Non-aqueous electrolyte of lithium ion battery and lithium ion battery
A lithium-ion battery and non-aqueous electrolyte technology, which is applied in the field of lithium-ion battery non-aqueous electrolyte and lithium-ion batteries, can solve problems such as unstable phosphate compounds containing double bonds, electrolyte gas swelling, and potential safety hazards. Achieve good high-temperature storage performance and high-temperature cycle performance, prevent oxidation and decomposition, and inhibit dissolution
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Embodiment 1
[0038] 1) Preparation of electrolyte
[0039] Ethylene carbonate (EC), diethyl carbonate (DEC) and ethyl methyl carbonate (EMC) are mixed according to the mass ratio EC:DEC:EMC=1:1:1, and then lithium hexafluorophosphate (LiPF 6 ) To a molar concentration of 1 mol / L, and then add 0.5% of compound 1 based on the total mass of the electrolyte (compound 1 and compound 2 referred to in the specific embodiment...refer to the corresponding numbers listed in Table 1 Compound, the same applies to the following examples) phosphate compound.
[0040] 2) Preparation of positive plate
[0041] Mixed cathode active material lithium nickel cobalt manganese oxide LiNi in a mass ratio of 93:4:3 0.5 Co 0.2 Mn 0.3 O 2 , Conductive carbon black Super-P and binder polyvinylidene fluoride (PVDF), and then disperse them in N-methyl-2-pyrrolidone (NMP) to obtain positive electrode slurry. The slurry is evenly coated on both sides of the aluminum foil, dried, calendered and vacuum dried, and then the alumi...
Embodiment 2
[0058] Except that 0.5% of compound 1 is replaced with 0.5% of compound 2 in the preparation of the electrolyte, the rest is the same as in Example 1. The measured data of normal temperature cycle, high temperature cycle and high temperature storage are shown in Table 2.
Embodiment 3
[0060] Except that 0.5% of compound 1 is replaced with 0.5% of compound 4 in the preparation of the electrolyte, the rest is the same as in Example 1. The measured data of normal temperature cycle, high temperature cycle and high temperature storage are shown in Table 2.
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