dual ion fuel cells

A single battery, dual-ion technology, applied in the direction of fuel cells, fuel cell additives, electrolyte treatment of solid electrolyte batteries, etc., can solve the problems of large drainage resistance, affecting battery performance, small pore size, etc., to increase battery life, The effect of improving battery performance

Active Publication Date: 2016-12-07
先进储能材料国家工程研究中心有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The advantage of this design is that it reduces the process steps and difficulty in the preparation process. The structure of the electrolyte layer is relatively stable during the sintering process, but the water vapor discharge channel is not deliberately fixed, but is formed naturally between the particles of the electrolyte material itself. However, the porous microscopic channels naturally formed between electrolyte particles have small pore diameters and curved drainage paths, which will generate large drainage resistance and affect battery performance.

Method used

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Examples

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Embodiment 1

[0016] A dual-ion type fuel cell with a planar structure, such as figure 1 As shown, it includes a positive plate 1, a solid electrolyte 3 and a negative plate 2 stacked in sequence. A current collector 4 is respectively fixed on the outer contact surface of the positive plate 1 and the negative plate 2, and several conductors are arranged on the current collector 4. Launder 6 is used for the passage of hydrogen or oxygen, wherein the size of the positive plate 1 is 7cm×7cm×50 μm, and the material is NiO / BCZY, and the size of the negative plate 2 is 7cm×7cm×20 μm, and the material is BCZY / LSCF , the size of the solid electrolyte 3 is 7cm×7cm×10μm, and the material is BCZY. It is a single-component electrolyte, and there are several channels 5 in the same direction and parallel to each other in the solid electrolyte 3. The length direction of 3 is parallel, the channel 5 is located in the middle of the solid electrolyte 3 and arranged in a straight line, and the cross section o...

Embodiment 2

[0020] A dual-ion type fuel cell, its structure is similar to the dual-ion type fuel cell of embodiment 1, and its difference is that: the channel is located in the position near the negative electrode in the solid electrolyte, and the cross-section of the channel has a diameter of 2 μm circular.

Embodiment 3

[0022] A single dual-ion fuel cell, the structure of which is similar to the dual-ion fuel single cell in Example 1, the difference is that the cross section of the channel is a rectangle with four sides each with a length of 5 μm.

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Abstract

The invention provides a dual ionic single fuel cell. The dual ionic single fuel cell comprises a positive electrode plate, solid electrolyte and a negative electrode plate which are sequentially overlapped, wherein the solid electrolyte is mono-component electrolyte; a plurality of channels with consistent directions and parallel to one another are formed in the solid electrolyte; the directions of the channels are parallel to the length direction or the width direction of the solid electrolyte. Through the dual ionic single fuel cell, water steam generated during reaction of the fuel cell can be conveniently dispersed out of the individual channels specifically arranged in the electrolyte, so that separation of H2O from H2 and O2 can be achieved, the concentrations of the H2 and the O2 in the electrode are not affected, the cell performance can be can improved, and the service life of the cell can be prolonged.

Description

technical field [0001] The invention relates to a single fuel cell, in particular to a dual-ion type fuel single cell. Background technique [0002] Depending on where the water is generated, fuel cells can be divided into the following three types: [0003] a) Hydrogen ion fuel cell: When the battery is working, the electrolyte only transfers H + , water is generated on the cathode side, such as proton exchange membrane fuel cells (PEMFC) and direct methanol fuel cells (DMFC) are of this type. [0004] b) Oxygen ion fuel cell: when the battery is working, the electrolyte only transfers O 2- , water is generated on the anode side, such as in solid oxide fuel cells (SOFC). [0005] c) Dual-ion fuel cell: when the battery is working, the electrolyte transmits H at the same time + and O 2- , but water is generated neither on the cathode nor the anode side, but in the electrolyte. The electrolyte is dense on both sides close to the electrode, with gaps in the middle layer,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M8/1004H01M8/0258
CPCH01M8/04291H01M8/1016Y02E60/50
Inventor 欧腾蛟石建珍张洪涛蒋庆来王一乔
Owner 先进储能材料国家工程研究中心有限责任公司
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