A polyester with composite functions of moisture absorption, flame retardancy and UV resistance

A composite function, anti-ultraviolet technology, applied in the direction of single-component polyester rayon, melt spinning, etc., can solve the problems of secondary poisoning, undeveloped, moisture absorption performance modification, etc., to slow down dripping, increase Amorphous space, effect of increased hygroscopicity

Active Publication Date: 2016-08-17
BEIJING INST OF CLOTHING TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In the prior art, there are polyester materials with a single function and fibers made therefrom, or composite polyester materials with the above two functions and fibers made therefrom, which are obtained by adding anti- UV paste or flame retardant, thereby preparing polyester products with anti-ultraviolet function or flame-retardant function, such as Chinese patent CN101735578A, which discloses a flame-retardant and anti-ultraviolet polyester composite material and its preparation method. The material only modifies the polyester material in terms of flame retardancy and UV resistance, but does not modify its hygroscopic performance, and the flame retardant used in it contains halogen, which will bring toxic substances such as hydrogen halide while flame retardant. gas, may cause secondary poisoning incidents; and for example, Chinese patent CN201210526666.1 discloses a preparation method of moisture-absorbing flame-retardant polyester fiber, and its modification of polyester is limited to flame-retardant and moisture-absorbing aspects, No modification in UV
[0006] In summary, polyester and its fibers with composite functions of moisture absorption, UV resistance and flame retardancy have yet to be developed.

Method used

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  • A polyester with composite functions of moisture absorption, flame retardancy and UV resistance
  • A polyester with composite functions of moisture absorption, flame retardancy and UV resistance
  • A polyester with composite functions of moisture absorption, flame retardancy and UV resistance

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0083] Pretreatment of inorganic nano-anti-ultraviolet powder: Weigh 50g of zinc oxide and PEG2001g, mix and stir, and then use ethylene glycol as the dispersion medium to disperse the aforementioned mixture by ball milling. Centrifuge for 30 seconds to obtain a dispersed particle size of zinc oxide of 190-280 nm.

[0084] Weigh 45g of ethylene glycol (EG), 98g of terephthalic acid (PTA), 2g of isophthalic acid (IPA), flame retardant 9,10-dihydro-9-oxa-10-phosphaphenanthrene- 5.4g of 10-oxide and 0.032g of antimony trioxide were added to the first esterification reactor at the same time to carry out the esterification reaction at a temperature of 245°C. The esterification reaction was carried out for 3.5 hours, and the first esterification product was introduced into the second esterification reactor. , adding 7.5g of diethylene glycol isophthalate-5-sodium sulfonate (SIPE), 10g of polyethylene glycol and 1.7g of treated zinc oxide in sequence, and after continuing the esterif...

Embodiment 2

[0086] Pretreatment of inorganic nano-anti-ultraviolet powder: Weigh 70g of aluminum oxide, mix and stir 1g of PEG400, and then use ethylene glycol as the dispersion medium to disperse the aforementioned mixture by ball milling. The aluminum oxide powder after ball milling and dispersion is in the Centrifuge at 2600r / min for 25 seconds to obtain aluminum oxide with a particle size of 220nm-300nm.

[0087] Weigh 41g of ethylene glycol (EG), 98g of terephthalic acid (PTA), 2g of isophthalic acid (IPA), flame retardant 9,10-dihydro-9-oxa-10-phosphaphenanthrene- 10-oxide 3.0g, 10-(2,5-dihydroxyphenyl)-10-hydro-9-oxa-10-phosphaphenanthrene-10-oxide 3.0g and antimony acetate 0.03g, add a The esterification reaction is carried out at a temperature of 258°C in the esterification reaction kettle, and the esterification reaction is carried out for 3 hours. The monoesterification product is introduced into the diesterification reaction kettle, and dimethyl isophthalate-5-sodium sulfonate...

Embodiment 3

[0089] Pre-treatment of inorganic nano-anti-ultraviolet powder: Weigh 10g of titanium dioxide, 10g of kaolin, and 10g of silicon dioxide respectively, mix and mix with 1g of PEG200 and stir, and then use ethylene glycol as the dispersion medium for titanium dioxide, kaolin, and silicon dioxide Mix the solid powders for ball milling and disperse. After ball milling, the mixed powder of titanium dioxide, kaolin and silicon dioxide is centrifuged at 2600r / min for 30 seconds to obtain titanium dioxide, kaolin and silicon dioxide with a particle size of 200-400nm.

[0090] Weigh 48g of ethylene glycol (EG), 95g of terephthalic acid (PTA), 5g of isophthalic acid (IPA), 6-oxo-6H-dibenzo-c,e-1,2-oxaphospha Hexan-6-one methyl-succinic acid 6.8g and ethylene glycol antimony 0.035g were added into the esterification reaction kettle at the same time to carry out the esterification reaction at a temperature of 250°C. The esterification reaction was carried out for 3.5 hours, and the esterif...

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Abstract

The present invention discloses a polyester having moisture absorption, fire retardation and ultraviolet resistance composite function. According to the present invention, a fire retardation agent, inorganic nanometer anti-ultraviolet powder, a moisture absorption modification monomer and the like are added to the polymerization raw material, wherein the fire retardation agent and the moisture absorption modification monomer have the synergy effect so as to improve the moisture absorption property of the polyester, such that the chemical structure of the polyester is modified so as to make the polyester concurrently have functions of strong moisture absorption, strong fire retardation and strong ultraviolet resistance.

Description

technical field [0001] The invention relates to the fields of polymer materials and textile fiber materials, in particular to a polyester with composite functions of moisture absorption, flame retardancy and ultraviolet resistance. Background technique [0002] Polyester fiber, namely polyester, has good strength, drapability, excellent wrinkle resistance and is practical and durable, so it is widely used in clothing textiles. However, garments made of polyester fibers still have many deficiencies in terms of heat and humidity comfort, health protection and flammability when worn. As well as Guangdong Shunde Jinfang Group, etc., all use special-shaped spinnerets to form various types of fine grooves on the surface of polyester fibers to achieve the purpose of dehumidification and quick drying, and to prepare polyester products with comfortable functions. The surface morphology of the fiber has been modified, but the molecular structure of the polyester fiber has not been im...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G63/688C08G63/672C08G63/66C08K13/06C08K9/04C08K3/22C08K5/53C08K5/098C08K3/34C08K3/36C08K5/057D01F6/92D01D5/098
Inventor 朱志国王锐周静宜张秀芹
Owner BEIJING INST OF CLOTHING TECH
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