Sulfur/carbon coated lithium manganate cathode material and preparation method thereof

A positive electrode material, lithium manganate technology, applied in the field of lithium manganate positive electrode material and its preparation, can solve the problems of restricting development prospects, lack of manganese resources, high price, etc., and achieve the goal of prolonging storage time, improving self-discharge, and low cost Effect

Inactive Publication Date: 2014-09-24
QINGDAO QIANYUN HIGH TECH NEW MATERIAL
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  • Abstract
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  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Since the commercialization of lithium-ion batteries, most of the positive electrode materials used in lithium-ion batteries are lithium manganate, lithium manganate or ternary materials, etc., and its components are mainly active materials plus conductive agents and binders. The active materials It is lithium manganate, lithium manganate or ternary, etc.; most of the negative electrode materials use graphite as the active material, and then add some conductive agent and binder; i

Method used

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Example Embodiment

[0014] The sulfur / carbon coated lithium manganate cathode material is based on parts by weight and is prepared from the following components in the ratio shown: sulfur / carbon composite material 15-25, active material 80-85, functional material 5-10 , Conductive materials 3~5, bonding materials 3~5. The functional material is a 60% lithium iron nitrate solution. The positive electrode material is lithium manganate. The conductive agent is flake graphite

[0015] The preparation method of the sulfur / carbon coated lithium manganate cathode material includes the following steps:

[0016] (1) Put the carbon material and the sublimated sulfur or sulfur powder into the zirconium dioxide or agate ball milling tank according to the above-mentioned weight ratio. After injecting the high-purity inert gas into the ball milling tank in the glove box, place it on the planetary ball mill for ball milling for 5 hours. The ball milling speed is 500 r / min, and the mass ratio of elemental sulfur t...

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Abstract

The invention relates to a sulfur/carbon coated lithium manganate cathode material and a preparation method thereof. The sulfur/carbon coated lithium manganate cathode material is prepared from the following components in parts by weight: 15-25 parts of sulfur/carbon composite material, 80-85 parts of active material, 5-10 parts of functional material, 4-8 parts of conductive material and 4-8 parts of binding material, wherein the functional material is 60% lithium iron nitrate solution; the cathode material is lithium manganate; the conductive agent is flake graphite. The defect of failure of lithium ion batteries caused by self-discharge of protection boards is overcome by adopting the sulfur/carbon coated lithium manganate cathode material, thus improving self-discharge of the whole battery pack, achieving the aim of prolonging the lithium battery storage time and ensuring that the lithium batteries can be stored for a longer time under the condition that users do not charge the electric appliances after using the electric appliances.

Description

technical field [0001] The invention relates to a lithium manganate cathode material coated with sulfur / carbon and a preparation method thereof. Background technique [0002] Since the commercialization of lithium-ion batteries, most of the positive electrode materials used in lithium-ion batteries are lithium manganate, lithium manganate or ternary materials, etc., and its components are mainly active materials plus conductive agents and binders. The active materials It is lithium manganate, lithium manganate or ternary, etc.; most of the negative electrode materials use graphite as the active material, and then add some conductive agent and binder; its advantages are high capacity and long cycle life, but manganese resources are scarce and expensive And it is toxic, so it has become an important research direction for lithium-ion batteries to seek cheap, reliable, and environmentally friendly cathode materials. Spinel-type cathode materials represented by lithium manganat...

Claims

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Application Information

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IPC IPC(8): H01M4/505
CPCY02E60/122H01M4/386H01M4/505H01M4/587H01M10/0525Y02E60/10
Inventor 孙琦李岩孙慧英
Owner QINGDAO QIANYUN HIGH TECH NEW MATERIAL
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