Preparation method of waterproof fabric
A waterproof fabric and fabric technology, applied in textiles, papermaking, fiber treatment, etc., can solve the problems of inability to achieve protective effect, non-fitting of rubber layer and fabric layer, poor use effect, etc., and achieve excellent waterproof performance, sensitive use, good reinforcing effect
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Embodiment 1
[0032] This embodiment relates to a preparation method of waterproof gloves, specifically comprising the following steps:
[0033] Step 1. Prepare waterproof emulsion
[0034] Add the nanometer fluorocarbon resin polymer into water under stirring conditions to obtain a mixed solution, the concentration of the nanometer fluorocarbon resin polymer is 30g / L; add glacial acetic acid or citric acid dropwise to the mixed solution until the pH value is 5, i.e. Get a waterproof lotion.
[0035] The nano-fluorocarbon resin polymer in this embodiment is self-made, and the specific methods are as follows:
[0036] Add 1.74g (0.01mol) of 2,4-toluene diisocyanate, 4ml of anhydrous methyl isobutyl ketone and 1 drop of dibutyltin dilaurate (catalyst) in a four-necked flask to dry N 2 Protect, heat up to 65-70°C, slowly add 4.57g (0.01mol) of N-hydroxyethyl perfluorooctylamide and 12ml of anhydrous methyl isobutyl ketone solution dropwise, dropwise for 1h, and maintain this state after drop...
Embodiment 2
[0046] This embodiment relates to a preparation method of waterproof gloves, specifically comprising the following steps:
[0047] Step 1. Prepare waterproof emulsion
[0048] Add the nanometer fluorocarbon resin polymer into water under stirring conditions to obtain a mixed solution, the concentration of the nanometer fluorocarbon resin polymer is 30g / L; add glacial acetic acid or citric acid dropwise to the mixed solution until the pH value is 5, i.e. Get a waterproof lotion.
[0049] The nano-fluorocarbon resin polymer in this embodiment is a self-made organosilicon-modified nano-fluorocarbon resin polymer, and the specific preparation method is as follows:
[0050] The nano-fluorocarbon resin polymer prepared by the method of Example 1 is mixed with the silane coupling agent KH-570, and a coupling reaction occurs to obtain a silicone-modified nano-fluorocarbon resin polymer; the amount of the silane coupling agent 5wt.%.
[0051] Step 2. Glove dipping
[0052] Wash / soa...
Embodiment 3
[0060] This embodiment relates to a preparation method of waterproof gloves, specifically comprising the following steps:
[0061] Step 1. Prepare waterproof emulsion
[0062] Add the nanometer fluorocarbon resin polymer into water under stirring conditions to obtain a mixed solution, the concentration of the nanometer fluorocarbon resin polymer is 30g / L; add glacial acetic acid or citric acid dropwise to the mixed solution until the pH value is 5, i.e. Get a waterproof lotion.
[0063] The nanometer fluorocarbon resin polymer in the present embodiment is CF-1114 fluorocarbon resin, is made of molecular size less than 10 -9 Fluorocarbon polymer colloids of 80-185nm that are agglomerated from m particles.
[0064] Step 2. Glove dipping
[0065] Wash / soak the gloves in water to wash off the floating color, dirt and hydrophilic groups on the surface of the fabric, so that the fabric and the waterproof agent have a better hinge reaction at high temperature; spin dry to quickly ...
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