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Method for preparing alumina rock mineral polymer organic-inorganic composite material by impregnation method

A technology of inorganic composite materials and mineral polymers, which is applied in the field of preparation of aluminum rock mineral polymer organic-inorganic composite materials by impregnation method, which can solve the problems of insufficient mechanical properties such as strength and insufficient wide application range, and achieve simple preparation process , high economic value and environmental benefits, the effect of rich resources

Active Publication Date: 2016-06-22
GUIZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although this aluminum rock polymer material has great utilization value, its application range is not wide enough because of its mechanical properties such as strength are not high enough, and its mechanical properties such as compressive strength and flexural strength need to be improved to make it The application range is wider, and this aluminum rock-based mineral polymer material can be further prepared into other functional materials such as ceramic materials, high-strength building panels and high-strength toughening materials, etc.

Method used

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  • Method for preparing alumina rock mineral polymer organic-inorganic composite material by impregnation method

Examples

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Effect test

Embodiment 1

[0019] Take 40×40×160mm sample of aluminous rock polymer material for drying treatment, prepare an MMA (methyl methacrylate) organic solution containing 0.3% benzoyl peroxide curing agent, and immerse the dried sample after drying and cooling. After immersion in MMA (methyl methacrylate) organic solution at room temperature and pressure for 4 days, it was taken out, prepolymerized at 80 °C for 2 hours, then quickly cooled to room temperature, then polymerized at 50 °C for 24 hours, and then kept at 80 °C After 2h, the reaction was completed, that is, the organic-inorganic composite material was obtained.

[0020] Its compressive strength reaches 116.1MPa, its flexural strength reaches 31.5MPa, and the material has excellent mechanical properties.

Embodiment 2

[0022] Take 40 × 40 × 160 mm aluminum rock polymer material samples for drying treatment, prepare epoxy resin organic solution containing 0.3% benzoyl peroxide curing agent, and immerse the dried samples in epoxy resin organic solution after drying and cooling. The solution was soaked at room temperature and pressure for 5 days, taken out, prepolymerized at 100 °C for 2 hours, then quickly cooled to room temperature, then polymerized at 65 °C for 24 hours, and then kept at 50 °C to 100 °C for 2 hours to complete the reaction, that is, Organic-inorganic composite materials were prepared.

[0023] Its compressive strength reaches 114.9MPa, its flexural strength reaches 31.4MPa, and the material has excellent mechanical properties.

Embodiment 3

[0025] A 40×40×160mm sample of aluminum rock polymer material was taken and dried, and an epoxy resin organic solution containing 0.3% benzoyl peroxide curing agent was prepared. After drying and cooling, the dried sample was immersed in the amino resin organic solution. After immersion at normal temperature and pressure for 6 days, take it out, prepolymerize at 120 °C for 2 hours, then quickly cool to room temperature, then polymerize at 80 °C for 24 hours, and then keep it at 120 °C for 2 hours to make the reaction complete, that is, the organic- Inorganic composite materials.

[0026] Its compressive strength reaches 115.4MPa, its flexural strength reaches 31.2MPa, and the material has excellent mechanical properties.

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Abstract

The invention discloses a method for preparing organic-inorganic composite materials of an aluminum rock mineral polymer by use of an impregnation method. The method comprises the following steps: preparing an organic solution containing 0.3% of a curing agent; drying and cooling an aluminum rock mineral polymer, immersing the aluminum rock mineral polymer into the organic solution to steep at normal pressure and normal temperature for 4-6 days, and then taking out the aluminum rock mineral polymer; prepolymerizing the aluminum rock mineral polymer at 80-120 DEG C for 2 hours and then quickly cooling to room temperature; and polymerizing the aluminum rock mineral polymer at 50-80 DEG C for 24-48 hours, and keeping at 80-120 DEG C for 2 hours, so that the aluminum rock mineral polymer completely reacts, so as to prepare the aluminum rock mineral polymer-based organic-inorganic composite materials. The mineral polymer material prepared from aluminous rocks is relatively low in cost, and low in energy consumption; the compressive strength of the organic-inorganic composite materials obtained by steeping the aluminum rock mineral polymer with an organic solution exceeds the strength (greater than C30 and the like) of common concrete; and the organic-inorganic composite materials can be used for preparing functional materials such as ceramic materials, high-strength building boards, and high-strength toughening materials.

Description

technical field [0001] The invention relates to a method for preparing an aluminous rock mineral polymer organic-inorganic composite material by an impregnation method. Background technique [0002] Aluminous rocks contain Al 2 O 3 lower, generally Al 2 O 3 The content is distributed in 40%~50%. In the mining of solid waste for bauxite mines, generally only a small amount is used as a raw material for refractory materials. At present, most of them are abandoned and piled up randomly with the mining, resulting in a huge waste of resources and pollution of the environment. Therefore, it is necessary to focus on solving the problem of comprehensive utilization of aluminous rock resources. [0003] The aluminous rock mineral polymer material is made of aluminous rock, kaolin, and quartz sand in a ratio of 1:0.45:0.43, and adding water glass, an alkali activator, calcium hydroxide and water to make a mineral polymer material. Although this aluminum rock polymer material ha...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B12/00
Inventor 张杰王建蕊曹杰张玉松吴林王砂徐旭
Owner GUIZHOU UNIV
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