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Manufacturing method of modified PET tangle film

A manufacturing method and modification technology, which is applied in the manufacturing field of modified PET twisted film, can solve problems such as small temperature range and difficult adjustment of production process parameters, and achieve good oil resistance and fragrance retention, good food hygiene and stable storage good sex effect

Inactive Publication Date: 2015-05-06
GUANGDONG HUAYE PACKING MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In film forming process, PETG material can be molded in a small temperature range, and the production process parameters are difficult to adjust, so blow molding method can only be used to obtain twisted film

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Polyethylene glycol-1,4-cyclohexanedimethanol terephthalate with an average molecular weight of 45,000 and a molar ratio of ethylenedioxy to 1,4-cyclohexanedimethoxy in the polymer is 1.52:1 , 145 kg of polymer and 5 kg of silica blocking agent were stirred and mixed on a mixer for 15 minutes, and then sent to a dew point dehumidification dryer for drying. The drying temperature was 50-60 ° C, and the dew point was lower than -40 ° C. The drying time 6 hours to reduce the moisture content of raw materials to below 400ppm. Send the dried raw materials to the conveying tank. The tank should be isolated from the outside world to ensure that the material will not absorb moisture in the tank. The raw materials in the material tank are accurately measured by a weight loss scale, and are stably added to a twin-screw extruder with a length-to-diameter ratio of 35 times, and are melted and mixed at 260 ° C. The material is sent to a T-die head at 260°C for extrusion, and cast i...

Embodiment 2

[0023] The molar ratio of ethylenedioxy and neopentyldioxy in the polymer is 1.8: 1, and polyethylene terephthalate-ethylene glycol-neopentyl glycol with an average molecular weight of 42000 is used to mix 145 kg of polymer with 5 kg The silicon dioxide anti-blocking agent is stirred and mixed on the mixer for 15 minutes, and then sent to the dew point dehumidification dryer for drying. The drying temperature is 50-60°C, the dew point is lower than -40°C, and the drying time is 6 hours, so that the moisture content of the raw materials is lower than 400ppm. Send the dried raw materials to the conveying tank. The tank should be isolated from the outside world to ensure that the material will not absorb moisture in the tank. The raw materials in the material tank are accurately measured by a weight loss scale, and are stably added to a twin-screw extruder with a length-to-diameter ratio of 35 times, and are melted and mixed at 260 ° C. The material is sent to a T-die head at 26...

Embodiment 3

[0026]Polyethylene terephthalate-1,4-cyclohexanedicarboxylate with an average molecular weight of 45,000 and a molar ratio of terephthaloyl to 1,4-cyclohexanedicarboxylate in the polymer is 2.2:1 , 145 kg of polymer and 5 kg of silica blocking agent were stirred and mixed on a mixer for 15 minutes, and then sent to a dew point dehumidification dryer for drying. The drying temperature was 50-60 ° C, and the dew point was lower than -40 ° C. The drying time 6 hours to make the moisture content of the raw material lower than 400ppm. Send the dried raw materials to the conveying tank. The tank should be isolated from the outside world to ensure that the material will not absorb moisture in the tank. The raw materials in the material tank are accurately measured by a weight loss scale, and are stably added to a twin-screw extruder with a length-to-diameter ratio of 35 times, and are melted and mixed at 260 ° C. The material is sent to a T-die head at 260°C for extrusion, and cast ...

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Abstract

The invention discloses a manufacturing method of a polyterephthalate-glycol-1,4-cyclohexylene dimethylene terephthalate, polyterephthalate-glycol-neopentyl glycol, polyterephthalate-glycol-1,4-cyclohexanedicarboxylate-gylcol ester or polyterephthalate-neoglutarate-gylcol ester modified PET tangle film. The manufacturing method comprises the following steps: adding modified PET materials with average molecular weight within 40000-50000 into an oleamide or silicon dioxide anti-blocking agent; mixing, drying, plastifying, melting and extruding to form a film; after quenching sizing on a cooling roll and pre-heating through a heating roll, carrying out 1: (2-5)-times-longitudinal stretching between a low-speed roll and a high-speed roll; sizing by a sizing roll; trimming and rolling; and carrying out ageing treatment to obtain the finished product. According to the manufacturing method provided by the invention, the production efficiency and the product performance of the modified PET tangle film can be greatly improved.

Description

technical field [0001] The invention relates to a method for manufacturing a packaging twist film, in particular to a method for manufacturing a modified PET twist film. Background technique [0002] Uniaxially stretched modified polyethylene terephthalate twist film is a new type of green packaging material developed in recent years. Compared with traditionally used polyethylene and polyvinyl chloride films, it has high strength, rigidity Large, non-toxic, easy to degrade, easy to color, good gloss and transparency, easy processing and other advantages, it is widely used in various items such as handicrafts, daily necessities, metal products, especially food packaging. [0003] CN101838445A discloses the improvement of PETG (polyethylene terephthalate-1,4-cyclohexanedimethanol ester) film and its preparation method, consisting of 85-92wt% PETG, 2.0-4.0wt% anti-blocking agent, 0.5-1.5 Wt% smooth agent, 0.2-1.0wt% antistatic agent, 0.005-0.01wt% chain extender, 5.0-10.0wt% t...

Claims

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Application Information

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IPC IPC(8): C08L67/02C08K5/20C08K3/36B29C69/02B29C47/92B29C55/06B29L7/00B29C48/92
Inventor 陈友标陈耿锋洪之全陈文娜
Owner GUANGDONG HUAYE PACKING MATERIAL