Anisotropic conductive film, connecting method, and joined body
An anisotropic, conductive connection technology, applied in the direction of conductive adhesive connection, conductive adhesive, structural connection of printed circuits, etc., can solve problems such as color change and inability to fully confirm the connection state, and achieve excellent storage stability Effect
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Embodiment 1
[0150]
[0151] -Production of insulating adhesive layer-
[0152] 47 parts by mass of phenoxy resin (trade name: PKHC, manufactured by Pakistan Industrial Co., Ltd.), 44 parts by mass of urethane acrylate (trade name: EB-600, manufactured by Daicel Corporation), organic peroxide (trade name : 3 parts by mass of パーヘキサ C, manufactured by NOF Corporation, and 6 parts by mass of a color developer (trade name: D-8, manufactured by Nippon Soda Co., Ltd., melting point: 130° C.) were uniformly mixed. The mixed complex was coated on silicone-treated PET (polyethylene terephthalate) with a bar coater so that the average thickness after drying was 8 μm, and dried at 70°C for 5 minutes to produce Insulating adhesive layer.
[0153] -Formation of conductive particle-containing layer-
[0154] 45 parts by mass of phenoxy resin (trade name: PKHJ, manufactured by Pakistan Industrial Co., Ltd.), 46 parts by mass of urethane acrylate (trade name: EB-600, manufactured by Daicel Corporation...
Embodiment 2
[0178]
[0179] -Production of insulating adhesive layer-
[0180] 47 parts by mass of phenoxy resin (trade name: PKHC, manufactured by Pakistan Industrial Co., Ltd.), 38 parts by mass of urethane acrylate (trade name: EB-600, manufactured by Daicel Corporation), organic peroxide (trade name : 3 parts by mass of パーヘキサ C, manufactured by NOF Corporation) and 2 parts by mass of phosphoric acid ester (trade name: PM-21, manufactured by Nippon Kayaku Co., Ltd.) were uniformly mixed. The mixed acidic complex was coated on silicone-treated PET (polyethylene terephthalate) with a bar coater so that the average thickness after drying was 8 μm, and dried at 70° C. for 5 minutes. , making an acidic (pH5.4) insulating adhesive layer.
[0181] In addition, phosphoric acid ester is used to make pH acidic.
[0182] The insulating adhesive layer obtained above and the conductive particle-containing layer obtained in Example 1 were laminated at a roll temperature of 45° C. using a roll la...
Embodiment 3
[0186]
[0187] -Production of insulating adhesive layer-
[0188] 47 parts by mass of phenoxy resin (trade name: PKHC, manufactured by Pakistan Industrial Co., Ltd.), 38 parts by mass of urethane acrylate (trade name: EB-600, manufactured by Daicel Corporation), organic peroxide (trade name : 3 parts by mass of Pahekisa C, manufactured by NOF Corporation) and 2 parts by mass of a silane coupling agent (trade name: KBE-903, manufactured by Shin-Etsu Chemical Co., Ltd.) were uniformly mixed. The mixed basic complex was coated on silicone-treated PET (polyethylene terephthalate) with a bar coater so that the average thickness after drying was 8 μm, and dried at 70° C. for 5 Minutes to make an alkaline (pH9.2) insulating adhesive layer.
[0189] -Formation of conductive particle-containing layer-
[0190] 45 parts by mass of phenoxy resin (trade name: PKHJ, manufactured by Pakistan Industrial Co., Ltd.), 46 parts by mass of urethane acrylate (trade name: EB-600, manufactured ...
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