as cleaning faults, charging faults, and image density imbalance, and achieve temperature rise suppression, upper film formation suppression, and adjacent adjacency suppression area effect
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manufacture Embodiment 1
[0295] (Production Example of Polyester Resin)
[0296] First, 517 parts of bisphenol A ethylene oxide 2mol adduct, 317 parts of terephthalic acid, 101 parts of ethylene glycol and 65 parts of hydrogenated bisphenol A were injected into the In the reaction chamber of the tube, the product was concentrated and reacted at 170° C. under atmospheric nitrogen flow for 10 hours, and then concentrated and reacted at a reaction temperature of 210° C. for 5 hours. Then, the product was continuously reacted for 5 hours while dehydrating under a reduced pressure of 0-15 mmHg, followed by cooling to obtain a polyester resin (PE1). For the obtained polyester resin (PE1), the weight-average molecular weight (Mw) of the THF-soluble portion was 2,900; the acid value was 5KOHmg / g, the glass transition point (Tg) was 43°C, and the weight-average molecular weight and glass transition The dot ratio (Mw / Tg) was 67. Also, the molar ratio of the benzene ring frame to the 1,4-cyclohexylene frame wa...
manufacture Embodiment 2
[0304] (Production Example of Polyester Resin)
[0305] There are 613 parts of bisphenol A ethylene oxide 2mol adduct, 322 parts of terephthalic acid; 13 parts of ethylene glycol; and 52 parts of hydrogenated bisphenol A injection with cooling tube, stirrer and nitrogen introduction The reaction chamber of the tube, and polyester resin (PE2) was obtained in the same manner as in Production Example 1. For the polyester resin (PE2) obtained, the weight-average molecular weight (Mw) of the THF-soluble portion was 5,800; the acid value was 38KOHmg / g, the glass transition point (Tg) was 59°C, and the weight-average molecular weight and glass transition point The ratio (Mw / Tg) was 98. Also, the molar ratio of the benzene ring frame to the 1,4-cyclohexylene frame was 13.5, and the molar ratio of the benzene ring frame to the ester-bonded alkylene frame at both ends was 27.0.
[0306] (Manufacture example of toner)
[0307] There are 85 parts of polyester (PE2), 15 parts of prepoly...
manufacture Embodiment 3
[0309] (Production Example of Polyester Resin)
[0310] There are 548 parts of bisphenol A ethylene oxide 2mol adduct, 296 parts of terephthalic acid; 44 parts of ethylene glycol; and 113 parts of hydrogenated bisphenol A injection with cooling tube, stirrer and nitrogen introduction The reaction chamber of the tube, and polyester resin (PE3) was obtained in the same manner as in Production Example 1. For the obtained polyester resin (PE3), the weight-average molecular weight (Mw) of the THF-soluble portion was 3,300; the acid value was 7KOHmg / g, the glass transition point (Tg) was 43°C, and the weight-average molecular weight and glass transition The dot ratio (Mw / Tg) was 77. Also, the molar ratio of the benzene ring frame to the 1,4-cyclohexylene frame was 5.6, and the molar ratio of the benzene ring frame to the ester-bonded alkylene frame at both ends was 7.5.
[0311] (Manufacture example of toner)
[0312] There are 83 parts of polyester resin (PE3), 17 parts of prepoly...
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