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Calendering grass green rubber foxing adhesive for wear-resistant liberation shoes as well as preparation method and application thereof

A technology of rubber strip glue and Jiefang shoes, which is applied in the field of rubber material preparation, can solve problems such as unreasonable reinforcement system, large temperature fluctuation of rubber material performance, and unstable process performance, so as to improve scorch resistance and durability. Inflection performance, improved molding pass rate and service life, rubber quality and stable process performance

Inactive Publication Date: 2015-01-28
JIHUA 3537 SHOE MAKING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This kind of system usually has the following problems: (1) The reinforcement of the rubber is poor, (2) The vulcanization accelerator system has after-effect and super-speed vulcanization. Since the vulcanization of the rubber is generally slow at the beginning, the vulcanization speed of the rubber is affected during the use of the rubber. It is difficult to control, which leads to quality defects such as low scorch resistance of rubber materials, high brittleness of vulcanized rubber, and poor bending resistance of products
(3) Due to the unreasonable reinforcement system, the color of the rubber material is insufficient in grass green, the hue is not correct, and the appearance is not good
(4) All natural rubber is used, and the performance of the rubber material is unstable due to large fluctuations in temperature.
Therefore, the production efficiency of the product is not high, and the service life cannot meet the needs of consumers.

Method used

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  • Calendering grass green rubber foxing adhesive for wear-resistant liberation shoes as well as preparation method and application thereof
  • Calendering grass green rubber foxing adhesive for wear-resistant liberation shoes as well as preparation method and application thereof
  • Calendering grass green rubber foxing adhesive for wear-resistant liberation shoes as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Embodiment 1 of the present invention: wear-resistant type Jiefang shoes use calendered grass-green rubber enclosure glue, calculated in parts by weight, including 90 parts of 2# standard glue, 10 parts of styrene-butadiene rubber, 15 parts of high styrene, 2.2 parts Sulfur, 4 parts of vulcanization accelerator, 2 parts of stearic acid, 2 parts of active zinc oxide, 7 parts of pine tar, 65 parts of clay, 3.8 parts of anti-aging agent, 6 parts of composite resin DS-B, 9 parts of 3# calcium base grease, 32 parts of light calcium carbonate and 5 parts of grass green masterbatch; every 5 parts of vulcanization accelerator is composed of 3 parts of accelerator DM, 1.5 parts of accelerator M and 0.5 parts of accelerator DS; every 3.8 parts of anti-aging agent is composed of 3 parts of anti-aging agent Composed of CD and 0.8 parts of anti-aging agent KY-405L.

[0022] The preparation method of the calendered grass-green rubber enclosure glue for wear-resistant Jiefang shoes co...

Embodiment 2

[0025] Embodiment 2 of the present invention: wear-resistant type Jiefang shoes use calendered grass-green rubber enclosure glue, calculated according to parts by weight, including 90 parts of 2# standard glue, 10 parts of styrene-butadiene rubber, 15 parts of high styrene, 2 parts Sulfur, 4 parts of vulcanization accelerator, 2 parts of stearic acid, 2.2 parts of active zinc oxide, 7 parts of pine tar, 65 parts of clay, 3 parts of antioxidant, 5 parts of composite resin DS-B, 8 parts of 3# calcium base grease, 30 parts of light calcium carbonate and 6 parts of grass green masterbatch; every 5 parts of vulcanization accelerator is composed of 3 parts of accelerator DM, 1.5 parts of accelerator M and 0.5 parts of accelerator DS; every 3.8 parts of anti-aging agent is composed of 3 parts of anti-aging agent Composed of CD and 0.8 parts of anti-aging agent KY-405L.

[0026] The preparation method is the same as in Example 1.

Embodiment 3

[0027] Embodiment 3 of the present invention: wear-resistant type Jiefang shoes use calendered grass-green rubber enclosure glue, calculated in parts by weight, including 85 parts of 2# standard glue, 15 parts of styrene-butadiene rubber, 15 parts of high styrene, and 2.4 parts Sulfur, 6 parts of vulcanization accelerator, 1.8 parts of stearic acid, 1.8 parts of active zinc oxide, 8 parts of pine tar, 70 parts of clay, 4 parts of anti-aging agent, 6 parts of composite resin DS-B, 9 parts of 3# calcium base grease, 34 parts of light calcium carbonate and 4 parts of grass green masterbatch; every 5 parts of vulcanization accelerator consists of 3 parts of accelerator DM, 1.5 parts of accelerator M and 0.5 parts of accelerator DS; every 3.8 parts of anti-aging agent consists of 3 parts of anti-aging agent Composed of CD and 0.8 parts of anti-aging agent KY-405L.

[0028] The preparation method is the same as in Example 1.

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PUM

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Abstract

The invention discloses a calendering grass green rubber foxing adhesive for wear-resistant liberation shoes. The adhesive is prepared from the following components in parts by weight: 85-90 parts of standard rubber, 10-15 parts of butadiene-styrene rubber, 15 parts of high styrene, 2.0-2.4 parts of sulfur, 3.6-4.0 parts of a vulcanization accelerator, 1.8-2.2 parts of stearic acid, 1.8-2.2 parts of activated zinc oxide, 6-8 parts of pine tar, 75-85 parts of argil, 2.0-2.4 parts of an anti-aging agent, 4-8 parts of composite resin DS-B, 8-10 parts of calcium grease, 30-36 parts of light calcium carbonate and 4-6 parts of grass green masterbatch.

Description

technical field [0001] The invention relates to the field of rubber material preparation, in particular to a calendered grass-green rubber enclosure glue for wear-resistant Jiefang shoes, a preparation method and application thereof. Background technique [0002] The calendered grass-green rubber enclosure glue for Jiefang shoes usually uses natural rubber as the skeleton material, thiuram and thiazole accelerators to form an AA-type accelerator system, and the filling system uses calcium carbonate, quartz powder, etc. as the main materials. The preparation method adopts a one-time feeding method, and various materials are directly batched. This kind of system usually has the following problems: (1) The reinforcement of the rubber is poor, (2) The vulcanization accelerator system has after-effect and super-speed vulcanization. Since the vulcanization of the rubber is generally slow at the beginning, the vulcanization speed of the rubber is affected during the use of the rubb...

Claims

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Application Information

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IPC IPC(8): C08L7/00C08L9/06C08K13/02C08K3/06C08K5/09C08K3/22C08K3/34C08K3/26A43B1/10
CPCC08L7/00A43B1/10C08L2205/035C08L9/06C08L91/00C08K13/02C08K3/06C08K5/09C08K2003/2296C08K3/346C08K2003/265
Inventor 杜江陈松雄周川泉晋齐怀石银平田吉张世林王春桥安廷飞
Owner JIHUA 3537 SHOE MAKING
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