The invention relates to an electrostatic 
spinning method and a nanometer 
fiber / anti-sticking non-
woven fabric composite filter material prepared through the electrostatic 
spinning method. Multi-needle electrostatic 
spinning is adopted in the electrostatic spinning method, and needles of multi-needle electrostatic spinning are insulated from one another. The prepared nanometer 
fiber / anti-sticking non-
woven fabric composite filter material is formed by overlapping and 
compositing materials for overlapping from bottom to top according to the low-to-high sequence of filtering efficiency of a filtering material, the face, with electrostatic spinning 
fiber, of each layer of material for overlapping faces upwards, the uppermost layer of material for overlapping is covered with anti-sticking non-
woven fabric, and therefore it is ensured that the top layer and the bottommost layer are both anti-sticking non-woven fabric 
layers; of every two adjacent 
layers of materials for overlapping, the filtering efficiency value for particles with grain size of 0.02 micron to 10 microns of the upper layer is 1.03-1.3 times that of the lower layer, the number of overlapping 
layers of the materials for overlapping ranges from 2 to 6, the anti-sticking non-woven fabric and the interlayer structure with 
electret effect nanometer fibers arrayed at intervals are formed, and the nanometer fiber / anti-sticking non-
woven fabric composite filter material is formed; the filtering efficiency of the nanometer fiber / anti-sticking non-
woven fabric composite filter material for particles with grain size of 0.02 micron to 10 microns reaches 99.999% or higher, and the 
pressure resistance is kept between 10 Pa and 30 Pa.