Denitration catalyst

A denitration catalyst and catalyst technology, applied in the field of denitration catalysts, can solve the problems of increased power system energy consumption, cost increase, catalyst blockage, etc., and achieve the effects of simple installation, cost saving, and convenient replacement.

Active Publication Date: 2014-11-19
耘太环保科技(山东)股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The catalyst has low pressure drop, wear resistance and excellent denitrification activity and has been widely used, but the existing honeycomb catalyst has some shortcomings, and its optimum working temperature is generally 300-450 °C. In actual working conditions, it is difficult for the flue gas temperature to reach this temperature range. In order to obtain a better denitrification effect, another heating source is required, which increases the cost; on the other hand, in order to achieve better denitrification effect and anti-sulfur and water resistance , the honeycomb denitration catalyst generally has a high pore density, but the large amount of water, sulfur dioxide and dust contained in the actual flue gas can easily cause the catalyst to be blocked, which greatly increases the energy consumption of the power system

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A production method of a selective catalytic reduction (SCR) denitration catalyst comprises the following steps in sequence according to the production process:

[0022] (1) Use a calender with gears to produce catalyst substrates from ceramic glass fibers; wherein, the teeth of the calender gears have a depth and width of 2mm*4mm, and a calendering temperature of 15°C; The gears are occluded and rolled to obtain corrugated sheets; a flat plate is added between the two corrugated sheets and fixed with adhesive.

[0023] (2) Soaking the catalyst substrate produced in step (1) with the mixture solution; wherein, the soaking time is 5 minutes, and the temperature of the mixture solution is 50°C.

[0024] (3) Dry the catalyst substrate soaked in step (2); the drying time is 20 hours, the heating rate is 15°C / min, and the drying temperature reaches 100°C.

[0025] (4) Calcination; the calcination temperature is 420° C., the calcination time is 72 hours, and the heating rate...

Embodiment 2

[0028] Repeat the operation of Example 1, except that the depth and width of the calender gear teeth described in step (1) are changed to 15mm*25mm, and the calendering temperature is 30°C. The mixture solution in step (2) contains SiO2 30% of the total mass of the mixture solution, glass fiber 10%, V2O5 10%, WO3 10%, TiO2 30%; the soaking time is 10 minutes, and the temperature of the mixture solution is 70°C . The drying time in step (3) is 30 hours, the drying temperature reaches 120° C., and the heating rate is 10° C. / minute. In step (4), the calcination temperature is 450° C., the calcination time is 48 hours, and the heating rate is 2° C. / minute.

Embodiment 3

[0030] Repeat the operation of Example 1, except that the depth and width of the calender gear teeth described in step (1) are changed to 10mm*15mm, and the calendering temperature is 25°C; the mixture solution in step (2) contains SiO2 25%, glass fiber 15%, V2O5 15%, WO3 8%, TiO2 25%; the soaking time is 8 minutes, and the temperature of the mixture solution is 60°C. Said drying in step (3), the time is 25 hours, the heating rate is 12°C / min, and the drying temperature reaches 110°C. In step (4), the calcination temperature is 440° C., the calcination time is 62 hours, and the heating rate is 3° C. / minute.

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PUM

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Abstract

A denitration catalyst. A producing process of the denitration catalyst successively includes following steps: (1) manufacturing a catalyst base material with ceramic glass fibers; (2) soaking the catalyst base material manufactured in the step (1) in a mixture solution; (3) drying the soaked catalyst base material; (4) performing a calcining process. The catalyst base material in the step (1) is manufactured through a calendar having gears. The mixture solution includes following components on the basis of the total mass of the mixture solution, by mass, 20-30% of SiO2, 10-20% of glass fibers, 10-20% of V2O5, 5-10% of WO3 and 20-30% of TiO2. The catalyst is large in a specific surface area and is high in strength. On the premise of ensuring denitration effect, the catalyst is more excellent than a conventional honeycomb catalyst in anti-corrosion performance, anti-flue gas impact performance and the like.

Description

technical field [0001] The invention relates to a denitration catalyst, in particular to a selective catalytic reduction catalyst. Background technique [0002] The installed capacity, power generation and coal consumption of my country's thermal power industry are all on the rise, and the resulting nitrogen oxides (NO x ) have increasingly serious impacts on the environment. According to different catalyst carriers, the catalysts currently on the market for stationary source tail gas denitrification are mainly honeycomb catalysts. The catalyst has low pressure drop, wear resistance and excellent denitrification activity and has been widely used, but the existing honeycomb catalyst has some shortcomings, and its optimum working temperature is generally 300-450 °C. In actual working conditions, it is difficult for the flue gas temperature to reach this temperature range. In order to obtain a better denitrification effect, another heating source is required, which increases ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/30B01D53/90B01D53/56
Inventor 史红华
Owner 耘太环保科技(山东)股份有限公司
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