A device for continuously destroying radioactive waste organic solvents
An organic solvent and radioactive waste technology is applied in the field of devices for continuously destroying radioactive waste organic solvents. Effect
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Embodiment 1
[0038] A device for continuously destroying radioactive waste organic solvents, the device includes a constant temperature tank 1 with a temperature setting of 55°C and an electrochemical oxidation destruction container located inside the constant temperature tank 1, the container is mainly composed of an anode chamber with a sealed cover on the top 8. The cathode chamber 15 and the clarification chamber 2 are composed, wherein the volume ratio of the cathode chamber 15 and the clarification chamber 2 is 1:1, and the volume ratio of the anode chamber 8 and the cathode chamber 15 is 4:1.
[0039] The inside of the anode chamber 8 is equipped with a stirrer 9, the stirrer 9, the oxidizing medium adding pipe 10, the tail gas outlet pipe of the anode chamber and the anode electrode 3 all enter the anode chamber 8 through the hole on the sealing cover, wherein the anode electrode 3 is a platinum electrode; The interior of the anode chamber 8 is equipped with Ag + HNO 3 The solutio...
Embodiment 2
[0047] Different from Example 1, the volume ratio of the anode chamber and the cathode chamber is 10:1, containing Ag + HNO 3 The solution acts as an oxidation medium, where Ag + The concentration is 0.5mol / L, HNO 3 The concentration of the solution is 7mol / L, the concentration of the nitric acid solution in the cathode chamber is 5mol / L, and the temperature of the constant temperature bath is 65°C. The current density is 0.5A / cm 2 , the voltage is 10V.
Embodiment 3
[0049] Different from Example 1, the volume ratio of the anode chamber and the cathode chamber is 8:1, containing Ag + HNO 3 The solution acts as an oxidation medium, where Ag + The concentration is 0.8mol / L, HNO 3 The concentration of the nitric acid solution in the cathode chamber is 8mol / L, the concentration of the nitric acid solution in the cathode chamber is 7mol / L, and the temperature of the constant temperature bath is 60°C. The current density is 0.6A / cm 2 , the voltage is 15V.
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